• Bulletin of the Korean Chemical Society
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• v.28 no.1
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• pp.108-114
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• 2007

The lyotropic behaviors to form the structure of distearoylphosphatidylcholine (DSPC)-based liquid crystal (LC) hydrated by only propylene glycol (PG) without water were examined by differential scanning calorimetry (DSC), X-ray diffractions (XRD), polarized microscope (PM) and transmission electron microscope (TEM). By increasing the amount of PG instead of water, it showed the phase transition to be gradually changed from anisotropic structures to other structures more close to isotropic ones and their appearance to be changed from solid-like states to liquid-like ones with more fluidity. Below 50% w/w PG, the mixtures of DSPC and PG resulted in no direct observation of LC structure through PM because they were very close to solid-states. From 55% w/w to 90% w/w of PG, the dense lamella crystalline structures were observed through PM, and their thickness and area decreased as the content of PG increased. Measured by DSC with heating process, the main phase transition from α -lamella phase to isotropic phase appeared from 52.89 °C to 47.41 °C to show linearly decreasing behaviors because PG affects the hydrophobic region of DSPC-based lamella phase. The repeating distance of the lamella phase and the interlayer distance between bilayers were calculated with XRDs and the average number of bilayers related to the thickness in LC structure was approximately estimated by combining with TEM results. The WAXS and DSC measurements showed that all of PG molecules contributed to swelling both the lipid layer in the edge region of lamella phase close to phosphate groups and the interlayer between bilayers below 90% w/w of PG. The phase and thermal behaviors were found to depend on the amount of PG used by means of dissolving DSPC as a phospholipid and rearranging its structure. Instead of water, the inducement of PG as a polar solvent in solid-lamella phase is discussed in terms of the swelling effect of PG for DSPC-based lamella membrane.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.8
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• pp.612-620
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• 2008

New alternative refrigerants have been developed due to the ozone layer depletion and global warming. For this reason, carbon dioxide is believed to be a promising refrigerant for use in air conditioners and heat pumps. Evaporative heat transfer characteristics and pressure drop of $CO_2$ with outer diameter of 5 mm in inclined ($45^{\circ}$) smooth and micro-fin tubes have been investigated by the experiments with respect to several test conditions such as mass fluxes, heat fluxes, evaporation temperatures in this study. The inclined ($45^{\circ}$) smooth and micro-fin tubes with length of 1.44 m were installed to measure the evaporative heat transfer coefficients of $CO_2$ and heat was supplied to the refrigerant by direct heating method where the test tube was uniformly heated by electricity. The tests were conducted at mass fluxes from 212 to $656\;kg/m^2s$, heat fluxes from 15 to $60\;kW/m^2$ and evaporation temperatures from -10 to $20^{\circ}C$. The heat transfer coefficients of $CO_2$ are slightly increased with increasing mass flux, and the heat transfer characteristics in the inclined ($45^{\circ}$) tubes are enhanced about $5{\sim}10%$ compared with those in horizontal or vertical tubes.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.2
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• pp.101-108
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• 2013

This paper is presented an experimental study of flow boiling heat transfer characteristics of ammonia, and is focused on pressure gradient and heat transfer coefficient of the refrigerant flow inside horizontal small tube with inner diameter of 3.0 mm and length of 2000 mm. The direct heating method is applied for supplying heat to the refrigerant, where the test tube is uniformly heated by electric current. The local heat transfer coefficients were obtained over a heat flux range of 20 to $80kW/m^2$, a mass flux range of 50 to $500kg/m^2s$, a saturation temperature range of 0 to $10^{\circ}C$, and quality up to 1.0. The pressure drops increase with increasing mass flux and heat flux, and with decreasing saturation temperature. The heat transfer coefficients increase with increasing mass flux and saturation temperature in middle and high quality region. And the local heat transfer coefficient increase with increasing heat flux in low quality region. The heat transfer coefficient of the experimental result was compared with six existing heat transfer coefficient correlation. A new boiling heat transfer coefficient correlation based on the superposition model for ammonia in small tubes is developed average deviation of -0.17% and mean deviation of 10.85%.

• Journal of Ecology and Environment
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• v.29 no.4
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• pp.405-410
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• 2006

Landscape changes for 20 years between 1981 and 2001 in the Wangsuk stream basin located on the central Korea were investigated on the basis of physiognomic vegetation map made from the aerial photograph interpretation and field check. Changes of landscape structure were noticeable in agricultural field and forest landscape elements. Changes in the agricultural fields due to transformation of agricultural pattern into the institutional agriculture dominated landscape change, although urbanization also contributed to such change. The former change due to change of food production structure originated from socio-economic development during this period and the latter to the overpopulation of Seoul. As energy sources for heating and cooking, fertilizer, and fodder for livestock transform from plant materials to fossil fuel, manufactured one, and grain, succession of forest escaped from direct human disturbance dominated change of landscape structure in forested land. Differently from the positive landscape change in the upper area, change in the lower area deteriorated landscape quality by increasing artificial land. It was estimated that such landscape deterioration in the Wangsuk stream basin would influence water quality of the stream. In order to realize sustainable land-use against such environmental degradation, systematic environmental management based on landscape ecological perspective such as "an eco-plan for creating riparian vegetation belt," which is under preparation by Ministry of Environment, was recommended.

• Journal of the Korean Ceramic Society
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• v.53 no.5
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• pp.506-510
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• 2016

The eutectic melt of BaO-CuO flux is known to be a potential sintering aid for $Ba(Zr,Y)O_3$ (BZY) electrolyte for proton-conducting ceramic fuel cells (PCFCs). A density of BZY higher than 97% of theoretical density can be achieved via sintering at $1300^{\circ}C$ for 2 h using a flux composed of 28 mol% BaO and 72 mol% CuO. In the present study, chemical and structural evolution of BaO-CuO flux throughout the sintering process was investigated. An intermediate holding step at $1100^{\circ}C$ leads to formation of various impurity compounds such as $BaCuO_{1.977}$, $Ba_{0.92}Cu_{1.06}O_{2.28}$ and $Cu_{16}O_{14.15}$, which exhibit significantly larger unit cell volumes than the matrix. The presence of such secondary compounds with large lattice mismatch can potentially lead to mechanical failure. On the other hand, direct heating to the final sintering temperature produced CuO and $Cu_2O$ as secondary phases, whose unit cell volumes are close to that of the matrix. Therefore, the final composition of the flux is strongly affected by the thermal history, and a proper sintering schedule should be used to obtain the desired properties of the final product.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.9
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• pp.583-589
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• 2012

The various promotion countermeasures such as solidification, carbonization, and the creation of cement materials have been considered to existing treatment methods such as incineration and the creation of composts, since direct landfill was prohibited for encouraging the recycling based on the sludge treatment on land. The Main objective of this study is to investigate the feasibility of co-incineration for MSW (Municipal Solid Waste) and SS (Sewage Sludge) through the change of heat and atmospheric pollutants. In this study, LHV (Low Heating Value) is 100~300 kcal/kg because the MC (Moisture Content) of de-hydrated sewage sludge is approximately 80%. From the results, we knew the feasibility of co-incineration for MSW (80%) and SS (20%). As the co-incineration rate of SS up to 20% became higher, the loading of heat and atmospheric pollutants was not influenced.

• Journal of the Korean Institute of Gas
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• v.24 no.1
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• pp.33-40
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• 2020

Chiller systems which have better temperature stability than Direction expansion coils are often used as condensing units in HVAC systems for offshore plants. Large capacity compressors and electronic expansion valves in chiller systems are mostly imported, and the size of a chiller system depends on heat exchangers such as evaporators and condensers which are locally produced. Due to limited space in the offshore plants, shipyards are demanding manufacturers to make equipment compact. In this paper, a shell & tube heat exchanger, which is used as an evaporator in the conventional flooded chiller system, is replaced by a newly developed compact plate & shell heat exchanger. The main development process of the plate & shell heat exchanger is introduced, and its performances were experimentally evaluated with a real flooded chiller system, and the results are presented.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.11
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• pp.906-914
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• 2006

The present paper dealt with an experimental study of boiling heat transfer characteristics of R-290. Pressure gradient and heat transfer coefficient of the refrigerant flow inside horizontal smooth minichannel were obtained with inner tube diameter of 3.0 mm and length of 2,000 mm. The direct electric heating method was applied for supplying a heat to the refrigerant uniformly. The experiments were conducted with R-290 purity of 99.99%, at saturation temperature of 0 to $10^{\circ}C$, a mass flux range of $50{\sim}250kg/m^2s$, and a heat flux range of $5{\sim}20kW/m^2$. The heat transfer coefficients of R-290 increased with increasing mass flux and saturation temperature, wherein the effect of mass flux was higher than that of the saturation temperature. Heat flux has a low effect on the increasing of heat transfer coefficient. The heat transfer coefficient was compared with six existing heat transfer coefficient correlations. The Zhang et al.'s correlation (2004) gave the best prediction of heat transfer coefficient. A new correlation to predict the two-phase flow heat transfer coefficient was developed based on the Chen correlation. The new correlation predicted the experimental data well with a mean deviation of 11.78% and average deviation of -0.07%.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.68-73
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• 2006

The present paper deals with an experimental study of boiling heat transfer characteristics of R-290, and is focused on pressure gradient and heat transfer coefficient of the refrigerant flow inside horizontal smooth minichannel with inner diameter of 3.0 mm and length of 2000 mm. The direct heating method applied for supplying heat to the refrigerant where the test tube was uniformly heated by electric current which was applied to the tube wall. The experiments were conducted with R-290 with purity of 99.99% at saturation temperature of 0 to $10^{\circ}C$. The range of mass flux is $50{\sim}250kg/m^2s$ and heat flux is $5{\sim}20kW/m^2$. The heat transfer coefficients of R-290 increases with increasing mass flux and saturation temperature, wherein the effect of mass flux is higher than that of the saturation temperature, whereas the heat flux has a low effect on increasing heat transfer coefficient. The significant effect of mass flux on heat transfer coefficient is shown at high quality, the effect of heat flux on heat transfer coefficient at low quality shows a domination of nucleate boiling contribution. The heat transfer coefficient of the experimental result was compared with six existing heat transfer coefficient correlation. Zang et al.'s correlation(2004) gave the best prediction of heat transfer coefficient.

• Journal of the Korean Magnetics Society
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• v.21 no.6
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• pp.204-207
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• 2011

We developed a time-resolved magneto-optical Kerr effect microscope system to investigate ultrafast magnetization dynamics. Based on the pump-probe method, 0.1-ps time resolution was achieved by use of a fs Ti:Sapphire laser. The magnetization dynamics was then measured on Pt/Co/Pt thin films with various Co thicknesses. All the samples exhibited ultrafast demagnetization within a few ps by direct heating of pump laser. Some thicker samples showed precessional motion of magnetization, from which the Gilbert damping constant was determined based on the Landau-Lifshitz-Gilbert equation.