• 제목/요약/키워드: Direct extraction

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Constituents of Paulownia tomentosa Stem(III): The Crystal Structure of Methyl 5-Hydroxy-dinaphtho[1,2-2',3]furan-7,12-dione-6-carboxylate

  • Park, Il-Yeong;Kim, Bak-Kwang;Kim, Yang-Bae
    • Archives of Pharmacal Research
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    • 제15권1호
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    • pp.52-57
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    • 1992
  • The molecular structure of a natural compound was determined by single crystal X-ray diffraction analysis. The compound was isolated by methanol extraction and repeated chromatography from the stem of Paulownia tomentosa. Yellow prismatic crystals of the compound, which were recrystallized from tetrahydrofuran, are triclinic, with a = 7.310 (6), b = 10.753(6), c = 11.586(5) ${\AA}.\;\alpha= 93.30(6),\;\beta=105.62(10),\;\gamma=109.49(7)^\circ,\;D_x=1.514,\;D_m=1.51 g/cm^3$, space group P1 and Z = 2. The structure was solved by direct method, and refined by least-squares procedure to the final R-value of 0.032 for 1271 independent reflections $(F\le3\sigma{(F))}$. The compound is one of new furanquinone analogue. The molecule has a nearly planar conformation with an intramolecular hydrogen bond. In the crystal, the planar molecules are arranged as a prallel sheet-like pattern, and these stackings are stabilized by the O-H...O type intermolecular hydrogen bonds. The other intermolecular contacts appear to be the normal van der Waals interactions.

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Determination of Plutonium Present in Highly Radioactive Irradiated Fuel Solution by Spectrophotometric Method

  • Dhamodharan, Krishnan;Pius, Anitha
    • Nuclear Engineering and Technology
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    • 제48권3호
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    • pp.727-732
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    • 2016
  • A simple and rapid spectrophotometric method has been developed to enable the determination of plutonium concentration in an irradiated fuel solution in the presence of all fission products. An excess of ceric ammonium nitrate solution was employed to oxidize all the valence states of plutonium to +6 oxidation state. Interference due to the presence of fission products such as ruthenium and zirconium, and corrosion products such as iron in the envisaged concentration range, as in the irradiated fuel solution, was studied in the determination of plutonium concentration by the direct spectrophotometric method. The stability of plutonium in +6 oxidation state was monitored under experimental conditions as a function of time. Results obtained are reproducible, and this method is applicable to radioactive samples resulting before the solvent extraction process during the reprocessing of fast reactor spent fuel. An analysis of the concentration of plutonium shows a relative standard deviation of <1.2% in standard as well as in simulated conditions. This reflects the fast reactor fuel composition with respect to uranium, plutonium, fission products such as ruthenium and zirconium, and corrosion products such as iron.

체형의 변이 경향에 대한 연구 -우리나라 19~54세 남성을 대상으로- (A Study on the Trend of Bodytype Change -On the adult male between age 19 and 54-)

  • 김구자;이순원
    • 한국의류학회지
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    • 제20권1호
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    • pp.218-227
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    • 1996
  • The purpose of this study was performed to analyze the trend of bodytype change of adult males. Subjects were 1290 Korean adult males and their age range was from 19 to 54 year, ; old. 75 variables(66 variables from the direct anthropometric data and 9 variables from the multiplication method) in total were applied to analyze. The principal component analysis was applied to the data with orthogonal rotation after extraction of major factors. The high factor loading items extracted by factor analysis were analyzed for the trend of bodytype change by the age group respectively. The result of factor analysis indicated that the first factor was composed with about 30 items, girth, depth and width-measures in 4 age groups and was analysed as form factors. Especially, age-related change was caused by increase of waist girth, depth and width. The second factor was composed with about 23 items, length and height-measures in all age groups. Stature has a constant factor loading value in 4 groups. Front and back waist-height and the navel-height have the highest factor loading value. The third, fourth and fifth factors were composed with different variables among the age groups.

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신사복 상의제작을 위한 사이즈스팩의 분류-28세에서 35세 우리나라 남성을 대상으로- (Classification of Size Specifications for the Ready-made Jacket-from 28 years to 35 on the Korean adult male-)

  • 김구자
    • 한국의류학회지
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    • 제22권8호
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    • pp.1090-1098
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    • 1998
  • The purpose of this study was to classify size specifications of the Korean adult male for the men's ready-made garments, especially jacket and dress shirts. By the stratified sampling method, data were collected by the real anthropometric measurement and by the photo-graphic sources. Sample size was 532 subjects as the sample and their age range was from 28 to 35 years old. 66 variables from the direct anthropometric data in total were applied to analyze. ANOVA in SPSS WIN package was applied to the data and the expected frequency distribution of 10.000 men was calculated by the extraction of density function. This study was performed to classify size specifications by the control dimensions and at the same interval of KS-K. The drop values of 15, 12 and 9 have the high coverage rate of 26.00%, 24.29% and 21.06% respectively and are composed of the majority of 71.35% of the subjects. According to the drop values, size specifications and distribution of control and reference dimensions are predicted. About 52.12% of the expected frequency distribution without stature were covered by 12 size specifications.

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High Resistivity SOI RF CMOS 대칭형 인덕터 모델링을 위한 개선된 Optimization 방법 연구 (A Study on Improved Optimization Method for Modeling High Resistivity SOI RF CMOS Symmetric Inductor)

  • 안자현;이성현
    • 전자공학회논문지
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    • 제52권9호
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    • pp.21-27
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    • 2015
  • High resistivity(HR) silicon-on-insulator(SOI) RF CMOS 공정 인덕터의 모델 파라미터를 정확히 결정하기 위하여 직접추출과 simultaneous optimization을 사용한 개선된 방법을 개발하였다. 먼저, 대칭형 인덕터와 센터탭이 접지된 대칭형 인덕터 등가회로들의 Y 및 Z-파라미터 방정식 유도를 통해 일부 모델 파라미터들을 직접 추출하고, 병렬 저항과 전체 인덕턴스 방정식들로 미지 변수들을 줄여 모델링 정확도를 향상시켰다. 또한, 두 등가회로의 동일한 모델 파라미터들을 공통 변수로 두고 S-파라미터 데이터 세트를 동시에 optimization함으로써 optimization 정확도를 크게 향상시켰다.

Cellular Automaton법을 이용한 주물의 응고조직 시뮬레이션에의 적용 (Application of Solifidification Grain Structure Simulation for the Casting by Cellular Automaton Method)

  • 조인성
    • 한국주조공학회지
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    • 제21권1호
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    • pp.41-47
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    • 2001
  • 본 연구에서는 FDM법과 CA법을 결합하여 주물의 응고조직성장 예측 프로그램을 개발하였다. 새로운 농도장 분포 알고리즘을 개발하고, 이 결과를 1차원 해석해와 비교하였으며, 이를 2차원 응고조직 및 농도계산에 적용하였다. 3차원 응고조직 예측 해석연구를 통하여 복잡한 형상의 주물에 적용 하였으며, turbine blade형상의 응고조직 시뮬레이션을 통하여 인출속도가 응고조직에 미치는 영향에 대하여 조사하였고, 원하는 주조조업변수를 본 시뮬레이션에 의하여 결정할 수 있으리라 생각된다.

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Guinea Pig Heart의 관상동맥 순환기능과 Calcium Release에 있어서 Caffeine이 미치는 영향 (Effect of Caffeine on Coronary Circulation and Calcium Release in Isolated Guinea Pig Hearts)

  • 김은지
    • Journal of Nutrition and Health
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    • 제25권7호
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    • pp.597-607
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    • 1992
  • The present study examined effects of caffeine on coronary circulation myocardial oxygen me-tabolism and calcium release in isolated perfused guinea pig hearts. Intracoronary caffeine({{{{ {10 }^{-5 } }}}}∼{{{{ { 10}^{-3 } }}}}M) was employed for 10 minutes to measure coronary perfusate flow(CF) and coronary vascular sresistance(CVR) at a constant coronary perfusion pressure of 80 cmH2O Perfusate myocardial oxygen consumption(MVO2) and percent oxygen extraction(%EC2) were calcula-ted. In addition calcium contents in both perfusate samples were measured to calculate calcium release in coronary venous effluent. Caffeine significantly decreased CF and increased CVR during 10 minutes of caffeine perfusion regardless of dose of caffeine perfused exhibiting time-response. While % EO2 was significantly enhanced with caffeine MVO2 was markedly reduced. The coronary venous perfusate pH dcreased during the perfusion with caffeine. These changes were consistent with caffeine-induced metabolic acidosis. Calcium release appeared to be dose-dependent and high dose of caffeine greatly increased venous calcium release even 2 minutes after perfusion with carffeine. These finding in dicate that caffeine produced coronary vasoconst-riction with increased calcium release in isolated perfused guinea pig hearts. Additionaly this vasoconstrictor response mignt be due tin part to the direct actions of caffeine.

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Esthetic rehabilitation of single anterior edentulous space using fiber-reinforced composite

  • Kim, Hyeon;Song, Min-Ju;Shin, Su-Jung;Lee, Yoon;Park, Jeong-Won
    • Restorative Dentistry and Endodontics
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    • 제39권3호
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    • pp.220-225
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    • 2014
  • A fiber-reinforced composite (FRC) fixed prosthesis is an innovative alternative to a traditional metal restoration, as it is a conservative treatment method. This case report demonstrates a detailed procedure for restoring a missing anterior tooth with an FRC. A 44-year-old woman visited our department with an avulsed tooth that had fallen out on the previous day and was completely dry. This tooth was replanted, but it failed after one year. A semi-direct technique was used to fabricate a FRC fixed partial prosthesis for its replacement. The FRC framework and the pontic were fabricated using a duplicated cast model and nanofilled composite resin. Later on, interproximal contact, tooth shape, and shade were adjusted at chairside. This technique not only enables the clinician to replace a missing tooth immediately after extraction for minimizing esthetic problems, but it also decreases both tooth reduction and cost.

신사복 상의 설계를 위한 체형의 호칭 분류와 사이즈 스팩;36세에서 43세 우리나라 남성을 대상으로 (Designation of Bodytypes and Size Specifications for Designing of the Ready-made Jacket)

  • 김구자
    • 한국의류학회지
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    • 제23권8호
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    • pp.1240-1247
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    • 1999
  • The purpose of this study was to classify size specifications of Korean adult male for the men's ready-made garments especially jacket and dress shirts By the stratified sampling method data were collected by the real anthropometric measurement. Sample size was 263 subjects as the sample and their age range was from 36 to 43 years old 66 variables from the direct anthropometric data were applied to analyze. ANOVA is SPSSWIN 8.0 package was applied to the data and the expected frequency distribution of 10.000 men was calculated by the extraction of density function. This study was performed to classify size specificatios by the control dimensions. The drop values of 9,12 and 6 have the high coverage rate of 28.52% 23.44% respectively Obese body type ; H type HD type and HE type are composed of the majority of 55.47% of the subjects. According to the drop values size specifications and distribution of control dimensions are predicted About 69.82% of the expected frequency distribution were covered by 19 size specifications.

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기성복 제작을 위한 성인 남성의 사이즈 스팩의 분류 (Size Specifications of Korean Adult Male for the Ready-made Garments)

  • 김구자;이순원
    • 한국의류학회지
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    • 제21권7호
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    • pp.1247-1257
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    • 1997
  • The purpose of this study was to classify size specifications of Korean adult male for the men's ready·made garments, especially jacket and dress shirts. Concept of the comfort and fitness has become a major concern in the basic function of the ready-made garments. Data were collected by the real anthropometric measurement and by the photographic sources. Sample size was 1.290 subjects as the sample and their age range was from 19 to 54 pean old by the stratified sampling method. 66 variables from the direct anthropometric data in total were applied to analyze. ANOVA in SAS package was applied to the data and the expected frequency distribution of 10.000 men was calculated by the extraction of density function. Control dimensions for jacket and dress shirts has been designated by Bcorean Apparel Sizing System (KS-K). Therefore this study was performed to classify size specifications by the control dimensions and at the same interval of KS-K. The drop values of 15, 12 and 9 has the high coverage rate of 22.1%, 21.0% and 18.8% respectively and are composed of the majority of 61.9% of the subjects. According to the drop values, size specifications and distribution of control and reference dimensions are predicted. About 65.75% of the expected frequency distribution without stature were covered by 19 size specification.

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