• Title/Summary/Keyword: Dipole moment

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Experimentally Measured Rotational Reorientation Time of Coumarin 6 Laser Dye in Ethanol and Acetonitrile Solvents

  • Renuka, C.G.;Raikar, U.S.
    • Journal of Photoscience
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    • v.12 no.3
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    • pp.119-122
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    • 2005
  • The photophysical properties of coumarin 6 laser dye have been studied in two solvents; ethanol and acetonitrile using steady-state fluorescence depolarization technique. The experimentally measured reorientation time of coumarin 6 is more or less the same in given solvents at particular temperature. It is found that coumarin 6 rotates slower in acetonitrile than in ethanol especially at higher values of viscosity over temperature. We also measure the ground and excited state dipole moments of coumarin 6 by solvent perturbation method. The results found that excited state dipole moment is greater than ground state dipole moment, which indicates that excited state is more polar than the ground state.

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Development of Magnetic Torquer for Satellite Attitude Control (인공위성 자세제어용 Magnetic Torquer 개발)

  • Son, D.
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.54-57
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    • 2008
  • Magnetic torquer, which uses torque between magnetic dipole moment and earth magnetic field, has been used to control attitude of satellites. In this work, we developed a magnetic torquer for small scientific satellite and test under environmental conditions of the satellite launching and orbital motion have been carried out. The developed magnetic torquer shows saturation magnetic dipole moment of $15Am^2$, linearity of 0.3 % in the range of ${\pm}12Am^2$, mass of 0.46 kg, and power consumption of 1 Watt at magnetic dipole moment of $10Am^2$.

Calculation of NMR Chemical Shift for 5d$^n$ Systems (Ⅰ). Application of the Expansion Method for Spherical Harmonics for Computation of Overlap and Dipole Moment Matrix Elements

  • Ahn, Sang-Woon;Oh, Se-Woung;Park, Eui-Suh
    • Bulletin of the Korean Chemical Society
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    • v.6 no.1
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    • pp.3-7
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    • 1985
  • The general formulas for SCF atomic orbitals |5s > and |6p > have been derived separately by expressing the spherical harmonics part in terms of the coordinate($r_1,\;$r_2$) of the reference point, and by translating the exponential part, $r^4\;exp\;(-{\beta}r)$), in terms of $r_1,\;and\;r_2$ and the modified Bessel functions. Master formulas for overlap and dipole moment matrix elements are derived. The computed values of overlap and dipole moment matrix elements for hypothetical NO molecule are exactly in agreement with those for the previous methods.

Radiation Characteristics of Log-Periodic Bent Dipole Antennas (대수주기 벤트 다이폴 안테나의 복사특성)

  • 최학근;김선표;임성빈
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.14 no.11
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    • pp.1207-1215
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    • 2003
  • In this paper Log-Periodic Bent Dipole Antenna(LPBDA), which is composed of bent dipole elements instead of dipole elements, is proposed to reduce the size of Log-Periodic Dipole Antenna(LPDA). LPBDA for the operating frequency band of 1 ㎓∼3 ㎓ is designed and its radiation characteristics are analyzed by the moment method, and compared with radiation characteristics of LPDA. It is shown that although LPBDA decreases in size by about 20 %, radiation characteristics of LPBDA are similar to radiation characteristics of LPDA. Calculated results show good agreement with measured results.

2D-QSAR Analyses on The Tyrosinase Inhibitory Activity of 2-[(2,6-Dioxocyclohexyl)methyl]-cyclohexane-1,3-dione Analogues (2-[(2,6-Dioxocyclohexyl)methyl]cyclohexane-1,3-dione 유도체의 Tyrosinase 저해활성에 관한 2D-QSAR 분석)

  • Kim, Sang-Jin;Sung, Nack-Do
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.4
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    • pp.383-390
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    • 2014
  • The following conclusion was made from the 2D-QSAR model for the tyrosinase inhibitory activity according to the variation of the substituents R1 and R2 in analogues of compound 2-[(2,6-dioxocyclohexyl)methyl]cyclohexane- 1,3-dione (1-23). The best optimized 2D-QSAR model was $Obs.pI_{50}=-0.295({\pm}0.031)TDM$ $-0.120({\pm}0.014)DMZ+0.135({\pm}0.050)DMX.R_2+6.382({\pm}0.17)$, and the correlation $r^2=0.905$) of which was greater than its predictability ($q^2=0.843$). The magnitude of the effect of tyrosinase inhibitory activities was in order of TDM > $DMX.R_2{\geq}DMZ$, and it tended to increase as the hydrophobicity of substrate molecule (ClogP > 0) as well as the steric favor of substituent $R_1$ increased. The analysis of the model implies that inhibitory activity of substrate molecule will increase as $DMX.R_2$ (Dipole moment X component of $R_2$-substituent) increases, while TDM (Total Dipole Moment) and DMZ(Dipole Moment of Z-Component) decrease. As such, it is deemed feasible to conclude, that in order to increase the inhibitory effect, it would be rather desirable to replace the polar groups within the molecules with non-polar functional groups.

Theoretical Analysis of Dipole Moment Derivatives in Fluoromethanes. (III) CH$_3$F and CF$_4$

  • Kim, Kwan;Park, Cheol-Woo
    • Bulletin of the Korean Chemical Society
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    • v.8 no.3
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    • pp.174-179
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    • 1987
  • The results of an ab initio (6-31G) molecular orbital calculations of the dipole moment derivatives and gas phase IR intensities in $CH_3F$ and $CF_4$ are reported. The results are compared with corresponding values obtained from a CNDO calculation. We have also analyzed the theoretical polar tensors into the charge, charge flux, and overlap contributions. The effective term charges of hydrogen atom appeared to be transferable among the fluoromethane molecules.

Polarization Mode Coupling Constants in Solid-State Lasers

  • Park, Jong-Dae;Cho, Chang-Ho
    • The Journal of Natural Sciences
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    • v.17 no.1
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    • pp.31-37
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    • 2006
  • We have found that the polarization mode coupling between the orthogonally linearly polarized dual mode laser results from the anisotropy of dipole moments. Rate equation analysis demonstrated that high anisotropy in dipole moment components can give rise to law intrinsic mode coupling constants while isotropic dipole moment components give high intrinsic mode coupling constant. The populations at active ion sites are shown to self-organize the populations such that laser mode gain is constant adove threshold while the gain contributions from the each site adjust themselves with pump power.

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Analysis on Harmonics Characteristics of ELF Magnetic Fields Generated by Electric Appliances (가전기기 발생 극저주파 자계 고조파 특성 해석)

  • Min Suk-Won;Song Ki-Hyun;Yang Kwang-Ho;Ju Mun-No
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.54 no.1
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    • pp.31-37
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    • 2005
  • With biological effects by ELF(Extremely Low Frequency) magnetic field generated from power system, the transient magnetic field from electric appliances is a major issue presently. In this paper, we measured magnetic field distributions around electric appliances in view of harmonics and analyzed them by the use of an equivalent magnetic dipole moment method. This method was applied to 19 types of appliances, and their equivalent magnetic dipole moments and harmonic components were determined. The results show that this method is applicable to many appliances and the higher frequency magnetic field may induce higher current inside living bodies.

Dielectric Properties of Low Viscosity Silicone Oils with Degree of Polymerization (중합도에 따른 저점도 실리콘유의 유전 특성)

  • Cho, Kyung-Soon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.847-851
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    • 2014
  • The characteristics of dielectric constant and $tan{\delta}$ of low viscosity silicone oils with changing degree of polymerization were investigated. The result shows dipole loss mechanism at low temperature range. The dielectric loss in the range of low frequencies are predominantly of ionic nature with temperature increase. The peak of dielectric loss is the detrapping of the electrons which is were trapped in the localized level of the silicone oils at the frequency of 30 kHz. The increase of ionic conduction is attributed to the presence of ionizable oxidation products and their increased dissociation feature. The activation energy ${\Delta}H$ and dipole moment ${\mu}_d$ were increased whit increasing degree of polymerization.

Calculation of NMR Chemical Shift for a 3d$^1$ System in a Strong Crystal Field Environment of Tetrahedral Symmetry (1). Application of the Expansion Method for a Spherical Harmonics for Derivation of Overlap and the Dipole Moment Matrix Elements of $\mid$4p > Atomic Orbitals and Derivation of the Radial Integrals for the Hyperfine Interaction for $\mid$4p > Atomic Orbitals

  • Ahn, Sang-Woon;Kim, Dong-Hee;Choi, Chang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.7 no.4
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    • pp.299-304
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    • 1986
  • Master formulas for overlap integrals and the dipole moments involving |4p > atomic orbitals have been derived by the expansion method for spherical harmonics. The radial integrals for the hyperfine interaction have also been derived for |4p > atomic orbitals. The calculated values of the overlap integrals and dipole moment matrix elements by the expansion method for spherical harmonics for a hypothetical NO molecule are exactly in agreement with those of Mulliken's method. The radial integrals for the hyperfine interaction may be used to calculate the chemical shift for |4p > atomic orbitals.