• Corrosion Science and Technology
• /
• v.21 no.6
• /
• pp.514-524
• /
• 2022

Carbon emissions from fuel consumption have been pointed by scientists as the cause of global warming. In particular, fossil fuels are known to emit more carbon when burned than other types of fuels. In this regard, International Maritime Organization has announced a regulation plan to reduce carbon dioxide emissions. Therefore, recently, Liquefied Natural Gas propulsion ships are responding to such carbon reduction regulation. However, from a long-term perspective, it is necessary to use carbon-free fuels such as hydrogen and ammonia. Nitrogen oxides might be generated during ammonia combustion. There is a possibility that incompletely burned ammonia is discharged. Therefore, rather than being used as a direct fuel, Ammonia is only used to reduce NO_X such as urea solution in diesel vehicle Selective Catalyst Reduction. Currently, LPG vehicle fuel feed system studies have evaluated the durability of combustion injectors and fuel tanks in ammonia environment. However, few studies have been conducted to apply ammonia as a ship fuel. Therefore, this study aims to evaluate corrosion damage that might occur when ammonia is used as a propulsion fuel on ships.

• Journal of Wellbeing Management and Applied Psychology
• /
• v.6 no.3
• /
• pp.19-23
• /
• 2023

Purpose: High concentrations of nitrogen exist in food wastewater, and when nitrogen is not properly treated and discharged, it can cause eutrophication in the aquatic ecosystem. Research design, data and methodology: In order to remove nitrogen using sodium hypochlorite, the BNCR tank was designed and installed in the step behind the biological treatment tank, and the data of pH, TOC, and T-N were collected after about a month of demonstration. Results: As a result of operating the BNCR tank, total nitrogen decreased by about 83% on average. The total nitrogen in the second sedimentation tank before going through the BNCR tank must be removed and finally discharged after nitrogen is removed above the legal standard of 60 mg/L. Conclusions: If BNCR tank is added to the process currently applied to nitrogen removal and operated, ammonia nitrogen can be removed more efficiently. However, the disadvantage is that nitric acid nitrogen and nitric acid nitrogen cannot be removed. If these disadvantages are supplemented and optimized in the future, it will be helpful for workplaces that are having difficulty removing nitrogen.

• Journal of Korean Society for Atmospheric Environment
• /
• v.22 no.5
• /
• pp.701-711
• /
• 2006

Sewage treatment plants located near to large cities emit extremely higher concentration of odorous materials. This study evaluated flux profiles of ammonia emitted from the water surface of sewage treatment plants using a dynamic flux chamber. Also, an ammonia overall mass transfer coefficient and a mass transfer model was developed in order to estimate fluxes of ammonia using environment parameters and the flux from the sewage treatment plants. The developed mass transfer model was evaluated through a fitness analysis. Comparison modeled flux applying empirical overall mass transfer coefficients of ammonia and measured ammonia flux show a high linearity with 0.977. The flux ratio of 1.282 demonstrated highly statistical fitness, also. Modeled flux using the mass transfer model was compared with measured flux. In result, it indicated that empirical overall mass transfer coefficients were similar to measured flux. The mass transfer model using the empirical overall mass transfer coefficient developed in this study was proved to be an easy and effective method to make accurate and precise predictions for ammonia flux discharged from sewage treatment plants.

• Journal of Korean Society of Water and Wastewater
• /
• v.36 no.2
• /
• pp.81-95
• /
• 2022

The present study was performed to investigate the effects of NH₃-N and nitrifying microorganisms on the increased BOD of downstream of the Yeongsan river in Gwangju. Water samples were collected periodically from the 13 sampling sites of rivers from April to October 2021 to monitor water qualities. In addition, the trends of nitrogenous biochemical oxygen demand (NBOD) and microbial clusters were analyzed by adding different NH₃-N concentrations to the water samples. The monitoring results showed that NH₃-N concentration in the Yeongsan river was 22 times increased after the inflow of discharged water from the Gwangju 1st public sewage treatment plant (G-1-PSTP). Increased NH₃-N elevated NBOD levels through the nitrification process in the river, consequently, it would attribute to the increase of BOD in the Yeongsan river. Meanwhile, there was no proportional relation between NBOD and NH₃-N concentrations. However, there was a significant difference in NBOD occurrence by sampling sites. Specifically, when 5 mg/L NH₃-N was added, NBOD of the river sample showed 2-4 times higher values after the inflow of discharged water from G-1-PSTP. Therefore, it could be thought other factors such as microorganisms influence the elevated NBOD levels. Through next-generation sequencing analysis, nitrifying microorganisms such as Nitrosomonas, Nitroga, and Nitrospira (Genus) were detected in rivers samples, especially, the proportion of them was the highest in river samples after the inflow of discharged water from G-1-PSTP. These results indicated the effects of nitrifying microorganisms and NH₃-N concentrations as important limiting factors on the increased NBOD levels in the rivers. Taken together, comprehensive strategies are needed not only to reduce the NH₃-N concentration of discharged water but also to control discharged nitrifying microorganisms to effectively reduce the NBOD levels in the downstream of the Yeongsan river where discharged water from G-1-PSTP flows.

• Transactions of the Korean hydrogen and new energy society
• /
• v.34 no.6
• /
• pp.594-600
• /
• 2023

In this study, a process model and optimization design direction for a hydrogen production plant through ammonia decomposition are presented. If the reactor decomposition rate is designed to approach 100%, the amount of catalyst increases and the devices that make up the entire system also have a large design capacity. However, if the characteristics of the hydrogen regeneration process are reflected in the design of the reactor, it becomes possible to satisfy the total flow rate of fuel gas with the discharged tail gas flow rate. Analyzing the plant process simulation results, it was confirmed that when an appropriate decomposition rate is maintained in the reactor, the phenomenon of excess or shortage of fuel gas disappears. In addition, it became possible to reduce the amount of catalyst required and design the optimized capacity of the relevant processes.

• Journal of the Korean Institute of Gas
• /
• v.26 no.5
• /
• pp.22-27
• /
• 2022

Atomic Layer Deposition (ALD) is a facility that deposits an atomic layer on a wafer by causing a chemical reaction after decomposition using heat or plasma by inputting two or more gases during the semiconductor process. The main gas used at this time is NH₃ (Ammonia). NH₃ has a relatively narrow explosive range with an upper limit (UFL) of 33.6% and a lower limit (LEL) of 15%, but it can explode if a large amount suddenly gathers in one place. It is Velocity and fatal if inhaled or in contact with the skin. NH₃ (Ammonia) of ALD (Atomic Layer Deposition) facility is supplied to the chamber through the gas inlet and discharged after the reaction.

• Journal of Korean Society on Water Environment
• /
• v.31 no.4
• /
• pp.377-386
• /
• 2015

The purpose of this research was to suggest the water quality improvement in streams by evaluating the distribution characteristics of organics and ammonia nitrogen discharged by pollution sources from human living. The public sewage treatment plants'(PSTPs) effluents and the waters from streams in Gyeonggi-do were sampled and analyzed. Nitrogenous oxygen demand (NOD) was measured for the stream waters as well as the PSTPs effluents, and the correlations of NOD and $NH_3$-N, $NH_3$-N and water temperature in the PSTPs effluents were confirmed. In the case of the stream waters, the ratios of NOD to BOD and $NH_3$-N increased in the downstream sites after discharging the PSTPs effluents. As a result of statistical analysis of $NH_3$-N concentrations for the national water quality monitoring streams in Gyeonggi-do, $NH_3$-N showed the non-normal distribution which were biased to the left, but showed the considerable level because of higher coefficient of variation. Therefore, it is required to establish the water quality standard for the $NH_3$-N as a new parameter for judging the quality of the streams. In addition, inducing complete nitrification and introducing a logical standard setting system are needed to improve the water quality of streams by identifying distribution of the nitrogen components from PSTPs effluents.

• Journal of Animal Environmental Science
• /
• v.13 no.3
• /
• pp.187-194
• /
• 2007

Six pig farms were surveyed to measure the odor concentrations and characteristics of ammonia and sulfide corollary compounds in piggery. They were depended on the scale of piggery, weather conditions such as temperature, humidity, wind speed and direction, scales and types of pig breeding, and manure treatment methods. The highest ammonia concentrations in piggery were measured during the winter, since the tight sealed insulation in piggery made less amount of generated ammonia discharged from piggery. The objective of this study was to measure concentrations of odor in the piggery by season and growing, and to measure concentrations of odor at boundary area. So, we investigated the raising managements, manure managements, and methods of reducing odor according to farm scale. We found that concentration of ammonia gas in the swine fattening piggery in winter was the highest. This result is consistent with the lower ventilation rate to maintain Indoor temperature. In this result, there was no connection between farm scale and ventilating system. Concentration of ammonia gas was 1.64 ppm at one boundary area in the middle scale. $H_2S$, $CH_3SH$, $(CH_3)_2S$, and $(CH_3)_2S_2$ were below the standard of protection odor policy.

• KSBB Journal
• /
• v.14 no.3
• /
• pp.328-336
• /
• 1999

A green microalga, Chlorella vulgaris UTX 259, was cultivated in a bench-scale raceway pond. During the culture, 15%(v/v) $CO_2$ was supplied and industrial wastewater discharged from a steel-making plant was used as a culture medium. In a small scale culture bottle, the microalga grew up to 1.8 g $dm^{-3}$ of cell concentration and ammonia was completely removed from the wastewater with an yield coefficient of 25.7 g dry cell weight $g^{-1}\;NH_3-N$. During the bottle-culture, microalga was dominant over heterotrophic microorganisms in the culture medium. Therefore, the amount of carbon dioxide fixation could be estimated from the change of dry cell weight. In a semi-continuous operation of raceway pond with intermittent lighting (12 h light and 12 h dark), increase of dilution rate resulted in increase of the ammonia removal rate as well as the $CO_2$ fixation rate but the ammonia removal efficiency decreased. Ammonia was not completely removed from the medium (wastewater) of raceway pond which was operated in a batch mode under a light intensity up to 20 klux. The incomplete removal of ammonia was believed due to insufficient light supply. A mathematical model, capable of predicting experimental data, was developed in order to simulate the performance of the raceway pond under the light intensity of sun during a bright daytime. Simulation results showed that the rates of $CO_2$ fixation and ammonia removal could be enhanced by increasing light intensity. According to the simulation, 80 mg $dm^{-3}$ of ammonia in the medium could be completely removed if the light intensity was over 60 klux with a continuous lighting. Under the optimal operating condition determined by the simulation, the rates of carbon dioxide fixation and ammonia removal in the outdoor operation of raceway pond were estimated as high as $24.7 g m^{-2} day^{-1}$ and $0.52 g NH_3-N m^{-2} day^{-1}$, respectively.

• Clean Technology
• /
• v.28 no.2
• /
• pp.131-137
• /
• 2022

The semiconductor process currently emits various by-products and unused gases. Emissions containing pollutants are generally classified into categories such as organic, acid, alkali, thermal, and cabinet exhaust. They are discharged after treatment in an atmospheric prevention facility suitable for each exhaust type. The main components of organic exhaust are volatile organic compounds (VOC), which is a generic term for oxygen-containing hydrocarbons, sulfur-containing hydrocarbons, and volatile hydrocarbons, while the main components of alkali exhaust include ammonia and tetramethylammonium hydroxide. The purpose of this study was to determine the combustion characteristics and analyze the NO_X reduction rate by maintaining a direct combustion and temperature to process organic and alkaline exhaust gases simultaneously. Acetone, isopropyl alcohol (IPA), and propylene glycol methyl ether acetate (PGMEA) were used as VOCs and ammonia was used as an alkali exhaust material. Independent and VOC-ammonia mixture combustion tests were conducted for each material. The combustion tests for the VOCs confirmed that complete combustion occurred at an equivalence ratio of 1.4. In the ammonia combustion test, the NO_X concentration decreased at a lower equivalence ratio. In the co-combustion of VOC and ammonia, NO was dominant in the NO_X emission while NO₂ was detected at approximately 10 ppm. Overall, the concentration of nitrogen oxide decreased due to the activation of the oxidation reaction as the reaction temperature increased. On the other hand, the concentration of carbon dioxide increased. Flameless combustion with an electric heat source achieved successful combustion of VOC and ammonia. This technology is expected to have advantages in cost and compactness compared to existing organic and alkaline treatment systems applied separately.