By using the liquid -phase-deposition (LPD) process, which has a potetnial of preparing organic inorganic composite materials, samples doped with benzo[f]quinoline (BfQ)into silica thia films wre prepared. We observed the fluorescene and fluorescene excitation spectra of the samples, as well as the fluorescence lifetimes and time-resoluved fluorescence spectra. The comparison of thefluorescence spectra in pH-controlled buffer solutions yields the results that the dominant species of BfQ in the LPD silica films is a protonated one. The fluorescence band assigned to a hydrogen-bonded species was observed on the samples prepared from the dipping solutions of 3 and 2 M hexafluorosilicic acid. The band assignment was confirmed by the fluorescence lifetime measurement. The FT-IR M hexaflurosilicic acid. The band assignment was confirmed by the flurescence lifetime meausurement. The FT-IR data proved the existence of included water in silica films prepared from the LPD process. The appearance of the band corresponding to the hydrogen-bonded species within LPD silica phases was explained by the proesence of included water. Depending on the preparation conditions of LPD silica films, the band assigned to protonated species shows bad shifts in a wavenumber region between the peak of hydrogen-bonded and typical protonated species. This implies that there is some distribution of steric conformation of protonated species of BfQ interacting with adsorbing sites of LPD silica. The time -resolved fluorescence spectra suggest that some relaxation process is involved in the conformation of BfQ doped into the solid phase of LPD silica.
Two insecticides, fenobucarb (36, 12 ppm) and imidacloprid (0.7, 0.4 ppm) were treated on rice seedling roots by root uptake method with different dipping time (1, 4, 8, 12, 16, 20, 24 hrs). This study was performed to elucidate the correlation between insecticidal activity and feeding behavior of Nilaparvata lugens using EPG (electrical penetration graph). EPG waveforms are recorded for 4 hours and classified into six waveforms. In the correlation between root uptake and corrected mortality, both insecticides showed higher corrected mortality as higher doses and as longer root uptake times. In the analysis of waveforms, N. lugens showed longer nonprobe time but shorter phloem feeding time at a higher dose. It was also showed the same result as longer the root uptake times. Therefore, it showed the correlation between insecticidal activity by root uptake time and both EPG waveforms (non-probing time and phloem feeding time).
These studies were made on coating of fresh fruits and vegetables with PVC under view on preservation of fresh fruits and vegetables due to restrain water evaporation of them and control gas metabolisms. The results obtained, as selection of PVC materials availble for preservation of them, procedure of the coating, useful organic solvents, concentration of PVC solution and the time of dipping, and effects of the preservation of them, were summarized as follows: 1) PVC powder 222 and PVC powder 443 were surveyed as suitable materials for coating apple, and later was excellent in lustrous aspect. 2) The coating procedure which dipt into PVC solution was suitable to treat much within a short space of time, and using of ventillator accelerate rather evaporation of the organic solvent. 3) Aceton and methyethylketon as solvent of the PVC were, in purpose of storage only, avaible, while aceton was, in view ef taste, better. 4) 10% of the PVC solutions were better to preserve the freshness of apple and 5, 4, 1 and 0.5% of them in order were gradually decreased in preservability, and 15% of them as high concentration were looked like fermentation in one week after the coating. 5) The dipping time was also better n minute than 10 seconds in a preservation but 1-2 minutes could be applied owing to be not affected of the taste due to coating. 6) The freshness of treatment groups were extend about 48 days after coating in room temperature but control lost market value with 12 days. 7) Weight of control was decreased to 10-13% but treatment which was dipped into 10% of coating solution for one minute was decreased to 3.5-4.6% and treatment for four minutes was did to 2.9-3.0%. 8) Change in respiration was less is treatment groups than control in exhaustion of $CO_2$, and water soluble sugar, reduced sugar and pH were not changed almost due to coating. 9) Pannel discussion of the taste was indicated that control was better than treatments soon after coating, but treatments were rather than control last period of storage and treatment with aceton solvent specially was better than others.
Journal of the Korean Recycled Construction Resources Institute
/
v.7
no.3
/
pp.77-84
/
2012
It is known that some components of wood obstruct the hydration of cement when wood is mixed with cement. In order to examine the effect of pretreatment of wood chips in hot water, this study conducted the experiments for the setting and compressive strength of mortar by sieving pine wood chips with a 2.4mm sieve, dipping them in waters of different temperatures, and then using them as a part of the fine aggregate. For the experiments, water-cement ratio of the mortar was 0.50 and the amount of the fine aggregate substituted by wood chips was set at 0%, 2%, 4%, 6%, 8%, and 10% of the mass of the fine aggregate. As a result of the test, it was found out that when wood chips were used to substitute fine aggregate for the production of mortar, more usage of wood chips postponed setting more, and the treatment of wood chips with water improved the problem of the delay in setting time. Especially, the final setting time of the mortar which used 2~6% of wood chips treated in $100^{\circ}C$ water for 30 minutes was almost the same as the final setting time of the mortar which used no wood chips. Also, the compressive strength of the mortar which used the wood chips treated with water was compared to that of the mortar which used the wood chips not treated with water. The result showed that the strength improved for age of 7 days and 28 days, while there was little change in strength for age of 3 days.
Proceedings of the Korean Vacuum Society Conference
/
2016.02a
/
pp.157.1-157.1
/
2016
In this work, we experimentally investigated the solar absorption performance of Cu-based scalable nanostructured surfaces and compared their performance with the conventional TiNOX. We fabricated Cu-based nanostructured surfaces with a controlled chemical oxidation process applicable to a large area or complex geometry. We optimized the process parameters including the chemical compounds, dipping time and process temperature. We conducted both lab-scale and outdoor experiments to characterize the conversion efficiency of each absorber surfaces with single and double glazing setup. Lab-scale experiment was conducted with $50mm{\times}50mm$ absorber sample with 1-sun condition (1kW/m2) using a solar simulator (PEC-L01) with measuring the temperature at the absorber plate, cover glass, air gap and ambient. From the lab-scale experiment, we obtained ${\sim}91^{\circ}C$ and $94^{\circ}C$ for CuO and TiNOX surfaces after 1 hr of solar illumination at single glazing, respectively. To measure the absorber performance at actual operating condition, outdoor experiment was also conducted using $110mm{\times}110mm$ absorber sample. We measured the solar flux with thermopile detector (919P-040-50). From outdoor experiment, we observed ${\sim}123^{\circ}C$ and $131^{\circ}C$ for CuO and TiNOX with 0.6 kW/m2 insolation at double glazing, respectively. We showed that the suggested nanostructured CuO solar absorber has near-equivalent collection efficiency compared with the state-of-the-art TiNOX surfaces even with much simpler manufacturing process that does not require an expensive equipment.
Proceedings of the Korean Vacuum Society Conference
/
2016.02a
/
pp.319.1-319.1
/
2016
Recently, the Al-doped ZnO (ZnO:Al) films are intensively used in thin film a-Si solar cell applications due to their high transmittance and good conductivity. The textured ZnO:Al films are used to enhance the light trapping in thin film solar cells. The wet etch process is used to texture ZnO:Al films by dipping in diluted acidic solutions like HCl or HF. During that process the glass substrate could be damaged by the acidic solution and it may be difficult to apply it for the inline mass production process since it has to be done outside the chamber. In this paper we report a new technique to control the surface morphology of RF-sputtered ZnO:Al films. The ZnO:Al films are textured with vaporized HF formed by the mixture of HF and H2SiO3 solution. Even though the surface of textured ZnO:Al films by vapor etching process showed smaller and sharper surface structures compared to that of the films textured by wet etching, the haze value was dramatically improved. We achieved the high haze value of 78% at the wavelength of 540 nm by increasing etching time and HF concentration. The haze value of about 58% was achieved at the wavelength of 800 nm when vapor texturing was used. The ZnO:Al film texture by HCl had haze ratio of about 9.5 % at 800 nm and less than 40 % at 540 nm. In addition to low haze ratio, the texturing by HCl was very difficult to control etching and to keep reproducibility due to its very fast etching speed.
Journal of Advanced Marine Engineering and Technology
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v.31
no.2
/
pp.173-181
/
2007
Recently, galvanizing method is predominantly being used not only a economical point of view but also due to it s stability and long life. For example, guard rail of high way, all kinds of structures for ship etc. were protected with galvanizing and demand of galvanized structural materials was being increased with more and more. However, galvanized structures were inevitably being deteriorated with time eventually because they were corroded with solution of galvanizing film and exfoliation of it s film in the present severe corrosive environment. Therefore, it is necessary to improve the corrosion resistance of the galvanizing film through various methods such as variation of chemical composition of galvanizing bath, chromate treatment and coating treatment. In this study, three test specimens such as pure galvanizing, galvarium, and chromate treatment were submerged at tap water with inhibitor addition. And the effect of their corrosion resistance improvement was comparatively investigated with electrochemical method. Corrosion current density of the galvanized steel was the largest among three specimens, however, the galvarium steel showed the lowest corrosion current density. Futhermore, these three kinds of test specimens indicated considerably excellent corrosion resistance by dipped at tap water with inhibitor addition. Especially, the galvanized steel showed the best effect of corrosion resistance improvement than other test specimens.
The pathogenicity of the fish nodavirus causing viral nervous necrosis (VNN) of sevenband grouper, Epinephelus septemfasciatus was examined in sevenband grouper and other marine fish by intramuscular injection. Sevenband groupers of 27~104 g in body weight were highly susceptible to the fish nodavirus, but yellowtail (537 g in body weight), red seabream (207 g), rock bream (43 g), flounder (41 g), tiger puffer (27 g) and rockfish (94 g) of the sizes used to this experiment were not. The pathogenicity of the viral agent to the sevenband grouper was high without regard to fish sizes at rearing water temperature over $20^{\circ}C$, but not at $15^{\circ}C$. Therefore, susceptibility of sevenband grouper to the viral agent causing VNN was thought to be water temperature-dependent rather than fish size (age-dependent). Compared to the infectivity of the viral agent to sevenband grouper with artificial infection methods, fish were successfully affected by intramuscular, intraperitoneal, oral, dipping and cohabitation administrations although there were slight differences in mortalities among infection methods. And survival sevenband grouper after infection with the fish nodavirus was resistant to the reinfection for a long time.
The pathogenicity of the extracted WSBV from the hepatopancreas, the lymphoid organ, the stomach and the heart of infected shrimps was examined after artificial infection in shrimps(Penaeus chinensis). In terms of the infection route, the strength of the pathogenicity of WSBV was in the order of intramuscular, oral and dipping method. The influence of rearing water temperature on the pathogenicity of WSBV was the strongest in the order of $30^{\circ}C$, $25^{\circ}C$, $20^{\circ}C$, and $15^{\circ}C$. The isolated WSBV from the diseased shrimps showed very high pathogenicity regardless of their sizes, even though there was difference in time to reach 100% mortality. Degenerated cells characterized by hypertrophied nuclei were found in various tissues such as the lymphoid organ, the hematopoietic tissue and the epidermis in the stomach.
KSCE Journal of Civil and Environmental Engineering Research
/
v.36
no.4
/
pp.659-665
/
2016
The limit equilibrium method (LEM) is commonly used for slope design and stability analysis because it is easy to simulate slope and requires short calculating time. However, LEM cannot adequately simulate ploughing failure in a footwall slope with a joint set dipping parallel with slope, e.g. bedding joint set. This study performed parametric study to analyze the influence factors on ploughing failure using UDEC which is a commercial two-dimensional DEM (Distinct Element Method)-based numerical program. The influence of joint structure and properties on stability of a footwall slope against ploughing failure was investigated, and the factor of safety was estimated using the shear strength reduction method. It was found that the stability of footwall slope against ploughing failure strongly relies on dip angle of conjugate joint, and the critical bedding joint spacing and the critical length of slab triggering ploughing failure are also affected by dip angle of conjugate joint. The results obtained from this study can be used for effective slope design and construction including reinforcement.
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