• Title/Summary/Keyword: Dispersion force

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A Study on Mechanical Properties of Wood-Polymer Composites due to Environmental Characteristic (목재 고분자 복합재료의 환경 특성에 따른 기계적 물성연구)

  • Lee, Joong-Hee;Jeon, Sang-Jin;Heo, Seok-Bong;Kim, Hong-Gun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.91-94
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    • 2005
  • Polypropylene as a matrix has been used for wood polymer composites(WPC). In preparing WPC, the coupling agent, Polypropylene grafted Maleic Anhydride(PP-G-MA) was used in order to obtain a good interfacial bonding force between matrix and fillers and dispersion of wood powders. In this study, the effects of wood powder contents and water absorption on the mechanical properties were experimentally investigated. The tensile strength and flexural strength of composites reached its peak value when the wood powder content was around 60 wt%. However, the peak value of the impact was observed about 30 wt% of wood powder content. The tensile strength and flexural strength increase with increasing the wood power contents. But the impact strength decrease with increasing the wood powder contents. The slight change was observed with the water absorption in the WPC. The optimal condition of the compositions such as Anti-oxidant and UV stabilizers for the outdoor application was suggested in this research.

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Fabrication of $Al_2O_3/Al$ Composite Materials by Mashy State Forming and its Hot Extrusion Process (반용융가공에 의한 $Al_2O_3/Al$ 복합재료의 제조 및 열간압출공정)

  • Kang, Chung-Gil;Kang, Sung-Soo
    • Journal of Korea Foundry Society
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    • v.13 no.3
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    • pp.248-258
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    • 1993
  • A semi-solid alloy in which solid and liquid phase are co-existing is obtained by stirring of A17075 molten metal. A semi-solid alloy is dependent on the corresponding temperature within the solid-liquid range, and the process parameters should be controlled accurately to obtain the homogeneous semisolid alloy. The fabrication possibility of fiber-reinforced aluminum alloy containing $Al_2O_3$ short fibers with vigorous agitation of short fibers were obtained by control of stirring time, solid fraction and impeller speed in extrusion billet fabrication processes. The microstructure to extrusion billet fabricated by low pressure casting was investigated for fiber dispersion state. The relationship between the extrustion force and velocity at hot extrustion, the flow strain and extrusion ratio were theoretically described. The surface defects with lubricants and without lubricant after hot extrusion were investigated. The composites materials after hot extrusion were measured by vickers hardness with extrusion ratio. It has become clear that the secondary working such as hot extrusion was very useful to obtained improved the mechanical properties of metal matrix composites.

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Acoustic Radiation from a Finite-length Shell with Substructures Subjected to an Impulsive Load (부구조물이 있는 유한길이의 쉘 구조물에서의 충격하중에 의한 음향방사)

  • 최성훈
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1995.10a
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    • pp.62-67
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    • 1995
  • A method for determining impulsive responses and acoustic radiation for submerged shells of finite length has been presented. The method is a modal-based method, and uses a surface variational principle to obtain data in the frequency domain. The fast Fourier transform technique is used to convert the data to the time domain. The surface pressure responses of a cylindrical shell with endcaps wer compared with those of an infinite shell. It was shown that the surface pressures coincide exactly before any significant reflections from the endcaps occur. Traces of different types of waves were identified from the dispersion relations of the infinite shell. The contributions of flexural and longitudinal waves and these due to the direct radiation from the driving force to the fluid pressure were demonstrated using near-field plots. The exchange of energy between the shell and fluid was examined for shells with and without bulkheads. It was shown that a significant amount of the energy which enters the fluid returns to the shell and most of the energy is dissipated in the shell. It was also shown that the shell with bulkheads radiate significantly more energy into the far-field than the empty shell.

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Dispersion Characteristics of Surface-Modified Graphene Nanoplate in Organic Solvent for Development of Graphene / Epoxy Paint to Protect Concrete (콘크리트 보호용 그래핀/에폭시 도료개발을 위해 표면개질한 그래핀 나노플레이트의 유기용매 분산특성)

  • Seo, Won-Woo;Kim, Gyu-Yong;Yoon, Min-Ho;Lee, Sang-Kyu;Hwang, Eui Chul;Son, Min-Jae
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.244-245
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    • 2017
  • This study aims to develop high durability graphene / epoxy paint for durability improvement of construction structure. For the development of graphene / epoxy coatings, first, graphene must remain stable in the polymer. Second, the integrity of graphene and polymer should be ensured. Accordingly, in order to obtain dispersibility, surface modification of graphene nanoplate(GnP) with CH and COOH functional groups and its dispersibility in organic solvents were investigated. Also, Fourier Transform Infrared Spectroscopy(FT-IR) analysis and Atomic Force Microscope(AFM) analysis were performed to confirm whether the functional groups were synthesized by surface modification. As a result, FT-IR and AFM analysis did not confirm the surface modification, but GnP was found to be stable when dispersed in an organic solvent.

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OBSERV ATION OF MICRO-STRUCTURE AND OPTICAL PROPERTISE OF TITANIUM DIOXIDE THIN FILMS USING OPTICAL MMEHODS

  • Kim, S.Y.;Kim, H.J.
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.788-796
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    • 1996
  • $TiO_2$ films prepared by RF magnetron sputtering, electron beam evaporation, ion assisted deposition (IAD) and sol-gel method are prepared on c-Si substrate and vitreous silica substrate respectively. From the transmission spectra of $TiO_2$ films on vitreous silica substrate in the spectral region from 190 nm to 900 nm, k($\lambda$) of $TiO_2$ is obtained. Using k($\lambda$) in the interband transition region the coefficients of the quantum mechanical dispersion relation of an amorphous $TiO_2$ and hence n($\lambda$) including the optically opaque region of above fundamental transition energy are obtained. The spectroscopic ellipsometry spectra of $TiO_2$ films in the spectral region of 1.5-5.0eV are model analyzed to get the film packing density variation versus i) substrate material, ii) film thickness and iii) film growth technique. The complex refractive index change of these $TiO_2$ films versus water condensation is also studied. Film micro-structures by SE modelling results are compared with those by atomic force microscopy images and X-ray diffraction data.

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A Genetic Algorithm for Trip Distribution and Traffic Assignment from Traffic Counts in a Stochastic User Equilibrium

  • Sung, Ki-Seok;Rakha, Hesham
    • Management Science and Financial Engineering
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    • v.15 no.1
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    • pp.51-69
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    • 2009
  • A network model and a Genetic Algorithm (GA) is proposed to solve the simultaneous estimation of the trip distribution and traffic assignment from traffic counts in the congested networks in a logit-based Stochastic User Equilibrium (SUE). The model is formulated as a problem of minimizing a non-linear objective function with the linear constraints. In the model, the flow-conservation constraints are utilized to restrict the solution space and to force the link flows become consistent to the traffic counts. The objective of the model is to minimize the discrepancies between two sets of link flows. One is the set of link flows satisfying the constraints of flow-conservation, trip production from origin, trip attraction to destination and traffic counts at observed links. The other is the set of link flows those are estimated through the trip distribution and traffic assignment using the path flow estimator in the logit-based SUE. In the proposed GA, a chromosome is defined as a real vector representing a set of Origin-Destination Matrix (ODM), link flows and route-choice dispersion coefficient. Each chromosome is evaluated by the corresponding discrepancies. The population of the chromosome is evolved by the concurrent simplex crossover and random mutation. To maintain the feasibility of solutions, a bounded vector shipment technique is used during the crossover and mutation.

Generation of High Pretilt Angle in Liquid Crystal Cell with Slanted Non-Polarized Ultraviolet Light Irradiation on Polyimide Film as for Non-Rubbing Techniques (경사진 자외선을 폴리이미드막 표면에 조사한 넌러방법에 의한 액정소자의 고 프리틸트각의 발생)

  • Seo, Dae-Shik;Hwang, Lyul-Yeon;Lee, Bo-Ho
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1585-1587
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    • 1997
  • We investigated the generation of high pretilt angle for nematic liquid crystal (NLC) in the cell with slanted non-polarized ultraviolet (UV) light irradiation on two kinds of the polyimide (PI) film. It was shown that the monodomain alignment in NLC is obtained in the cell with slanted non-polarized UV light irradiation on PI surface. The pretilt angle of NLC is generated about 3 degrees in the cell with slanted non-polarized UV light irradiation with 70 degrees on PI surface without side chain. But, the pretilt angle of NLC is generated about 1 degree in the cell with slanted non-polarized UV light irradiation with 80 degrees on PI surface with side chain. We consider that the pretilt angle generation in NLC is attributted to anisotropic dispersion force between the LC molecular and the PI surface.

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Two-Photon Absorption Cross Sections of Dithienothiophene-Based Molecules

  • Chung, Myung-Ae;Lee, Kwang-Sup;Jung, Sang-Don
    • ETRI Journal
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    • v.24 no.3
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    • pp.221-225
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    • 2002
  • We performed nonlinear transmission measurements and quantum-chemical calculations on dithienothiophene(DTT)-based molecules to gain insight into the effect of acceptor and donor groups on two-photon absorption(TPA) properties. The TPA intensity showed dispersion characteristics of the single-photon absorption spectrum. When the molecules included an asymmetric donor-acceptor pair, the single- and two-photon absorption maximum wavelengths were red-shifted more than when the molecules had a symmetric donor-donor structure. We interpreted this result as indicating that the $S_2$ state plays the dominating role in the absorption process of molecules with a symmetric structure. The experimental TPA ${\delta}$ values at the absorption peak wavelength showed a dependence on the structural variations. We found the self-consistent force-field theory and Hartree-Fock Hamiltonian with single configuration interaction formalism to be valid for evaluating TPA ${\delta}$. Although the quantum-chemical calculations slightly underestimated the experimental ${\delta}$ values obtained from nonlinear trans -mission measurements, they reasonably predicted the dependence of the ${\delta}$ value on the structural variations. We confirmed the role of molecular symmetry by observing that donor-donor substituted structure gave the highest experimental and theoretical TPA ${\delta}$ values and that the donor-acceptor substituted structure showed a greater red-shift in the TPA absorption maximum wavelength. Overall, the theoretical ${\delta}$ values of DTT-based molecules were in the order of $10^{-46}\;cm^4{\cdot}s{\cdot}photon^{-1}$ and are higher than that of AF-50 by nearly two orders of magnitude.

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Optimized for Low-temperature Sintering of TiO2 Paste with TTIP (TTIP를 이용한 저온소성용 TiO2 페이스트 최적화)

  • Jung, You-Ra;Jin, En Mei;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.8
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    • pp.608-613
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    • 2013
  • In this paper, the low-temperature sintering of $TiO_2$ is approached to solve the problem of high temperature sintering which decreases the interconnection between particles or between substrate and particle. $TiO_2$ paste is prepared with Titanium (IV) isopropoxide as the precursor material and calcinate at different conditions (low temperature). In the results, since the changing of temperature and time of sintering, crystalline phase do not change and the intensities of anatase, rutile phase are higher. At $110^{\circ}C$, 7 h sintering condition, crystalline size of anatase and rutile phase are the smallest which are 13.07 and 17.47 nm, respectively. In addition, the highest zeta potential is about 32.77 mV and the repulsive force increases thus leading to the best of the dispersion characteristics between $TiO_2$ particles. Futhermore, DSSCs at that condition exhibits the highest efficiency with the values of $V_{oc}$, $J_{sc}$, FF and ${\eta}$ are 0.69 V, $8.60mA\;cm^{-2}$, 67.93% and 4.06%, respectively.

INTERPARTICLE POTENTIAL OF 10 NANOMETER TITANIUM NANOPARTICLES IN LIQUID SODIUM: THEORETICAL APPROACH

  • KIM, SOO JAE;PARK, GUNYEOP;PARK, HYUN SUN;KIM, MOO HWAN;BAEK, JEHYUN
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.662-668
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    • 2015
  • A suspension of titanium nanoparticles (Ti NPs) in liquid sodium (Na) has been proposed as a method to mitigate the violent sodium-water reaction (SWR). The interparticle potential between Ti NPs in liquid Na may play a significant role in the agglomeration of NPs on the reaction surface and in the bulk liquid Na, since the potential contributes to a reduction in the long-term dispersion stability. For the effective control of the SWR with NPs, a physical understanding of the molecular dynamics of NPs in liquid Na is key. Therefore in this study, the nonretarded Van der Waals model and the solvation potential model are employed to analyze the interparticle potential. The ab initio calculation reveals that a strong repulsive force driven by the solvation potential exceeds the interparticle attraction and predicts the agglomeration energy required for two 10-nm Ti NPs to be $4{\times}10^{-17}J$. The collision theory suggests that Ti NPs can be effective suppressors of the SWR due to the high energy barrier that prevents significant agglomeration of Ti NPs in quiescent liquid Na.