• 제목/요약/키워드: Discharge Mechanism

검색결과 337건 처리시간 0.025초

Mechanism of Tungsten Recovery from Spent Cemented Carbide by Molten Salt Electrodeposition

  • Hongxuan Xing;Zhen Li;Enrui Feng;Xiaomin Wang;Hongguang Kang;Yiyong Wang;Hui Jin;Jidong Li
    • Journal of Electrochemical Science and Technology
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    • 제14권1호
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    • pp.75-84
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    • 2023
  • The accumulation of spent carbide (YG8), not only pollutes the environment but also causes waste of tungsten, cobalt and other rare metal resources. To better address this issue, we proposed a combined electrochemical separation process of low-temperature aqueous solution and high-temperature molten salt for tungsten and cobalt. H2WO4 was obtained from spent carbide in an aqueous solution, and we calcined it to obtain WO3, which was used as a raw material to obtain tungsten by using molten salt electrodeposition. The influence of the current efficiency and the electrochemical behavior of the discharge precipitation of W(VI) were also studied. The calcination results showed that the morphology of WO3 was regular and there were no other impurities. The maximum current efficiency of 82.91% was achieved in a series of electrodeposition experiments. According to XRD and SEM analysis, the recovered product was high purity tungsten, which belongs to the simple cubic crystal system. In the W(VI) reduction mechanism experiments, the electrochemical process of W(VI) in NaCl-Na2WO4-WO3 molten salt was investigated using linear scanning voltammetry (LSV) and chronoamperometry in a three-electrode system. The LSV showed that W(VI) was reduced at the cathode in two steps and the electrode reaction was controlled by diffusion. The fitting results of chronoamperometry showed that the nucleation mechanism of W(VI) was an instantaneous nucleation mode, and the diffusion coefficient was 7.379×10-10 cm2·s-1.

인간활동으로 인한 부유토양유출의 환경변화 (Environmental Change of Suspended Sediment Discharge by Human Action)

  • 박종관
    • 한국환경과학회지
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    • 제2권2호
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    • pp.153-160
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    • 1993
  • 산지유역에서 토사공급과 이동에 관한 문제는 동적지형학뿐만 아니 수문학적 순환의 입장에서 매우 중요하다. 토사유출 자연의 개변정도등 지형학적 요인에 크게 지배된다. 본 연구에서는 강우시 자연의 개변정도가 서로 다른 유역에서 유출되는 부류토량을 비교하여 부류토사 유출과정과 메타니즘을 알아 보았다. 강우강도가 유사한 30mm의 비가 내렸을때 채석장이 분포하고 있는 인공개변유역의 부유토사농도는 최고 27,000mg/l인 반면, 백연유역의 부유토사농도는 270mg/l에 불과해 100배 정도의 농도차이가 나타났다. 또 인공개역중에서도 인공개변도에 따라 최대부유토사양도 6,400mg/l에서 27,000mg/l까지 다양하게 관측되었다. 일반적으로 부유토사 공급원은 자연유역의 경우 하상, 하안, 그리고 하도주변하도입이며, 인공개변유역은 사면등의 하도외 지역이다.

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낙동강 하구 지형변화 예측 및 외력조건에 따른 기여도 분석 (Prediction of Topographic Change in the Estuary of Nakdong River and Analysis of Its Contribution by External Force Condition)

  • 김강민;이중우
    • 한국항해항만학회지
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    • 제43권1호
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    • pp.64-71
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    • 2019
  • 낙동강 하구의 지형변화 메커니즘을 파악하는 것은 하구의 관리방안과 처리방법 연구에 매우 중요하다. 본 연구에서는 낙동강 하구의 지형변화에 관여하는 강우, 하천유량, 유사량과 같은 육역으로부터 영향과 조석, 조류, 파랑, 표층퇴적물 등과 같은 해역으로부터의 영향을 조사 분석하였다. 분석된 자료에 근거하여 지형변화 실험을 수행하고, 지형변화와 외력조건별 기여도를 분석하였다. 수치실험 결과 지형변화는 하굿둑 방류 영향을 직접적으로 받는 수로부를 중심으로 침식이, 간접 영향권인 간석지를 중심으로 퇴적이 우세하게 나타났다. 수로부를 따라 이동되는 퇴적물이 파랑에 의해 분급, 배분되면서 울타리선 전면부에는 퇴적이 우세하였다. 지형변화 실험결과인 퇴적 우세현상과 비교하여, 외력조건별로 침식의 기여도가 크게 나타나고 있으나 각 외력조건의 복합적인 영향은 퇴적이 우세하게 나타나고 있다. 따라서, 낙동강 하구의 지형변화는 여러 복합적인 외력인자의 결과로 판단된다. 또한, 각 외력조건별 영향은 구역별로 상이한 기여도를 보이므로 하구관리방안 수립시 이러한 결과를 고려해야 하고, 반드시 복합적인 상호작용의 결과로 이해하고 있어야 할 것으로 사료된다.

펌프 장기손상 메커니즘 규명을 위한 진동영향 평가 (The vibration impact assessment for long-term damage mechanism of a pump)

  • 김태현;김형석;김동건;김원태;한병섭
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2009년도 추계학술대회 논문집
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    • pp.441-445
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    • 2009
  • The most of the goals of pump designers and users are efficient operation and productivity. But the safety-grade pumps in nuclear power plants are needed to operate continuously for an essential condition of system operation. Also, most of the rules and regulatory standards that have been prepared for nuclear pumps are dedicated to achieve public safety. The study examined pump vibration in a pump outlet flow and distinguished the regions of pump vibration frequency cause by cavitation and recirculation. The study made a counterproposal in determination of pump outlet flow so that the discharge flow will be able to minimize the long-term damage of the pump.

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코로나 하전한 고분자의 표면전하감쇄 (The Charge decay characteristics of Polymer surface by Corona discharge)

  • 이백수;김영봉;박종국;김진식;이진;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 하계학술대회 논문집 C
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    • pp.1156-1158
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    • 1995
  • Charge decay, thermally stimulated current(TSC), charging and discharging currents(I) are measured for negatively corona-charged polymers. In this study, we will make an experiment in charge decay on polymer surface, TSC, polarity effect and the others in order to analysis it's mechanism. Especially polyvinylidene fluoride(PVDF) film is the best functional material which has been so far. Therefore, It's worthy of notice to investigate it's characteristic. And then some other functional polymers will be focused on. An experimental result was missed out for the shortage of setting. So, this thesis will be explained on the theory and direction of reseach hereafter.

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대두유의 물리적 특성에 따른 화재감식 (Fire Identification based on Physical Properties of Bean Oil)

  • 진복권;정수일
    • 한국화재소방학회논문지
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    • 제22권3호
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    • pp.246-251
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    • 2008
  • 일반적으로 유류화재의 경우 상온 상압 하에서 그 물리적 성질과 에너지 특성이 유사한 양상을 나타내나 식용유에 의한 화재발생은 그 특성이 매우 특이하여 취급자의 무지로 인한 화재가 자주 발생하고 있다. 따라서 본 연구에서는 식용유에 대한 에너지 특성과 그 물적 성질을 고찰한 연후 실제 연소실험을 통하여 식용유에 대한 물리적 성질을 검증하였다. 뿐만 아니라 실제 화재사례를 통하여 식용유에 의한 화재원인을 감식하였고 식용유화재 방지를 위한 대응방안을 고찰하여 제시 하였다.

Structure Optimization of ESD Diodes for Input Protection of CMOS RF ICs

  • Choi, Jin-Young
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제17권3호
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    • pp.401-410
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    • 2017
  • In this work, we show that the excessive lattice heating problem due to parasitic pnp transistor action in the diode electrostatic discharge (ESD) protection device in the diode input protection circuit, which is favorably used in CMOS RF ICs, can be solved by adopting a symmetrical cathode structure. To explain how the recipe works, we construct an equivalent circuit for input human-body model (HBM) test environment of a CMOS chip equipped with the diode protection circuit, and execute mixed-mode transient simulations utilizing a 2-dimensional device simulator. We attempt an in-depth comparison study by varying device structures to suggest valuable design guidelines in designing the protection diodes connected to the $V_{DD}$ and $V_{SS}$ buses. Even though this work is based on mixed-mode simulations utilizing device and circuit simulators, the analysis given in this work clearly explain the mechanism involved, which cannot be done by measurements.

낙동강 하상토의 제방재료 활용방안 (The application levee material in the bed sediment of Nakdong River)

  • 최계운;이승우;이호선;이병주
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2006년도 학술발표회 논문집
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    • pp.1576-1580
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    • 2006
  • The destruction of river and damage caused by flood are suddenly increasing due to the abnormal climate. In the investigation result about the damage, approximate 52% of the destruction of embankment are caused by earth work. Moreover, to recover conveyance of relief channel, bed sediment is dredged about 198 millions $m^3$ with 'the project of bed dredging'. So, the concern for bed sediment is the more increasing, the requiring high quality material for banking and the way for application of bed sediment are also the more increasing. In this paper, properties of bed sediment were analyzed through sedimentary mechanism analysis. Moreover, possibility to build embankment with bed sediment in 6 points which is in catchment of the Nak-dong river was also analyzed. At 6 points, which were selected to survey easily, sediment discharge was analyzed with formula. Moreover, size and permeability were analyzed and the feasibility for material of embankment was proposed. If bed sediment wasn't proper, complementary measures were proposed.

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펄스 중첩법을 이용한 내부 보이드에서의 부분방전 특성. (Partial Discharge Characteristics at a Internal Void Using a Pulse Superimposing Technique)

  • 강지훈;신두성;황보승;한민구
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1624-1626
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    • 1997
  • In this paper, a new PD measurement technique of pulse superposition method was proposed in order to investigate both PD mechanism and phase related PD patterns. From the experimental results, we could find that the polarity and the phase angle of the superposed pulse take great effects on PD characteristics and these method make it possible to get the physical information which statistical approach can not give. We could conclude that the changes of PD characteristics in the void surrounded by polymers may be attributed to the injection of charge carriers thereby formation of space charge in the surface and/or the bulk of the polymer.

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Characteristics of Electron Beam Extraction in Large Area Electron Beam Generator

  • Woo, Sung-Hun;Lee, Hong-Sik
    • KIEE International Transactions on Electrophysics and Applications
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    • 제4C권1호
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    • pp.10-14
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    • 2004
  • A large area electron beam generator has been developed for industrial applications, for example, waste water cleaning, flue gas treatment, and food pasteurization. The operational principle is based on the emission of secondary electrons from the cathode when ions in the plasma contact the cathode, which are accelerated toward the exit window by the gradient of the electric potential. Conventional electron beam generators require an electron beam scanning mechanism because a small area thermal electron emitter is used. The electron beam of the large area electron beam generator does not need to be scanned over target material because the beam area is considerable. We have fabricated a large area electron beam generator with peak energy of 200keV, and a beam diameter of 200mm. The electron beam current has been investigated as a function of accelerating voltage and distance from the extracting window while its radial distribution in front of the extracting window has been also measured.