• Title/Summary/Keyword: Dispersion Degree

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Enhanced Dispersion of Yttria Stabilized Zirconia by Mixed Dispersants Containing Carboxyl Group in Aqueous System (수성 현탁액에서 카르복실기를 포함하는 혼합 분산제에 의한 이트리아 안정화 지르코니아의 분산성 향상)

  • Kim, Soo-Hyun;Kang, Jong-Bong;Bae, Sung-Hwan
    • Korean Journal of Materials Research
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    • v.28 no.2
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    • pp.82-88
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    • 2018
  • Stable slurries of YSZ in aqueous suspension with added polymer dispersants, namely, poly-methacrylic acid ammonium salt (PMMA), poly-acrylic acid (PAA) and poly-acrylic-co-maleic acid (PAMA), were mixed with the monomolecular dispersants citric acid and oxalic acid. The dispersion properties of the suspension were investigated using PSA, viscosity, sedimentation, and FT-IR. The polymer dispersants and monomolecular dispersants were attached to the YSZ surface by the carboxylic group, as shown by the FTIR results. A stabilized aqueous suspension was obtained when the polymer dispersant and citric acid were mixed and compared to the use of citric acid alone as a dispersant agent. When the polymer dispersant and citric acid were mixed and milled through attrition milling, there was a smaller particle size compared to when the polymer dispersant alone was used as a dispersant agent. This study determined that the particle size of the mixed dispersant was affected by the properties of the monomolecular dispersant and that the stability of the suspension was affected by the polymer dispersant. However, when slurries of YSZ were mixed with oxalic acid, the particle bridging behavior was the result of the high degree of viscosity and the small sedimentation height.

AN OPTICAL FIBER FEED LITTROW-MOUNTED SPECTROMETER (광섬유 피드 리트로마운트형 분광계)

  • Bae, J.H.;Song, J.W.;Yoon, T.S.
    • Publications of The Korean Astronomical Society
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    • v.27 no.3
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    • pp.87-93
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    • 2012
  • A low-dispersion fiber feed Littrow-mounted grating spectrometer for education was designed and fabricated. The dispersion element is a reflective type blazed grating Edmundoptics NT 46-075 (spatial frequency 600 lines/mm, dimension $30mm{\times}30mm$, blazed angle 8.6 degree). The optical fiber coupler module for optical guiding from telescope to spectrometer is composed of a multi-mode FC connector - FC connector optical fiber patch cord (core/cladding diameter $50{\mu}m/125{\mu}m$) and two 1.25" throw-tube couplers. The lens for collimating and imaging is a general purpose focal length 50 mm camera lens (f/1.8). The device for optical path control is a rectangular prism (size $25mm{\times}25mm$). The imaging camera sensor is a Meade DSI Pro 2 CCD sensor (black and white, $752{\times}582$ pixels and pixel size $8.3{\mu}m{\times}8.6{\mu}m$). Softwares for data logging and analysis consist of Meade Autostar Suite, NIH imagej and Vernier Logger Pro 3. The wavelength coverage range of the spectrometer is 205 nm at central wavelength 550 nm. The wavelength resolution is 1.7 nm.

Surface modification of silica aerogel by surfactant adsorption and heat treatment methods (계면활성제 흡착 및 열처리를 이용한 실리카 에어로겔의 표면 개질)

  • Kim, Nam-Yi;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.282-289
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    • 2010
  • In preparation of silica aerogel-based hybrid coating materials, the combination of hydrophobic aerogel with organic polar binder material is shown to be very limited due to dissimilar surface property between two materials. Accordingly, the surface modification of the aerogel would be required to obtain compatibilized hybrid coating sols with homogeneous dispersion. In this study, the surface of silica aerogel particles was modified by using both surfactant adsorption and heat treatment methods. Four types of surfactants with different molecular weights and HLB values were used to examine the effect of chain length and hydrophilicity. The surface property of the modified aerogel was evaluated in terms of visible observation for aerogel dispersion in water, water contact angle measurement, and FT-IR analysis. In surface modification using surfactants, the effects of surfactant type and content, and mixing time as process parameter on the degree of hydrophilicity for the modified aerogel. In addition, the temperature condition in modification process via heat treatment was revealed to be significant factor to prepare aerogel with highly hydrophilic property.

Performance of Cement Paste Incorporating Oxidized MWCNT after Nitro-Sulfuric Acid treatment (질산 처리 후 산화된 MWCNT를 혼입한 시멘트 페이스트의 성능)

  • Tugelbayev, Aidyn;Kim, Ji-Hyun;Chung, Chul-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.243-244
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    • 2022
  • Recently, the utilization of carbon nanotubes (CNT) in cement paste has been widely investigated in terms of improving the dispersion quality and enhancing the cement paste mechanical performance. While methods of functionalizing the CNT using surfactants to disperse the nanoparticles have been studied to some extent, the literature on the effects of chemical covalent functionalization is still scarce. This work focuses on chemical functionalization of multiwall carbon nanotubes (MWCNT) using acid treatment, and a consequent addition of the modified MWCNT to the cement paste. The microstructural observation and degree of the MWCNT functionalization are examined using FE-SEM. The compressive strength is measured at an age of 28 days. The results of the study suggest that the acid-functionalized MWCNT are dispersed better compared to the pristine MWCNT due to presence of functional groups. The better dispersion of the nanotubes and the attached functional groups may contribute to the refinement of the microstructure of the cement paste and hence, increase its mechanical strength.

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Characteristics of Luminescence Signals According to the Depositional Environment (퇴적 환경에 따른 루미네선스 신호의 특성)

  • Hong, Seongchan;Choi, Kwang Hee
    • Journal of The Geomorphological Association of Korea
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    • v.28 no.2
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    • pp.59-70
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    • 2021
  • This study aims to determine the sunlight exposure according to depositional environment to improve the accuracy of optically simulated luminescence (OSL) dating. Sufficient sunlight exposure during transportation of sediment is a basic assumption of the OSL dating, and if the process does not occur enough, the results may be overestimated compared to the actual depositional age. Therefore, the main purpose of this study is to establish a correction method by determining residual or unbleachable dose after sunlight exposure in the actual deposition process, not in the laboratory measurement. Four samples from two sites were collected according to the depositional environment from rivers and coasts, and various OSL signals, including the size of residual dose, degree of dispersion between grains, and OSL signal sensitivity, were measured. As a result, it was confirmed that sediments formed under temporarily high energy environments, such as floods and surges, had relatively high residual dose or large dispersion of residual dose between particles. In further studies, the OSL signal characteristics of river sediments by flow velocity will be identified and the relationship between energy and OSL signal characteristics will be identified in more detail. Moreover, a method of reconstructing the paleo-environment at the time of deposition for existing sediments will be devised. It is expected to provide important information for the frequency of disaster recurrence and prediction of future climate change.

"Cohesiveness of Hyaluronic Acid Fillers": Evaluation Using Multiple Cohesion Tests

  • Kyun Tae Kim;Won Lee;Eun-Jung Yang
    • Archives of Plastic Surgery
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    • v.51 no.1
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    • pp.14-19
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    • 2024
  • Background Hyaluronic acid fillers can be manufactured using various processes. They have multiple properties, including their concentration, degree of modification, and rheological data. Cohesion is one such property to evaluate gel integrity; however, there is no standardized method for calculating this parameter. This study aimed to evaluate different tests for calculating hyaluronic acid cohesion and discuss the importance of hyaluronic acid cohesion as a consideration when selecting fillers. Methods The cohesion levels of five different hyaluronic acid fillers with different rheological properties were evaluated and compared using the drop weight, compression, tack, and dispersion time tests. Results The cohesion tests yielded different results in the samples. Samples 2 and 4 showed approximately two times the number of droplets when compared with Sample 5 in drop weight test. Samples 1, 2, 3, and 4 were superior to Sample 5 in tack test. Samples 1, 2, and 3 showed cohesive appearances at 95 seconds in most cases in dispersion test. Rheological test results did not reflect the measures of cohesion. Conclusion Although there are no definite standardized tests to evaluate the cohesion of hyaluronic acid fillers, our proposed tests showed similar results for different hyaluronic acid filler products. Further studies are needed to evaluate the cohesion of hyaluronic acid fillers and determine the clinical use of this distinguishing characteristic for clinicians selecting the product of choice. Level of evidence statement: These data are Level IV evidence.

Electrical Properties of Supercapacitor Based on Dispersion Controlled Graphene Oxide According to the Change of Solution State by Washing Process (Washing을 통한 상분리 변화에 따른 그래핀 산화물의 분산도 조절 및 슈퍼커패시터의 특성에 관한 연구)

  • Sul, Ji-Hwan;You, In-kyu;Kang, Seok Hun;Kim, Bit-Na;Kim, In Gyoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.102-106
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    • 2018
  • Recently, there has been an increasing interest in the use of graphene as electrode materials for supercapacitors. In this regard, graphene oxide (GO) films were prepared using GO slurry obtained by dispersing GO powder in deionized (DI) water. The degree of dispersion of GO powder in DI water depends on the concentration of GO slurry, pH, impurity content, GO particle size, types of functional groups contained in GO, and manufacturing method of GO powder. In this study, the dispersivity of the GO powder was improved by adjusting the pH using only DI water (without additives), and a uniform GO film was obtained. The GO film was reduced by exposure to xenon intense pulsed light for a few milliseconds, and the reduced GO film was used as electrodes of a supercapacitor. The supercapacitor was characterized using cyclic voltammetry (CV), charge-discharge cycle, and electrochemical impedance spectroscopy measurements, and the specific capacitance of the supercapacitor was found to be ~140 F/g from the CV data.

Environmental Effects on the Hydrologic and Ecologic System around the Wasted Ore Dump of the Moak Gold-Silver Mine (모악 금·은광산에 방치된 폐석이 주변 수계 및 생태계에 미치는 환경적 영향)

  • Na, Choon-Ki;Jeon, Seo-Ryeong
    • Economic and Environmental Geology
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    • v.28 no.3
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    • pp.221-229
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    • 1995
  • The heavy metal contents and their dispersion patterns in stream water, stream sediments, land plants and aquatic larvae collected from the hydrologic system flowing via the wasted ore dump of the Moak Au-Ag mine were investigated systematically in order to evaluate the environmental impacts of the abandoned metal mine. The heavy metal content increases abruptly in the vicinity of the wasted ore dump, then attenuated with increasing distance from the mine area. Attenuating rates were stream water > stream sediments > land plants > aquatic larvae. On the other hand, the cumulative content of heavy metals was stream sediments >aquatic larvae > land plants > stream water. Each element tends to be enriched selectively according to media; Zn > Cu > Cd > Pb in stream water, Zn > Pb > Cu > Cd in stream sediments and land plants, and Zn > Cu > Pb > Cd in aquatic larvae. These results show that the degree of enrichment and dispersion of pollutant extruded from the wasted ore dump are different according to elements and media, and that the circulation system of materials of each medium is different. The heavy metals, especially Cu, Pb and Zn, of polluted downstream sediments occur in high proportions of Fe-Mn oxides and organic bounded forms, which show high potential of a secondary pollution source. The content of heavy metals and their dispersion patterns in stream sediments are different from those of ten years ago; pollution levels of heavy metals were degraded in various ranges. The Zn and Cu-polluted areas were widened whereas Fe and Pb-polluted areas were reduced. In crops collected from the farm lands in downstream area, the pepper was more concentrated in all heavy metal than rice. The pepper showed some contaminated level in Cu(9.7ppm) and Zn(149ppm), and the rice in Zn(90ppm). However, both crops showed no significant level in Cd(<0.2ppm) and Pb(<0.5ppm).

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Dispersion and property evaluation of nanocomposites by aspect ratio of MWCNT (다중벽 탄소나노튜브 형상비에 따른 나노복합재료 분산 및 물성 평가)

  • Jang, Jung-Hoon;Yi, Jin-Woo;Lee, Won-Oh;Lee, Hak-Gu;Um, Moon-Kwang;Kim, Jin-Bong;Byun, Joon-Hyung
    • Composites Research
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    • v.23 no.3
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    • pp.58-63
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    • 2010
  • Tensile and flexural properties and electrical conductivity of MWCNT/epoxy composites with different aspect ratios of MWCNTs were compared. The MWCNT/epoxy mixtures were prepared by mechanical dispersion methods using a homomixer and a three-roll mill, and then composite samples were fabricated by compression molding process. The fractured surfaces of the samples were observed by SEM in order to evaluate the degree of dispersion of MWCNTs. The addition of MWCNTs into epoxy resin improved its tensile strength by 7.0% while its flexural strength increased slightly as compared with the one without MWCNTs. In the case of MWCNTs having highest aspect ratio, the mechanical properties of the composites were decreased. When the contents of CM-95 MWCNTs were varied, maximum of tensile and flexural strengths occurred at 1wt% and 0.5wt%, respectively. From the higher contents than these, tensile and flexural strengths of the composites decreased. Electrical conductivities of in-plane and thought-the-thickness directions of MWCNT/epoxy composites were measured using a two-point probe method. They increased with the increase of the aspect ratios and concentrations of MWCNTs in the epoxy matrix.

Spray Characteristics on Impingement Angle Variation and Mixture ratio of Impinging Injectors (충돌각과 혼합비 변화에 따른 충돌형 분사기의 분무특성에 관한 연구)

  • Gang, Sin Jae;Song, Beom Geun;Song, Gi Jeong;Lee, Jeong Gyu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.5
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    • pp.72-79
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    • 2003
  • Spray characteristics were investigated by impinging F-O-O-F type injector with varying the impingement angle through 15, 20 and 30 degree and the mixture ratio(O/F ratio) from 1.5 to 3.0. Experimental results show that the correlation between dispersion and impingement angle is not influenced of the mixture ratio variation, but which has influence on number density, and there is a linear correlation between dispersion and impingement angle. Velocity distribution, standard deviation and SMD of droplets are decreased as the impingement angle increases. Also, it was confirmed that the distribution of droplet size are in accordance with Rosin-Rammler and Upper-limit distribution.