• Journal of the Korean Society of Safety
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• v.32 no.2
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• pp.52-58
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• 2017

One of the most important elements of the management of chemical accident is threat zone estimation of fires, explosions and toxic gas dispersion based on chemical releases. The threat zone estimation is going to be standard of emergency response for the first defender and base line data of off-site risk assesment (hereinafter referred to as "ORA") and risk management plan (hereinafter referred to as "RMP"). Generally, ALOHA form EPA(U.S.) and Kora(from KOREA MINISTRY OF ENVIRONMENT) has been used for the off-site consequence analysis in Korea. However it is hard to predict accurate consequences rapidly in case of emergency. Hydrochloric acid is a multipurpose raw material used in many industrial applications such as chemical, metal and food industries. It is usually treated in concentrations from 10 ~ 35 %, and release accident have occurred frequently. In this study, we have developed a simplified estimating method and equation to calculate threat zone easily in case of emergency due to release accident of hydrochloric acid.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.267-279
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• 1990

The adsorption mechanisms of phenols on XAD-2 and XAD-7 resins were studied by using the distribution coefficient(log Kd) measured in the optimum adsorption conditions. It was observed that the Langmuir adsorption isotherm, indicating a molecular size-dependent adsorption, was appropriate for characterizing the adsorption behaviors of phenols on XAD-2 and XAD-7 resins. The adsorption energies of phenols on XAD resins were calculated by Lennard-Jones potential equation. In the calculation of the adsorption energy, the molecular radii and dipole moments of the resins and phenols were calculated by their van der Waals volumes and Debye equation, respectively. The stacking factor (F) were determined from the radio of the equilibrium distance to the stacking distance of molecules. In order to explain the adsorption energy calculated from the stacking factor it was compared with the adsorption enthalpy for each of phenols which was experimentally determined by batch adsorption shake method. It was observed that the adsorption enthalpy of phenolate ions on the XAD resins was likely to be more seriously affected by dispersion interaction than by a dipole or a charge interaction.

• Asian Journal of Atmospheric Environment
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• v.11 no.4
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• pp.270-282
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• 2017

To evaluate the deposition amount on a ground surface, mesoscale numerical models coupled with atmospheric chemistry are widely used for larger horizontal domains ranging from a few to several hundreds of kilometers; however, these models are rarely applied to high-resolution simulations. In this study, the performance of a dry and wet deposition model is investigated to estimate the amount of deposition via computational fluid dynamics (CFD) models with high grid resolution. Reynolds-averaged Navier-Stokes (RANS) simulations are implemented for a cone and a two-dimensional ridge to estimate the dry deposition rate, and a constant deposition velocity is used to obtain the dry deposition flux. The results show that the dry deposition rate of RANS generally corresponds to that observed in wind-tunnel experiments. For the wet deposition model, the transport equation of a new scalar concentration scavenged by rain droplets is developed and used instead of the scalar concentration scavenged by raindrops falling to the ground surface just below the scavenging point, which is normally used in mesoscale numerical models. A sensitivity analysis of the proposed wet deposition procedure is implemented. The result indicates the applicability of RANS for high-resolution grids considering the effect of terrains on the wet deposition.

• Journal of Environmental Science International
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• v.19 no.2
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• pp.137-148
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• 2010

This paper investigates the characteristics of turbulence schemes. Turbulence closures are fundamental for modeling the atmospheric diffusion, transport and dispersion in the boundary layer. In particular, in non-homogeneous conditions, a proper description of turbulent transport in planetary boundary layer is fundamental aspect. This study is based on the Regional Atmospheric Modeling System (RAMS) and combines four different turbulence schemes to assess if the different schemes have a impact on simulation results of vertical profiles. Two of these schemes are Isotropc Deformation scheme (I.Def) and Anisotropic deformation scheme (A.Def) that are simple local scheme based on Smagorinsky scheme. The other two are Mellor-Yamada scheme (MY2.5) and Deardorff TKE scheme (D.TKE) that are more complex non-local schemes that include a prognostic equation for turbulence kinetic energy. The simulated potential temperature, wind speed and mixing ratio are compared against radiosonde observations from the study region. MY2.5 shows consistently reasonable vertical profile and closet to observation. D.TKE shows good results under relatively strong synoptic condition especially, mixing ratio simulation. Validation results show that all schemes consistently underestimated wind speed and mixing ratio but, potential temperature was somewhat overestimated.

• Geomechanics and Engineering
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• v.16 no.2
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• pp.169-176
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• 2018

An attempt has been made here to study the propagation of SH-type surface waves in an elastic medium, which is initially stressed and heterogeneous and has a point source inside the medium. The upper portion of the composite medium is a sandy layer. It is situated on an initially stressed heterogeneous half-space, whose density, rigidity and internal friction are function of depth. The analysis has been carried out by using Fourier transform and Green's function approach. The phase velocity has been investigated for several particular situations. It has been shown that the results of the study agree with those the case of Love wave propagation in a homogeneous medium in the absence of the sandy layer, when the initial stress is absent. In order to illustrate the validity of the analysis presented here, the derived analytical expression has been computed numerically, by considering an illustrative example and the variances of the concerned physical variables have been presented graphically. It is observed that the velocity of shear wave is amply influenced by the initial stress and heterogeneity parameters and the presence of the sandy layer. The study has an important bearing on investigations of different problems in the earth's interior and also in seismological studies.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.6 no.2
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• pp.93-101
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• 1986

The behavior of a plane buoyant jet discharged vertically upward into a stagnant uniform environment is analyzed by continuity, momentum transport equation by numerical scheme. The governing equations are solved by finite difference method employing stream function and vorticity transport and Prandtl's turbulent model. Results for centerline velocities and temperatures, temperature distribution and flow pattern in receiving environment due to buoyant jet in the range of discharge densimetric Froude number of 4 to 32 show good agreement with published data. Spreading rate and dispersion ratio, which are required in integral type analysis of whole range of buoyant jet and have not been obtained yet, are derived in terms of discharge densimetric Froude number and vertical distance from source.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.10 no.4
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• pp.237-246
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• 2012

In this study, numerical model for transport of radionuclide and colloid was developed. In order to solve reaction-migration governing equation for colloid and radionuclide, Strang-splitting Sequential Non-Iterative (SNI), which is one of Operator Splitting Method, was used for numerical method and this was coded by MATLAB. From the verification by comparing the simulation results with analytical solution considering only solute transport and rock diffusion, the Pearson's correlation coefficient was greater than 0.99 which demonstrates the accuracy of the model.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.17 no.2 s.119
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• pp.121-129
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• 2007

There has been much effort to find suitable methods for structural analysis in the mid-frequency region where traditional low frequency methods have increasing uncertainties whilst statistical energy analysis is not strictly applicable. Systems consisting of relatively stiff beams coupled to flexible plates have a particularly broad mid-frequency region where the beams support only a few modes whilst the plate has a high modal density and modal overlap. A system of two parallel beams coupled to a plate is investigated based on the wave method, which is an approximate method. Muller's method is utilised for obtaining complex roots of a dispersion wave equation, which does not converge in the conventional wave method based on a simple iteration. The wave model is extended from a single-beam-plate system, to a plate with two identical beams which is modelled using a symmetric-antisymmetric technique. The important hypothesis that the coupled beam wavenumber is sufficiently smaller than the plate free wavenumber is experimentally verified. Finally, experimental results such as powers and energy ratios show the validity of the analytical wave models.

• Journal of The Korean Astronomical Society
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• v.37 no.4
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• pp.249-255
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• 2004

Here we present a linear stability analysis and an MHD 2D model for the Parker-Jeans instability in the Galactic gaseous disk. The magnetic field is assumed parallel to a Galactic spiral arm, and the gaseous disk is modelled as a multi-component, magnetized, and isothermal gas layer. The model employs the observed vertical stratifications for the gas density and the gravitational acceleration in the Solar neighborhood, and the self-gravity of the gas is also included. By solving Poisson's equation for the gas density stratification, we determine the vertical acceleration due to self-gravity as a function of z. Subtracting it from the observed gravitational acceleration, we separate the total acceleration into self and external gravities. The linear stability analysis provides the corresponding dispersion relations. The time and length scales of the fastest growing mode of the Parker-Jeans instability are about 40 Myr and 3.3 kpc, respectively. In order to confirm the linear stability analysis, we have performed two-dimensional MHD simulations. These show that the Parker-Jeans instability under the self and external gravities evolves into a quasi-equilibrium state, creating condensations on the northern and southern sides of the plane, in an alternate manner.

• Macromolecular Research
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• v.17 no.6
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• pp.388-396
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• 2009

The surface properties (water sorption and repellency, adhesion) are closely related to the surface tension of polymer solids. The critical surface tension (${\gamma}_c$) and surface tension (${\gamma}_s$) of a polymer solid were estimated by the contact angle method by our quantitative imaging system. BPDA (3,3',4,4'-biphenyl tetracarboxylic dianhydride)-BAPP (1,3-Bis(4-aminophenoxy) propane) polyimide was successfully synthesized. The ${\gamma}_c$ values were analyzed by a Zisman plot, a Young-$Dupr\acute{e}$-Good-Girifalco plot, and a log ($1+cos{\theta}$) vs log ${\gamma}_L$ plot. The ${\gamma}_s$ value of BPDA-BAPE polyimide was evaluated using the geometric mean equation and our multiple regression analysis. The calculated values of ${{\gamma}_s^d$ (a dispersion component), ${{\gamma}_s^p$ (a polar component), ${{\gamma}_s^h$ (a hydrogen bonding component), and ${\gamma}_s$ were 30.79, 9.32, 0.20, and 40.31 $mN{\cdot}m^{-1}$, respectively. The ${\gamma}_s$ of BPDA-BAPP polyimide containing both a methylene group and an ether group was larger than that of the polyimide containing only a methylene group.