• Title/Summary/Keyword: Direct Disposal

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Analysis of Resource and GHG Reduction by Recycling Palladium in Plated Spent Catalyst Solution (도금폐촉매액내 팔라듐 재자원화에 따른 자원 및 온실가스 감축량 분석)

  • Shin, Ka-Young;Lee, Seong-You;Kang, Hong-Yoon
    • Resources Recycling
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    • v.30 no.3
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    • pp.47-54
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    • 2021
  • Palladium present in colloidal-type plated spent catalyst solution that is used in electroless plating process has not been recovered but discharged as wastewater so far. Recyclig of paladium in colloidal-type plated spent catalyst solution is achieved with this study. This study presents the estimation of resource consumption and GHG emissions during the recycling and disposal of palladium in the plated spent catalyst solution using life cycle assessment. The reduction of resources and GHG are also estimated. Based on the palladium amount of 1 kg during disposal, the GHG emission amount was estimated to be 9.67E+03 kgCO2eq., and the amount of resource consumption was 3.94E+01 kgSb-eq. However, GHG emission was 1.96E+03 kgCO2eq., and the amount of resource consumption was 1.54E+01 kgSb-eq. during recycling. Considering the major substances affecting GHG emissions and amount of resource consumption, CO2 was found to significantly affect GHG emissions, accounting for 91.42% in disposal and 98.37% in recycling. The major substance affecting the amount of resource consumption was hard coal, which accounted for 40.63% in disposal and 60.73% in recycling. Upon recycling 1 kg palladium, 8,967.17 kgCO2eq. of greenhouse gas emission was reduced, while the resource consumption was reduced to 10.10 kg Sb-eq. In addition, the direct palladium resource reduction rate due to palladium recycling was 50%.

A Study on the Improvement of Dairy Rousing Systems in Kore (한국의 낙농시설 개선에 관한 연구)

  • Kim, Moon-Ki;Koh, Chae-Koon;Kim, H. U.
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.24 no.1
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    • pp.31-43
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    • 1982
  • Engineering phase of dairy housing systems has close connection with the milk produc- tivity of dairy cattle, the quality of milk, extension of dairy production systems, labor- saving in management of dairy cattle and the like. Moreover, the rate of investment of dairy housing facilities is of relatively high level, However, there has been almost no research effort for the improvement of engineering aspects of dairy housing systems in Korea. The purpose of this study is to find out general engineering problems and to recomm- end the improvement in dairy housing systems in Korea. Field survey by means of questionaire, direct measurements, taking pictures and sketching was conducted to get necessary information for the study. Kyung-ki Do region was firstly chosen for sampling area since it has included more than half of the number of dairy farms of the whole country. The results obtained are summarized as follows: 1. In overall dairy farm layout, the dwellings of workers were ignored in the light of sanitary environment 2. The layout of stalls in a dairy barn belongs mostly to the type of double-row face-out, which is compatible with the emphasis of manure disposal activities. 3. While the width and length of stalls were sufficiently close to the standard dimension, the width of mangers was much less than the standard dimension. 4. The width and depth of manure gutters and the width of working alleys were much. less than the standard dimension. 5. The mooring equipment was mostly in the classes of chain or rope. The watering equipment was not facilitated independantly except the one cese of using watercup. 6. The bucket milkers with one or two bucket milkers with the capacity of two cattles. each were used as milking equipment in most dairy farms. 7. There were only few milk rooms independently spaced from other space, in which the arrangement of milking equipment was much less than the standard condition. 8. The lounging ground area was averaged to be sufficient for the activity of dairy herd. 9. Silos for silage used during winter consisted of mostly bunker silos, trench silos and underground vertical silos. Ordinary vertical silos were considered for the farmers to be inconvenient for the labor saving. 10. From the view point of heat conservation and moisture removal within the dairy barns, windows were not flexible for the easy ventilation and ceiling part was not adequate for temperatur maintenance. 11. Waste treatment and disposal systems were not provided with most dairy farms, therefore the livestock waste pollution problems would be serious in the near future.

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Demolition Cost Estimation of Small-size Rental Housing based on the Quantity per Unit Method (원가계산방식에 의한 다가구임대주택 해체공사비 예측)

  • Park, Seong-Sik;Lee, Sung-Bok;Shin, Sang-Hoon
    • Land and Housing Review
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    • v.2 no.4
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    • pp.415-427
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    • 2011
  • This study is aiming at estimating the demolition cost of deterioration housing by the rational method in order to provide for the demolition and new build project of the rental multi-family housing of LH. We investigated the actual state of demolition construction and work process of small size housing, and analysed an actual condition of estimation for the demolition cost through an advice by the expert of construction cost estimate. Furthermore, the 'estimation standard for the predetermined amount', 'estimation standard for the disposal cost of construction wastes' and precedent studies in public construction work were considered. As one of results in this study, cost accounting system, breakdown system and construction cost for the demolition work based on the standard of estimate were proposed and the predetermined amount of demolition construction for the multi-family housing with 2 or 3 floors could be produced by them. Eventually, It is estimated that the demolition cost per a multi-family housing is about 18,331,000(won) and 104,000(won) per floorage($m^2$). To the details, the result indicated that the direct demolition cost needs about 14,339,000(won) per a multi-family housing and the consignment disposal cost of wastes needs 3,992,000(won) per one. The results of the study will be used as the fundamental data to estimate the project cost in the phase of budget establishment for demolition and new build project of the deteriorated rental multi-family housings, and also cost accounting system of demolition construction and breakdown system are expect to be used effectively at the ordering of public construction work.

Glass Dissolution Rates From MCC-1 and Flow-Through Tests

  • Jeong, Seung-Young
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.257-258
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    • 2004
  • The dose from radionuclides released from high-level radioactive waste (HLW) glasses as they corrode must be taken into account when assessing the performance of a disposal system. In the performance assessment (PA) calculations conducted for the proposed Yucca Mountain, Nevada, disposal system, the release of radionuclides is conservatively assumed to occur at the same rate the glass matrix dissolves. A simple model was developed to calculate the glass dissolution rate of HLW glasses in these PA calculations [1]. For the PA calculations that were conducted for Site Recommendation, it was necessary to identify ranges of parameter values that bounded the dissolution rates of the wide range of HLW glass compositions that will be disposed. The values and ranges of the model parameters for the pH and temperature dependencies were extracted from the results of SPFT, static leach tests, and Soxhlet tests available in the literature. Static leach tests were conducted with a range of glass compositions to measure values for the glass composition parameter. The glass dissolution rate depends on temperature, pH, and the compositions of the glass and solution, The dissolution rate is calculated using Eq. 1: $rate{\;}={\;}k_{o}10^{(ph){\eta})}{\cdot}e^{(-Ea/RT)}{\cdot}(1-Q/K){\;}+{\;}k_{long}$ where $k_{0},\;{\eta}$ and Eaare the parameters for glass composition, pH, $\eta$ and temperature dependence, respectively, and R is the gas constant. The term (1-Q/K) is the affinity term, where Q is the ion activity product of the solution and K is the pseudo-equilibrium constant for the glass. Values of the parameters $k_{0},\;{\eta}\;and\;E_{a}$ are the parameters for glass composition, pH, and temperature dependence, respectively, and R is the gas constant. The term (1-Q/C) is the affinity term, where Q is the ion activity product of the solution and K is the pseudo-equilibrium constant for the glass. Values of the parameters $k_0$, and Ea are determined under test conditions where the value of Q is maintained near zero, so that the value of the affinity term remains near 1. The dissolution rate under conditions in which the value of the affinity term is near 1 is referred to as the forward rate. This is the highest dissolution rate that can occur at a particular pH and temperature. The value of the parameter K is determined from experiments in which the value of the ion activity product approaches the value of K. This results in a decrease in the value of the affinity term and the dissolution rate. The highly dilute solutions required to measure the forward rate and extract values for $k_0$, $\eta$, and Ea can be maintained by conducting dynamic tests in which the test solution is removed from the reaction cell and replaced with fresh solution. In the single-pass flow-through (PFT) test method, this is done by continuously pumping the test solution through the reaction cell. Alternatively, static tests can be conducted with sufficient solution volume that the solution concentrations of dissolved glass components do not increase significantly during the test. Both the SPFT and static tests can ve conducted for a wide range of pH values and temperatures. Both static and SPFt tests have short-comings. the SPFT test requires analysis of several solutions (typically 6-10) at each of several flow rates to determine the glass dissolution rate at each pH and temperature. As will be shown, the rate measured in an SPFt test depends on the solution flow rate. The solutions in static tests will eventually become concentrated enough to affect the dissolution rate. In both the SPFt and static test methods. a compromise is required between the need to minimize the effects of dissolved components on the dissolution rate and the need to attain solution concentrations that are high enough to analyze. In the paper, we compare the results of static leach tests and SPFT tests conducted with simple 5-component glass to confirm the equivalence of SPFT tests and static tests conducted with pH buffer solutions. Tests were conducted over the range pH values that are most relevant for waste glass disssolution in a disposal system. The glass and temperature used in the tests were selected to allow direct comparison with SPFT tests conducted previously. The ability to measure parameter values with more than one test method and an understanding of how the rate measured in each test is affected by various test parameters provides added confidence to the measured values. The dissolution rate of a simple 5-component glass was measured at pH values of 6.2, 8.3, and 9.6 and $70^{\circ}C$ using static tests and single-pass flow-through (SPFT) tests. Similar rates were measured with the two methods. However, the measured rates are about 10X higher than the rates measured previously for a glass having the same composition using an SPFT test method. Differences are attributed to effects of the solution flow rate on the glass dissolution reate and how the specific surface area of crushed glass is estimated. This comparison indicates the need to standardize the SPFT test procedure.

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Synthesis of Zeolite from Sewage Sludge Incinerator Fly Ash by Hydrothermal Reaction in Open System (Open System 수열반응을 통한 하수슬러지 소각 비산재의 Zeolite 합성가능성)

  • Lee, Je-Seung;Eom, Seok-Won;Choi, Han-Young
    • Journal of Environmental Health Sciences
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    • v.33 no.4
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    • pp.317-324
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    • 2007
  • The sewage treatment sludge disposal has become a serious environmental problem because of restricted direct land-filling and oceandumping in spite of their large amounts discharged. So the recycling of sewage treatment sludge is very useful alternative for waste management. Here, we studied the feasibility of zeolite synthesis in open system from the sewage treatment sludge incinerator fly ash by means of hydrothermal synthesis. We considered the concentration of NaOH, reaction time, reaction temperature and reaction step as synthesis variables. The phase of zeolite products was identified by X-ray diffractometer(XRD) and ammonium ion exchange test was performed for the raw fly ash and two zeolite products(Z-3 and Z-5). In leaching test of the raw fly ash, hazard metal is detected very low level compared with regulatory leaching test standard. But in total recoverable test, the total contents of the fly ash were very high in terms of the standard for waste-derived fertilizer. Through hydrothermal reaction, small amount of zeolite P was synthesied in 1 N of NaOH solution and relatively large amount of hydroxysodalite was synthesied in 3 N and 5 N of NaOH solution with similar peak intensity. Addition of an aging step in the synthesis didn't increase the amount of zeolite phase. Maximum $NE_4^+-N$ exchange capacity is 1.49 mg $NH_4^+-N/g$ in Z-3 and 1.38 mg $NH_4^+-N/g$ in Z-5. Most of the ammonium ion is exchanged in 30 minutes and disorption did not occur until 5 hours.

Present Status and Future of Spent Fuel Management(1) - National Strategies and Their Implementations (사용후핵연료관리의 현황 및 미래(1) -국가별 관리전략과 그 이행-)

  • Park, Won-Jae;Suk, Tae-Won
    • Journal of Radiation Protection and Research
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    • v.21 no.1
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    • pp.59-72
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    • 1996
  • The continuous expansions and development of nuclear power have led to generation of the significant volume of spent fuels and radioactive wastes. And so, safe and effective management of the spent fuel has been becoming internationally sensitive and significant issue since the early 1990s. Especially, more importance would be added in the view point of international politics, because of recent political changes in the countries of Eastern Europe including dissociation of the former Soviet Union and the difficulties faced by the nuclear industries worldwide. Accordingly, this paper is proposed to show an overview of national strategies and Policies on the spent fuel management, that are being assessed and carried out worldwide at this time. The overview is based on recent developments of the national strategies, their implementations and some related experiences presented in IAEA International meetings and some technical papers.

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LIfe Cycle Assessment(LCA) for Calculation of the Carbon Emission Amount of Organic Farming Material -With Oyster-shell, Expanded Rice Hull, Bordeaux Mixture Liquid- (유기농자재의 탄소배출량 산정을 위한 전과정평가(LCA) -패화석, 팽연왕겨, 보르도액을 중심으로-)

  • Yoon, Sung-Yee;Yang, Dong-Wook
    • Korean Journal of Organic Agriculture
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    • v.20 no.4
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    • pp.475-490
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    • 2012
  • Since 1997, Korean Ministry of Knowledge Economy and Ministry of Environment have established data on some 400 basic raw and subsidiary materials and process like energy, petro-chemical, steel, cement, glass, paper, construction materials, transportation, recycling and disposal etc by initiating establishment of LCI database. Regarding agriculture, Rural Development Administration has conducted establishment of LCI database for major farm products like rice, barley, beans, cabbage and radish etc from 2009, and released that they would establish LCI database for 50 items until 2020 later on. The domestic LCI database for seeds, seedling, agrochemical, inorganic, fertilizer and organic fertilizer etc is only at initial stage of establishment, so overseas LCI databases are brought and being used. However, since the domestic and overseas natural environments differ, they fall behind in reliability. Therefore, this study has the purpose to select organic farming materials, survey the production process for various types of organic farming materials and establish LCI database for the effects of greenhouse gas emitted by each crop during the process. As for selecting methods, in this study organic farming materials were selected in the method of direct observation of material and bottom-up method a survey method with focus on the organic farming materials admitted into rice production. For the basic unit of carbon emission amount by the production of 1kg of organic farming material, the software PASS 4.1.1 developed by Korea Accreditation Board under Ministry of Knowledge Economy was used. The study had the goal to ultimately provide basic unit to calculate carbon emission amount in executing many institutions like goal management system and carbon performance display system etc in agricultural sector to be conducted later on. As a result, emission basic units per 1kg of production were calculated to be 0.04968kg-$CO_2$ for oystershells, 0.004692kg-$CO_2$ for expanded rice hull, and 1.029kg-$CO_2$ for bordeaux mixture liquid.

Effects of waste dumpsites on geotechnical properties of the underlying soils in wet season

  • Essienubong, Ikpe Aniekan;Okechukwu, Ebunilo Patrick;Ejuvwedia, Sadjere Godwin
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.289-297
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    • 2019
  • Indiscriminate disposal of waste and citation of open dumpsites are some of the key factors affecting the various soil geotechnical properties. Atterberg limit and consolidation tests were conducted to determine the effects of two open waste dumpsites (Uselu Market and New Benin) on geotechnical properties of their underlying soils. Soil sample collected from Uselu Market dumpsite in Benin City metropolis showed slightly lower hydraulic conductivity (K) of $1.0{\times}10^{-6}$ with plasticity index of 18.53% compared to sample collected 1.6 m from the same dumpsite which had high K value of $2.42{\times}10^{-3}$ with plasticity index of 6.9%. Soil sample collected from New Benin dumpsite in Benin City metropolis showed slightly lower K of $1.45{\times}10^{-6}$ with plasticity index of 13.8% than sample collected 1.6 m from the same dumpsite which had high K value of $2.14{\times}10^{-2}$ with plasticity index of 6.0%. X-ray florescent analyser (X-MET 7000) and direct soil pH meter were used to determine the composition of the aforementioned soil samples. The result of samples collected from both dumpsites indicated a low hydraulic conductivity compared to samples collected 1.6 m from both dumpsites. Also, the chemical composition and pH of both dumpsite underlying soils indicated high level of soil contaminants with pH of 3.3 and 3.5 which is very acidic unlike pH of other samples which were in the neutral range (6.8-7.1). Hence, a liner is recommended for all dumpsites or engineered landfill systems to mitigate against the challenges associated with open waste dumping system in the environment.

Development on the Methodology of CDM Projects in the SF6 Recovery and Recycling of Electrical Equipment (전력설비에서의 SF6 회수 및 재활용 CDM 방법론 개발)

  • Pyo, Jeong-Gwan;Sa, Jae-Hwan;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.2 no.3
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    • pp.143-159
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    • 2011
  • Projects applying the CDM methodology AM0035 of the $SF_6$ Emission Reductions in Electrical Grids should provide direct monitoring of all the key parameters that are related to estimation of baseline and project emissions including detailed explanations of key operating conditions and procedures, and an explanation addressing uncertainty as the result of EB meeting 41. Through this study, recovery ratio during maintenance, purity of $SF_6$ before and after disposal, replacing, loss rate of $SF_6$ before and after reclamation, leakage emission from electricity consumption and fossil fuel combustion, considered conservatively the key parameter of various monitoring. Consequently, confirmed the reduction in the amount of reduction due to the baseline emission decrease, project emission increase.

Optimization of the Korean Nuclear Fuel Cycle Using Linear Programming (선형계획법을 이용한 한국 원전연료주기의 최적화)

  • Kim, J.I.;Chae, K.N.;Lee, B.W.
    • Nuclear Engineering and Technology
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    • v.27 no.5
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    • pp.721-729
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    • 1995
  • The Korean optimal nuclear fuel cycle strategy from the year 2000 to 2030 is derived using linear programming. The fuel cycle cost, the cost uncertainty, and the natural uranium consumption are used as the criteria for the optimization. These objectives are compromised by fuzzy decision-making technique which maximizes the minimum degree of satisfaction among the three objectives. The options for the back-end fuel cycle are direct disposal, reprocessing, and DUPIC. The optimal fuel cycle strategy of Korea is to start reprocessing in around 2010 and increase its capacity with the maximum of 800 tHM in around 2025, and to star DUPIC processing in 2025. The cot uncertainty and the natural uranium consumption of the optimal fuel cycle strategy are reduced by 7.1% and 6.1%, respectively, at the cost penalty of 5.4% compared with the cost-only optimal solution.

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