• 제목/요약/키워드: Direct CF

검색결과 60건 처리시간 0.026초

Large-area imaging evolution of micro-scale configuration of conducting filaments in resistive switching materials using a light-emitting diode

  • Lee, Keundong;Tchoe, Youngbin;Yoon, Hosang;Baek, Hyeonjun;Chung, Kunook;Lee, Sangik;Yoon, Chansoo;Park, Bae Ho;Yi, Gyu-Chul
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
    • /
    • pp.285-285
    • /
    • 2016
  • Resistive random access memory devices have been widely studied due to their high performance characteristics, such as high scalability, fast switching, and low power consumption. However, fluctuation in operational parameters remains a critical weakness that leads to device failures. Although the random formation and rupture of conducting filaments (CFs) in an oxide matrix during resistive switching processes have been proposed as the origin of such fluctuations, direct observations of the formation and rupture of CFs at the device scale during resistive switching processes have been limited by the lack of real-time large-area imaging methods. Here, a novel imaging method is proposed for monitoring CF formation and rupture across the whole area of a memory cell during resistive switching. A hybrid structure consisting of a resistive random access memory and a light-emitting diode enables real-time monitoring of CF configuration during various resistive switching processes including forming, semi-forming, stable/unstable set/reset switching, and repetitive set switching over 50 cycles.

  • PDF

Potential of Wood Vinegar in Enhancing Fruit Yield and Antioxidant Capacity in Tomato

  • Benzon, Hiyasmin Rose L.;Lee, Sang Chul
    • 한국자원식물학회지
    • /
    • 제29권6호
    • /
    • pp.704-711
    • /
    • 2016
  • Tomatoes are considered as one of the main components of daily meals in most households. Thus, it is important to invest in studies enhancing their yield and nutritional value. The study evaluated the effect of wood vinegar (WV) on tomato under greenhouse conditions. Data on fruit number, fruit weight, and plant height were recorded. Total phenolic content (TPC) and antioxidant activity of tomato were determined using the Folin-Ciocalteu reagent and 2, 2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging assay, respectively. FRR-CF+500x-WV significantly increased the fruit number (86.11%) and fruit weight (81.78%) over the control. Results were comparable to HRR-CF+250x-WV, indicating that conventional fertilizer and WV may have synergistic effect on each other. TPC and scavenging effect on DPPH radical was improved by 250x-WV application. The increase in the phenolic compounds can be attributed to WV as a direct source or as a factor triggering the plants to produce more secondary metabolites with the purpose of increasing natural defenses. The significant effect obtained by applying the full recommended rate of conventional fertilizer on the carotenoid content was due to the availability of the major nutrients needed by the plant. Correlation analysis showed that carotenoids have negative correlation with TPC and DPPH. However, TPC and DPPH showed that these are positively correlated with each other. Tomatoes are excellent source of antioxidants associated with the reduction of some human diseases and improved health. The results provided evidence that WV alone and/or its combination with conventional fertilizers has favorable effects on the quality of tomato.

표면불소화에 따른 Poly(phenylene oxide)막의 기체투과거동 연구 (Studies on the Gas Permeation Behaviors Using the Surface Fluorinated Poly(phenylene oxide) Membranes)

  • 이보성;김대훈;임지원
    • 멤브레인
    • /
    • 제20권2호
    • /
    • pp.106-112
    • /
    • 2010
  • 본 연구에서는 poly(phenylene oxide) (PPO)의 막 표면에 100 ppm의 농도를 갖는 불소가스를 접촉시켜 표면불소화하였다. 표면 개질된 막의 특성을 알아보기 위하여 표면접촉각, XPS, 기체투과 실험을 수행하였다. 표면특성 분석 결과 불소처리 시간이 증가함에 따라 막 표면에 $-CF_2$, $-CF_3$의 perfluoro group의 결합으로 인해 막의 소수성이 증가함을 알 수 있었다. 기체투과 측정으로부터 불소화시간이 증가함에 따라 기체에 대한 투과도는 감소하였으며, 불소노출이 60분 경과한 막의 경우 질소 33%, 산소 23%, 이산화탄소 3%의 감소율을 나타내었다. 선택도의 경우 질소 대비 산소의 경우 3.92로부터 4.47로, 이산화탄소에 대한 질소의 경우 18.09에서 25.4로 증가함을 얻었다.

불소방출성 수복재의 불소 재충전에 따른 불소유리와 표면변화 (An Effect of Fluoride Recharging on Fluoride Release and Surface Change of Fluoride-Releasing Restorative Materials)

  • 문장원;유미경;이광원
    • 구강회복응용과학지
    • /
    • 제21권1호
    • /
    • pp.25-32
    • /
    • 2005
  • The purpose of this study was to examine an effect of fluoride recharging on fluoride release and surface change of fluoride-releasing restorative materials. Six commercially available fluoride releasing restorative materials (Fuji II LC Improved: FL, Compoglass F: CF, Dyract AP: DA, F2000: FT, Gradia Direct: GD, and Tetric Ceram: TC) were selected as experimental materials. Disk specimens were fabricated with split teflon mold to the final dimensions of 15 mm in diameter and 1 mm in thickness. Ten samples of each material were fabricated and stored in deionized water at $37^{\circ}C{\pm}1^{\circ}C$ for 3 months. Before fluoride recharging, all specimens were polished sequentially from #800 to #2000 emery papers. Fluoride recharging was done at 5-day interval using 2.0% NaF gel. The release of fluoride into the storage water was monitored using a fluoride ion electrode. Data were analyzed by one-way ANOVA and Tukey's multiple range test. The results obtained were summarized as follows; 1. Fluoride recharge capability were FL > CF > DA and TC group after 12 times exposure to 2.0% NaF gel (P<0.05). 2. All the experimental materials, except for FT group, showed the increase of fluoride release and surface roughness. 3. Fluoride-releasing rates returned to base line within 3 days.

染色物의 日光에 對한 堅牢性에 關한 硏究 (第3報) 染料初濃度가 視覺에 依한 褪色判定結果에 미치는 影響 (Studies on the Light Fastness of Dyeings (3) Effect of Dye Concentration on the Visual Judgement of Fading)

  • 하완식
    • 대한화학회지
    • /
    • 제11권1호
    • /
    • pp.12-16
    • /
    • 1967
  • ?織物上의 Chlorantine Fast Red 5B(C.I. Direct Red 81)의 照光으로 因한 褪色을 檢討하여 同染料의 CF曲線의 기울기는 異例的으로 負의 기울기를 나타내는 反面 CFG 曲線의 기울기는 正의 기울기를 나타낸다는 것을 밝혀내고, 同染料의 CF曲線의 기울기가 負로 나타남에도 不拘하고 CFG曲線의 기울기는 正으로 나타나게 되는 理由를, Weber-Fechner의 法則이 染色物의 視覺에 依한 褪色判定에 作用하는 때문인 것으로 보고, 視覺判定에 依할 때의 染料의 褪色量($F_v$)은 $F_v=[logC_0-log(C_0-C_0F_t/100)]{\times}100/(logC_0+b)$$F_t$; t時間 照光後의 染料의 褪色量, $C_0$; 染料의 初濃度, b; 定數으로 表示할 수 있다는 것을 明白히 하였다. 아울러 染料濃度 增加에 따르는 日光堅牢度 上昇의 原因으로서 染料의 集合效果外에, 染料濃度가 視覺判定에 依한 褪色判定結果에 미치는 影響도 考慮해야 할것임을 明白히 하였다.

  • PDF

Effects of maleic anhydride content on mechanical properties of carbon fibers-reinforced maleic anhydride-grafted-poly-propylene matrix composites

  • Kim, Hyun-Il;Han, Woong;Choi, Woong-Ki;Park, Soo-Jin;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
    • /
    • 제20권
    • /
    • pp.39-46
    • /
    • 2016
  • In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (KIC). From the KIC test results, the KIC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

나선형 흡기포트 입구의 유동조건이 실린더 내 선회특성에 미치는 영향에 관한 연구 (Effects of the Inlet Flow Conditions of a Helical Intake Port on the In-cylinder Swirl Characteristics)

  • 이지근;강신재
    • 한국자동차공학회논문집
    • /
    • 제8권2호
    • /
    • pp.9-18
    • /
    • 2000
  • Combustion and emission characteristics in a direct injection diesel engine is closely related to the intake port system. It is therefore important to understand the swirl flow characteristics formed by a helical intake port. However there are still many uncertainties. The purpose of this experimental study is to investigate the effects of the valve eccentricity ratio and the inlet flow conditions of a helical intake port on the characteristics of an in-cylinder swirl flow. A steady state flow test rig consisted of ISM(impulse swirl meter), LFM(laminar flow meter) and cylinder head with a helical intake port was used. The swirl ratio(Rs) and mean flow coefficient(Cf(mean)) with inlet flow conditions were measured. The results of these experiment can be summarized as follows. Swirl flow characteristics of a helical intake port are affected by the inlet flow conditions, and especially they are much affected by the length of a manifold runner and the rotational angle of a curved manifold runner.

  • PDF

Synthesis and Cation Binding Properties of Triester Calix[4]arenes and Calix[4]quinones

  • 남계천;강성옥;전종철
    • Bulletin of the Korean Chemical Society
    • /
    • 제18권10호
    • /
    • pp.1050-1052
    • /
    • 1997
  • The complexes M(CO)4-1,2-(PPh2)2-1,2-C2B10H10 (M=Cr 2a, Mo 2b, W 2c) have been prepared in good yields from readily available bis-diphenylphosphino-o-carboranyl ligand, closo-1,2-(PPh2)2-1,2-C2B10H10 (1), by direct reaction with Group Ⅵ metal carbonyls. The infrared spectra of the complexes indicate that there is an octahedral disposition of chelate bis-diphenylphosphino-o-carboranyl ligand around the metal atom. The crystal structure of 2a was determined by X-ray diffraction. Complex 2a crystallizes in the monoclinic space group P21/n with cell parameters a = 12.2360(7), b = 17.156(1), c = 16.2040(6) Å, V = 3354.1(3) Å3, and Z =4. Of the reflections measured a total of 2514 unique reflections with F2 > 3σ(F2) was used during subsequent structure refinement. Refinement converged to R1 = 0.066 and R2 = 0.071. Structural studies showed that the chromium atom had a slightly distorted pseudo-octahedral configuration about the metal center with two phosphine groups of o-carborane occupying the equatorial plane cis-orientation to each other. These metal carbonyl complexes are rapidly converted to the corresponding metal carbene complexes, [(CO)3M=C(OCH3)(CH3)]-1,2-(PPh2)2-1,2-C2B10H10 (M= Cr 3a, Mo 3b, W 3c), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3.

Synthesis and Characterization of Air Stable σ-Bonded ortho-carborane Manganese Metal Complexes $1-[Mn(CO)_5]-2-R-1,2-closo-(σ-C_2B_{10}H_{10}$ and Their Conversion to the Stable ortho-carborane Substituted Fischer-type Carbene Compexes 1-[(CO

  • 김세진;김유혁;고재정;강상욱
    • Bulletin of the Korean Chemical Society
    • /
    • 제16권7호
    • /
    • pp.634-641
    • /
    • 1995
  • The metal-carbon σ-bond cluster complexes 1-Mn(CO)5-2-R-1,2-C2B10H10 (R=CH3 Ia, C6H5 Ib) have been prepared in good yields from readily available carboranyl lithium complexes, 1-Li+-2-R-1,2-C2B10H10- (R=CH3, C6H5), by direct reaction with (CO)5MnBr. These manganese metal complexes are rapidly converted to the corresponding manganese metal carbene complexes, 1-[(CO)4Mn=C(OCH3)(CH3)]-2-R-1,2-C2B10H10 (R=CH3 IIIa, C6H5 IIIb), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3. The crystal structure of IIIb was determined by X-ray diffraction. Thus, complex IIIb crystallizes in the orthorhombic space group P212121 with cell parameters a=15.5537(5), b=19.0697(5), c=7.4286(3) Å, V=2203.4(1) Å3, and Z=4. Of the reflections measured a total of 3805 unique reflections with F2>3σ(F2) was used during subsequent structure refinement. Refinement converged to R1=0.053 and R2=0.091. Structural studies showed that the manganese atom had a slightly distorted pseudo-octahedral configuration about the metal center with the carbene and ortho-carborane occupying the equatorial plane cis-orientation to each other.

다중 지구과학자료를 이용한 GIS 기반 공간통합과 통계량 분석 : 광물 부존 예상도 작성을 위한 사례 연구 (GIS-based Spatial Integration and Statistical Analysis using Multiple Geoscience Data Sets : A Case Study for Mineral Potential Mapping)

  • 이기원;박노욱;권병두;지광훈
    • 대한원격탐사학회지
    • /
    • 제15권2호
    • /
    • pp.91-105
    • /
    • 1999
  • 최근 다중 지질정보의 통합적 해석은 GIS의 중요한 응용 분야중 하나로 인식되고 있다. 공간통합을 위하여 지구통계학적 방법들이 개발되어 있지만, 통합결과와 입력 주제도들 사이의 관계에 대한 통계적, 정량적 분석방법론의 개발은 아직까지 체계적으로 정립되어 있지 못한 상황이다. 본 연구에서는 지질도, 지화학자료, 항공지구물리자료, 지형자료 및 원격탐사 영상등 다양한 지질정보등이 보고된 옥동지역을 대상으로 하여 광물 부존 예상도 작성 사례연구를 수행하여 기존에 이용되고 있는 여러 공간 통합 방법중 확실인자 (Certainty Factor: CF) 추정방법과 다변량 통계 분석방법중 하나인 주성분분석을 시험적인 통합방법으로 우선적으로 적용한 뒤, 입력 자료와 통합결과에 대한 정량적인 통계량 정보를 추출하고자 하였다. 입력 주제도와 통합 결과사이의 관계 규명에는 통계 분할표를 이용한 통계처리를 편의 분석에는 잭나이프 방법을 적용하였다. 통합정보에 대한 통계량 분석을 통하여, 통합 결과와 입력자료 사이의 정량적 관계를 추출할 수 있었으며, 부가적으로 입력자료의 상태수준에 대한 판단정보를 얻을 수 있었다. 이러한 결과는 GIS 관점에서 통합결과 해석에 중요한 결정보조자료로 활용될 수 있으며, 복잡한 다중정보를 다루는데 공간 통합문제에서도 입력정보 검증을 위한 일반적일 처리과정으로도 발전할 수 있을 것으로 생각된다.