• Elastomers and Composites
• /
• v.53 no.3
• /
• pp.109-123
• /
• 2018

The effect of the silica content on the state and properties of silica-filled styrene-butadiene rubber/butadiene rubber (SBR/BR) compounds containing coupling and dispersion agents was evaluated by varying the content of silica from 50 to 120 phr. Bis-[(triethoxysilyl)propyl] tetrasulfide (TESPT) and zinc 2-ethylhexanoate (ZEH) were used as the coupling and dispersion agents, respectively. The maximum silica content in the pristine material was 80 phr, which increased to 120 phr upon the addition of TESPT and ZEH. The incorporation of TESPT considerably improved most of the rubber properties due to its coupling action and the suppression of silica flocculation, while further addition of ZEH resulted in additional improvements. The properties of the rubber compounds with different silica contents can be fully explained either by an enhancement of the rubber-silica interactions or by their deterioration due to an excessive amount of silica aggregates.

• Elastomers and Composites
• /
• v.48 no.2
• /
• pp.114-124
• /
• 2013

To study the effects of structural difference and fatty acid chain length of glyceride, new dispersion agents having various glyceride structures such as mono-, di-, and tri-, were prepared using glycerol extracted from palm oil and fatty acid having various chain length ranges from 12 to 18. These dispersion agents were mixed with the rubber compounds and compared with conventional metal salt dispersion agents. Glyceride dispersion agent provided remarkable improvement in silica dispersion, compared to metal salt fatty acidic one, even though the viscosity of mixtures was relatively high due to low lubricating effect, and this was approved by mechanical properties, wear properties, and Payne effect. Also, the longer in chain length of fatty acid and the smaller in numbers of fatty acid, the dispersity of silica was improved.

• ETRI Journal
• /
• v.43 no.6
• /
• pp.1004-1012
• /
• 2021

The collaboration productively interacting between multi-agents has become an emerging issue in real-world applications. In reinforcement learning, multi-agent environments present challenges beyond tractable issues in single-agent settings. This collaborative environment has the following highly complex attributes: sparse rewards for task completion, limited communications between each other, and only partial observations. In particular, adjustments in an agent's action policy result in a nonstationary environment from the other agent's perspective, which causes high variance in the learned policies and prevents the direct use of reinforcement learning approaches. Unexpected social loafing caused by high dispersion makes it difficult for all agents to succeed in collaborative tasks. Therefore, we address a paradox caused by the social loafing to significantly reduce total returns after a certain timestep of multi-agent reinforcement learning. We further demonstrate that the collaborative paradox in multi-agent environments can be avoided by our proposed effective early stop method leveraging a metric for social loafing.

• Journal of Pharmaceutical Investigation
• /
• v.27 no.4
• /
• pp.295-301
• /
• 1997

Nitrendipine, a slightly soluble calcium channel blocking agent forms a solid dispersion system with $hydroxypropyl-{\beta}-cyclodextrin$, which exhibits better dissolution characteristics than the uncomplexed drug. The dissolution rate of nitrendipine was markedly increased in solid dispersion system in pharmacopeial disintegration media at pH 1.2 and pH 6.8. Four different dosage forms of nitrendipine were administered to rats: (a) nitrendipine in the solution of PEG 400; (b) nitrendipine solid dispersion system with $hydroxypropyl-{\beta}-cyclodextrin$ in a molar ratio of 1:2 by solvent evaporation method and administered in capsule form; (c) physical mixture of nitrendipine with $hydroxypropyl-{\beta}-cyclodextrin$ in a molar ratio of 1:2 and administered in capsule form; (d) nitrendipine alone administered in capsule form. Relative bioavailability after the oral administration of various dosage forms to rats with a dose of 10 mg/kg equivalent to nitrendipine was compared with that of nitrendipine in the solution of PEG 400. The AUC of solid dispersion was significantly bigger than that of nitrendipine powder. $T_{max}$ of solid dispersion was significantly shorter and $C_{max}$ was higher than that of nitrendipine powder. These results indicate that the bioavailability of nitrendipine could be improved markedly by inclusion complexation. An interesting correlation also appears to exist between the in vitro dissolution data and the area under the plasma concentration-time curves.

• Journal of Pharmaceutical Investigation
• /
• v.40 no.3
• /
• pp.181-185
• /
• 2010

The objective of this study was to improve the extent of drug release as well as the dissolution rate of TD49, a novel algicidal agent, via the preparation of solid dispersion (SD). Among the various carriers tested, $Solutol^{(R)}$ HS15 was most effective to enhance the solubility of TD49. Subsequently, SDs of TD49 were prepared by using $Solutol^{(R)}$ HS15 and their solubility, dissolution characteristics and drug crystallinity were examined at various drug-carrier ratios. Solubili ty of TD49 was increased significantly in accordance with increasing the ratio of $Solutol^{(R)}$ HS15 in SDs. Compared to untreated powders and physical mixtures (PMs), SDs facilitated the faster and greater extent of drug release in water. Particularly, SD having the drug-carrier ratio of 1:20 exhibited approximately 90% of drug release within 1 hr. Differential scanning calorimetry (DSC) thermograms and X-ray diffraction (XRD) patterns suggested that SDs might enhance the dissolution of TD49 by changing the drug crystallinity to an amorphous form in addition to the increased solubilization of drug in the presence of $Solutol^{(R)}$ HS15. In conclusion, SD using $Solutol^{(R)}$ HS15 appeared to be effective to improve the extent of drug release and the dissolution rate of poorly water soluble TD49.

• Corrosion Science and Technology
• /
• v.14 no.5
• /
• pp.207-212
• /
• 2015

The purpose of this research was to synthesize fluorine modified waterborne polyurethane dispersion (F-WPU) by soap-free (internal emulsifier) emulsion polymerization techniques, to prepare coating solution based on fluorine modified waterborne polyurethane dispersion (F-WPU) and to compare the chemical and thermo-mechanical properties on the electrogalvanized steel sheet. Environmentally friendly F-WPU was prepared with a fluorinated polyol containing 60 wt% of fluorine. There are various ways of combining a wide variety of fluorinated polyols and diisocyanate to exhibit novel properties of waterborne polyurethane dispersion. Components of coating solution were largely divided into 4 kinds i.e., F-WPU, acrylic emulsion, silane coupling agent, and colloidal silicate. F-WPU coating solution on the electro-galvanized steel sheet showed excellent properties of corrosion resistance, alkali resistance and heat resistance, as compared to other coating solutions using a general waterborne resin. The F-WPU coating solution's reliable effects are possibly due to the fluorine atoms incorporated even in a small amount of F-WPU.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.10a
• /
• pp.749-754
• /
• 2002

In this study, it is investigate to influence on tile dispersion of fiber and the flowability of matrix of type and amount of superplasticizer, velocity agent, mineral admixture and steel fiber to improve for construction performance of steel fiber reinforced cementitious composites. As for the test results, it was found that the dispersion of fiber and the flowability of matrix in steel fiber reinforced cementitious composites can improve by using of properly amount and combination of superplasticizer, velocity agent, mineral admixture. Furthermore, It show that the aspect ratio of steel fiber affect the construction performance of fiber reinforced cementitious composites, and the improvement for construction performance is the more effective the smaller aspect ration of steel fiber.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.61 no.10
• /
• pp.1454-1460
• /
• 2012

In order to develop an new electric insulation material for heavy electric equipments, epoxy/micro/nano composite (EMNC) was prepared by mixing micro-silica with nano layered silicate, where the nano layered silicate was synthesized by our electric field dispersion method, EMNSC was prepared by treating the EMNC with a silane coupling agent. Thermal properties such as glass transition temperature (Tg) and thermal expansion coefficient, and DMA characteristics were studied, and mechanicla properties such as tensile and flexural tests were performed. AC electrical insulation strength was also tested. All properties of EMNSC were modified by treating EMNC with silane coupling agent and it was confirmed that our new developed composites could be used in the heavy electric equipments.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.04a
• /
• pp.457-462
• /
• 1999

The purpose of this study is to design the requirements for the materials of stabilizing slurry and to determine the optimum slruuy mix design used in the underground wall of Inchon LNG #213 and 214 tank. After the materials and mix conditions of stabilizing slurry investigated and tested, we propose materials and optimum mix design according to testing items including funnel viscosity, we propose materials and optimum mix design according to testing items including funnel viscosity, fluid loss, cake thickness and specific gravity. As this results, we select optimum mix design that the upper limit ratio of bentonite is 2.0%, polymer is 0.1% considering the funnel viscosity and dispersion agent is 0.05% considering the fluid loss. Also we select all materials which are composed of GTC4 as bentonite, KSTP as polymer and Bentocryl as dispersion agent. All test results are satisfied our specifications for stabilizing slurry.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.19 no.2
• /
• pp.55-62
• /
• 2020

In this study, a PDMS-based low-elasticity magnetorheological elastomer (MRE) was fabricated and the Taguchi method was used to identify the factors affecting the elastic modulus. The mixing entropy was calculated using optical microscopy to confirm particle dispersion, which was referenced in the process establishment. In the MRE process, four parameters, namely the curing agent, particle type, particle fraction, and applied magnetic field, were divided into three levels. The elastic modulus of the specimen was compared at the off-state and at 0.2 T using compression tests, and the obtained signal to noise ratio indicated that the softness and change in the elastic modulus of the MRE was mainly affected by the curing agent and the particle fraction.