• Title/Summary/Keyword: Dip Coating

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Photoelectrochemical Properties of TiO2 Electrode Prepared by the Sol-Gel Method (Sol-Gel법으로 제조된 TiO2 전극의 광전기 화학적 특성)

  • 김진희;이재훈;설용건;이태희
    • Journal of Energy Engineering
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    • v.3 no.1
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    • pp.36-43
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    • 1994
  • 광전기화학전지의 전극으로 TiO2 반도체 전극을 선택하여, sol 용액을 dip-coating 방법으로 티타늄 금속위에 입혀 만든 TiO2 필름의 광전기화학특성을 연구하였다. Dipping 횟수와 TiO2 필름의 두께간에는 선형적인 비례관계가 나타났으며, 15회 코팅하여 얻은 5.5$\mu\textrm{m}$에서 가장 큰 광전류값을 얻을 수 있었다. 전극의 최종열처리를 50$0^{\circ}C$에서 20분간 행하였을 때 광전류값이 가장 컸고, 열처리시간을 증가시키고, 열처리 온도가 50$0^{\circ}C$ 이상이 되면 광전류는 감소하였다. 유기첨가제로 HPC를 사용한 경우 sol 용액의 점도 및 제조된 전극의 광전류값이 가장 크게 나타났다.

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A study on the electrophotographic properties of ${\tau}-H_2P_c$/oxadiazole photoreceptor (III) (${\tau}-H_2P_c$/oxadiazole 유기이층막의 감광특성 연구 (III))

  • Oh, S.H.;Park, J.K.;Shin, T.H.;Kim, Y.J.;Park, G.B.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1397-1399
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    • 1994
  • The purpose of this study is to measure the electrophotographic characteristics of double-layered organic photoreceptor made by dip-coating method, and to evaluate an application for the laser beam printer drum. From the result, electrophotographic characteristics of the photoreceptor were depend on the thickness of the CTL and the initial surface potential.

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Fabricatoin and electrochemical property of 3-dimesional $LiMn_2O_4$ thin film (3차원 구조의 $LiMn_2O_4$ 박막전극의 제조 및 전기화학적 특성)

  • Park, Bo-Gun;Ryu, Jea-Hyeok;Park, Yong-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.64-65
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    • 2008
  • 3D microbattery에 사용할 수 있는 $LiMn_2O_4$ 3차원 박막전극을 제조하여 그 전기화학적 특성을 관찰하였다. 3차원 구조의 형성을 위하여 먼저 polystyrene(PS) microsphere를 platinum이 증착된 Si/$SiO_2$ 기판위에 dip-coating 방식으로 코팅시켜 template로 사용하였다. 그 위에 sol-gel법을 이용, 박막을 형성시킨 후 template 를 제거하는 방식으로 $LiMn_2O_4$ 3차원 박막전극을 형성하였는데 이때 solution은 Lithium acetylacetonate[$LiCH_3CO-CHCOCH_3$], Manganese(III) acetylacetonate [Mn$(CH_3COCHCOCH_3)_3$]를 source 물질로 1-butanol과 acetic acid를 solvent로 활용하여 제조하였다.

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Fabrication of 3-Dimensional LiMn2O4 Thin Film

  • Park, Bo-Gun;Ryu, Jea Hyeok;Choi, Won Youl;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.653-656
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    • 2009
  • 3-Dimensionally ordered macroporous $LiMn_2O_4$ thin film was prepared by a sol-gel and dip coating method on Pt/Ti/$SiO_2$/Si substrate. An opal structure consisting of mono dispersed polystyrene beads (300 nm) was used as a template. After solution containing Mn and Li precursors was coated on the template-deposited substrate, the template and organic materials in the precursors was removed by calcination at 400 ${^{\circ}C}$. And then the 3-dimensional $LiMn_2O_4$ thin film with spinel structure was fabricated by heat treatment at 700 ${^{\circ}C}$. The structural and electrochemical property was investigated by XRD, SEM and charge-discharge cycler.

Structural Characteristics of Barium Ferrite Thin Film (바륨페라이트 박막의 구조적 특성)

  • Byeon, Tae-Bong;Kim, Tae-Uk
    • Korean Journal of Materials Research
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    • v.7 no.5
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    • pp.423-430
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    • 1997
  • 졸-겔 dip coating법에 의해 제조한 바륨페라이트 박막의 미세구조와 결정학적인 구조 특성에 관해 조사하였다. 기판에 형성된 바륨페라이트 입자는 침상 형태의 입자들로 구성되어 있었으며, C축은 장축 방향이었고, 막 두께가 증가함에 따라 침상형 입자들은 기판에 평행하게 배향하는 경향을 나타내었다. 박막은 바륨페라이트층, Ba, Fe, SiO$_{2}$로 구성되어 있는 중간층, 그리고 기판층인 SiO$_{2}$층으로 구성되어 있었으며, 중간층과 SiO$_{2}$층간의 계면은 Ba 와 SiO$_{2}$간의 화합물로 구성되어 있었다. 침상 형태의 입자는 95$0^{\circ}C$에서 3시간 열처리하므로써 완전히 소실하였고, 130$0^{\circ}C$에서 3시간 열처리하므로써 c면이 기판에 평행하게 위치하는 완전한 육각판상 형태의 입자로 변화되었다.

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Batch-type fabrication process of YBCO coated conductor using oxide-precursor-based MOD method (산화물 전구체 기반의 MOD방법을 이용한 YBCO 고온초전도 선재의 batch-type 제조 공정)

  • Chung Kook-chae;Yoo Jai-moo;Ko Jae-Woong;Kim Young-Kuk
    • Progress in Superconductivity and Cryogenics
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    • v.7 no.3
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    • pp.9-12
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    • 2005
  • [ $Y_1Ba_2Cu_3O_{7-8}$ ] (YBCO) coated conductor has been fabricated by batch-type process using oxide-precursor-based metal-organic deposition (MOD) method. The batch-type process can be scaled up more simply to Produce long-length YBCO conductor than the reel-to-reel process. Also, it has less handling problems and is adequate to the ambient gas environment. In this work, YBCO oride powder was used as a starting precursor for MOD method. After reel-to-reel dip coating process, me ter-long-buffered metal tape was wound around a cylinder and underwent calcination and annealing processes. Annealed YBCO films showed good c-axis alignment and dense surface morphology with no cracks, but exhibited very low critical current density of $10^5\;A/cm^2$.

CONDUCTIVE SnO$_2$ THIN FILM FABRICATION BY SOL-GEL METHOD

  • Lee, Seung-Chul;Lee, Jae-Ho;Kim, Young-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.456-460
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    • 1999
  • Transparent conducting tin (IV) oxide thin films have been studies and developed for the electrode materials of solar cell substrate. Fabrication of tin oxide thin films by sol-gel method is process development of lower cost photovoltaic solar cell system. The research is focused on the establishment of process condition and development of precursor. The precursor solution was made of tin isopropoxide dissolved in isopropyl alcohol. The hydrolysis rate was controlled by addition of triethanolamine. Dip and spin coating technique were applied to coat tin oxide on borosilicate glass. The resistivity of the thin film was lower than 0.1Ω-cm and the transmittance is higher than 90% in a visible range.

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Characteristics of Zn-Ni Electrodeposition of 60 kgf/$\textrm{mm}^2$ Grade Transformation Induced Plastic Steel Sheets for Automotive Body (60 kgf/$\textrm{mm}^2$급 자동차용 변태유기소성강화강 Zn-Ni 전기도금 특성 연구)

  • Kim D. H.;Kim B. I.;Jeon Y. T.;Jeong Y. S.
    • Journal of the Korean institute of surface engineering
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    • v.37 no.5
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    • pp.263-272
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    • 2004
  • High strength steels such as transformation induced plastic steel, dual phase and solid solution Hardening have been developed and continuously improved due to the intensified needs in the automotive industry. But silicon and manganese in transformation induced plastic steels were known to exhibit harmful effects on galvannealing reaction by oxide film formed during heat treatment. Therefore, in this work, the applicability of Zn-Ni electrodeposition instead of hot dip galvannealed coating to transformation induced plastic steels was evaluated and optimum electroplating condition was investigated. Based on these investigations optimized electroplating conditions were proposed and Zn-Ni electrogalvanized steel sheet was produced by EGL (electrogalvanized line). Its perfomance properties for automotive steel was evaluated.

The corrosion behavior of galvanized steel sheets at the cut edges (용융아연도금강판의 단면부 부식특성)

  • 남궁성;허보영
    • Journal of the Korean institute of surface engineering
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    • v.34 no.4
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    • pp.297-302
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    • 2001
  • As GA (Hot dip galvannealed steel sheet) has good corrosion resistance, weldability and paintability as well as excellent formability, it's demand is rapidly increasing for automotive panels. The GA coated layers are composed of several kinds of brittle Fe-Zn Metallic compounds which are susceptible to powdering during the press forming, however, very careful controls of manufacturing conditions such as galvannealing heat-treatment or bath composition are essential to meet with the required quality of automotive use. In this study the required characteristics of automotive panel are practically surveyed in detail and the appropriate manufacturing conditions of galvannealing or bath composition have experimentally investigated by using the various analyzing and simulating equipments. The result in this study indicated that the corrosion resistance at the cut edges was improved by increasing of coating weight and decreasing of thickness of sheet steels.

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Effect of Skinpassing Conditions on the Surface Characteristics of Hot-dip Galvanized Steel Sheets (용융아연도금강판의 표면특성에 미치는 조질압연 조업조건의 영향)

  • 전선호
    • Journal of the Korean institute of surface engineering
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    • v.34 no.4
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    • pp.327-336
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    • 2001
  • The skinpassing conditions such as roll type, roll force and roll roughness of the work roll were evaluated to give the surface properties of the galvanized steel sheets that were required for automotive and to get rid of the surface defects that caused with the bad control of galvanized coating process parameters. The surface defects of the galvanized steel sheets such as the ripple mark and the scratch were completely removed as the roll force of SPM work roll was increased and the amount of the transfer of roll surface texture to the strip was also gained a lot. The image clarity of electro discharge textured (EDT) coated steel sheets before and after painting was higher than that of the bright (BRT) and shot blasted (SBT) coated steel sheets because of higher PPI value, lower waviness and uniform surface pattern. Since micro-craters transferred on the surface of the galvanized steel sheets played a role of nucleation sites of chromate reaction, Increase of micro-craters was bring to better corrosion resistance with the increase of the roll force and the use of EDT roll at the skin pass mill.

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