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ANTICORROSION PROPERTIES OF SIOC COATED SUS-316

  • Kim, Su-Ryong;Gwon, U-Taek;Kim, Jeong-Ju;Kim, Jong-Il;Kim, Yeong-Hui;Kim, Jeong-Il;U, Chang-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.34.2-34.2
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    • 2009
  • The ceramic coatings on metallic materials have attracted by many researchers due to the chemical inertness of ceramic materials. In such aspect, SiOC is a promising material tobe used as protective coating layer on metallic materials due to its outstanding thermal stability and chemical inertness. In this research, SiOC coating was carried out onto SuS-316 substrate using Cl free preceramic polymers such aspolyphenylcarbosilane. 20% of polymethylphenylsilane in cyclohexane solution was coated onto metal surface by dip coating method. Thermal oxidation was carried out at $200^{\circ}C$ for crosslink of the preceramic polymer and the sample was pyrolysized at $800^{\circ}C$ under argon to convert the preceramic polymer to amorphous SiOCx state. The microstructure of the SiOCx film after pyrolysis was investigated using FE-SEM. Corrosion resistance of SiOC coated SuS-316 substrate has been investigated using 5% HCl solution at 25, 40, 60 and $80^{\circ}C$ for 7days. The data revealed that the corrosion resistance increased with SiOC coating on SuS-316 substrate.

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A study on removing impurities in the zind bate for hot dip galvannealed coatings (합금화 용융아연 도금욕의 불순물 제거에 관한 연구)

  • 진영구
    • Journal of the Korean institute of surface engineering
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    • v.31 no.6
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    • pp.371-378
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    • 1998
  • The zind bate contaminated in the hot dip galvannealed operation was successfully by appling the dross formation mechanism ; the Fe content was lowered from 0.028% to 0.011% and the dress size was decreased from 15~20$\mu\textrm{m}$ to under 3$\mu\textrm{m}$. The cooled metal from CGL zinc bath during operation of the galvannealed steel strip was remelted in graphite crucible at the lab and agitated after increasing Al content from 0.14% to 0.16% with decreasing the molten metal temperature from $470^{\circ}C$to $445^{\circ}C$. The agitating was done by agitator and nitrogen. The molten was analyed by SEM and EDS. It was considered that the Fe and the bottom dross($FeZN_7$) could react with aluminium to from the float dress($Fe_2Al_5$) according to the molten metal temperature down and the float dress rise to the surface of the zine bath. So the Fe and dross in the bath could be romoved out of the bath. It was confirmed that the proper purication conditions of GA zine bath is 0.02% of Al increasing, bath temperature down from $460^{\circ}C$ to $450^{\circ}C$and agitator and nitrogen.

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Fabrication and Properties of Au fine Particles Doped ZrO2 Thin Films by the Sol-gel Method (졸-겔법에 의한 Au 미립자 분산 ZrO2 박막의 제조와 특성)

  • 이승민;문종수
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.475-480
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    • 2003
  • Nanocomposite of Au doped ZrO$_2$ films was prepared, which could be used as non-linear optic materials, selective absorption and transmission films. After heat treatment of prepared thin film by dip-coating method, the characteristics were investigated by X-ray diffraction, UV-VIS Spectrometer, Atomic Force Microscopy (AFM) and Scanning Electron Microscope (SEM). Film thickness was about 150 nm, the Au particle size was 15~35 nm. The thin film had a smooth surface roughness about 1.06 nm. Nonlinearity optics was found that films showed absorption peak at 600~650 nm visible region by plasma resonance of Au metal particles.

A Study on the Eutrophication in the Keum River (금강의 부영양화 현상에 관한 연구)

  • 유선재;김종구;권태연;이석모
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.155-160
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    • 1999
  • To investigate the water quality characteristics and eutrophication of the Keum River, survey were conducted on samples collected from 6 stations in Aug. and Oct. in 1995 and Jan. and May in 1996. The results were summarized as follows ; Concentration of pollutants were in the range of 1.74~6.35(mean 3.81)mg/$\ell$for BOD and 1.98~8.21(5.14)mg/$\ell$for COD and 1.46~51.94(18.52)g/$\ell$for TSS. Water quality were evaluate to be 2~3 grade of station 1 and other stations were 3~4 grade of water quality criteria. The concentration of nutrients were in the range of 55.2~735.3(309.3)$\mu\textrm{g}$-at/$\ell$for Dissolved inorganic nitrogen(DIN) and 0.06~6.03(2.80)$\mu\textrm{g}$-at/$\ell$ for dissolved inorganic phosphate(DIP). Nutrient concentrations in Keum River were usually high and the DIN/DIP ratio ranged from 72 to 2648. The concentration of chlorophyll-a was in the range of 1.1~143.7(44.3)mg/㎥. Chlorophyll-a concentration were high 10mg/㎥ except station 1, which is the value of eutrophication criteria by EPA. Correlations between nutrients and chlorophlly-a were not significant. According to eutrophication evaluation, Keum river was equivalent to the eutrophic state.

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Application of Taguchi Method and Orthogonal Arrays for Optimization of Adhesion of $SrZrO_3$ Coatings on Ag/Bi(2223) Tapes

  • Lee, Se-Jong;Lee, Deuk-Yong;Song, Yo-Seung;Kim, Bae-Yeon
    • Progress in Superconductivity and Cryogenics
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    • v.5 no.1
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    • pp.13-16
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    • 2003
  • Adhesion of $SrZrO_3$ resistive oxide barrier on Ag sheathed Bi(2223) tapes prepared by the sol-gel and dip-coating method was evaluated with an aid of Taguchi method and Lie($2^1{\times}3^7$) orthogonal arrays to determine the optimal process combination of levels of factors that best satisfy the bigger is better quality characteristic (QC=B). For analyses of results statistical calculations such as average and analysis of variance (ANOVA) were employed to analyze the results for improving the performance qualities of the dip-coated $SrZrO_3$ film. Experimentally, the performance of the films was evaluated in terms of bond strength by varying Sr/Zr moi ratio (A), amount of organic vehicle additives (B), drying temperature (C) and time (D), heat treatment temperature (E) and time (F), respectively. The optimal combination of levels of factors was determined to be $A_3B_2C_3D_2E_1F_3$ having a 90% confidence level.

Development and Application of Protein-Protein interaction Prediction System, PreDIN (Prediction-oriented Database of Interaction Network)

  • 서정근
    • Proceedings of the Korean Society for Bioinformatics Conference
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    • 2002.06a
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    • pp.5-23
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    • 2002
  • Motivation: Protein-protein interaction plays a critical role in the biological processes. The identification of interacting proteins by bioinformatical methods can provide new lead In the functional studies of uncharacterized proteins without performing extensive experiments. Results: Protein-protein interactions are predicted by a computational algorithm based on the weighted scoring system for domain interactions between interacting protein pairs. Here we propose potential interaction domain (PID) pairs can be extracted from a data set of experimentally identified interacting protein pairs. where one protein contains a domain and its interacting protein contains the other. Every combinations of PID are summarized in a matrix table termed the PID matrix, and this matrix has proposed to be used for prediction of interactions. The database of interacting proteins (DIP) has used as a source of interacting protein pairs and InterPro, an integrated database of protein families, domains and functional sites, has used for defining domains in interacting pairs. A statistical scoring system. named "PID matrix score" has designed and applied as a measure of interaction probability between domains. Cross-validation has been performed with subsets of DIP data to evaluate the prediction accuracy of PID matrix. The prediction system gives about 50% of sensitivity and 98% of specificity, Based on the PID matrix, we develop a system providing several interaction information-finding services in the Internet. The system, named PreDIN (Prediction-oriented Database of Interaction Network) provides interacting domain finding services and interacting protein finding services. It is demonstrated that mapping of the genome-wide interaction network can be achieved by using the PreDIN system. This system can be also used as a new tool for functional prediction of unknown proteins.

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A Study on the Depth Dependent Characteristics of Earthquake Ground Motions in a Layered Ground Medium Using Point Source Models (점진원모델을 사용한 층상지반에서의 깊이에 따른 지반운동 특성 변화연구)

  • Koh, Hyun Moo;Kim, Jae Kwan;Kwon, Ki Jun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.453-462
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    • 1994
  • Variation of seismic wave field in a multi-layered attenuating elastic half space is studied by the propagator matrix method and point source models of which fault-slip functions are defined as ramp functions. In this paper, the earth is modeled as being composed of horizontally stratified layers, with uniform material properties for each layer. The partial differential equations for the seismic motion in each layer are solved using a Fourier Hankel transform approach. Time histories and frequency contents of accelerations and displacements due to a vertical dip-slip and strike-slip point source located in the underlain half space are calculated at the layer interfaces using the developed programs and their characteristics are represented.

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Dependence of Magneto-Impedence on Magnetizing Angle from Amorphous $Co_{66}Fe_4NiB_{14}Si_{15}$ Ribbon Axis (자화방향에 따른 비정질 $Co_{66}Fe_4NiB_{14}Si_{15}$ 리본의 자기임피던스 효과)

  • 유권상;김철기;윤석수;양재석;손대락
    • Journal of the Korean Magnetics Society
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    • v.7 no.3
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    • pp.134-139
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    • 1997
  • Magneto-impedence (MI) were measured in amorphous $Co_{66}Fe_4NiB_{14} Si_{15}$ ribbons at 100 kHz as a function of the angle from ribbon axis. The samples were prepared using etching method, with the angle deviated from ribbon axis, 0$^{\circ}$, 30$^{\circ}$, 45$^{\circ}$, 60$^{\circ}$ and 90$^{\circ}$. The MI measured in 60$^{\circ}$ sample increased with the increasing magnetic fields. The dip in profile appears at H = 0 above the angle of 30$^{\circ}$. The maximum values of MI and their dips are increased with the cutting angle, but the maximum value of MI decreased at 90$^{\circ}$. The increase of MI with the angle was analyzed in terms of the transverse magnetic permeability.

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Improvement of Open Circuit Voltage (OCV) depending on Thickness of GDC Electrolyte of LT-SOFCs (저온형 SOFC용 GDC 전해질 두께에 따른 Open Circuit Voltage 향상)

  • Ko, Hyun-Jun;Lee, Jong-Jin;Hyun, Sang-Hoon
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.195-198
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    • 2010
  • It has been considered to apply GDC ($Gd_{0.1}Ce_{0.9}O_{1-X}$) for low-temperature SOFC electrolytes because it has higher ionic conductivity than YSZ at low temperature. However, open circuit voltage with using GDC ($Gd_{0.1}Ce_{0.9}O_{1-X}$) electrolyte in SOFCs, becomes lower than using YSZ (8 mol% Yttria stabilized Zirconia) electrolyte because GDC has electronic conductivity. In this work, the effect of changing GDC electrolyte thickness on the open circuit voltage has been investigated. Ni-GDC anode-supported unit cells were fabricated as follows. Mixed NiO-GDC powders were pressed and pre-sintered at $1200^{\circ}C$. And then, GDC electrolyte material was dip-coated on the anode and sintered at $1400^{\circ}C$. Finally the LSCF-GDC cathode material was screen-printed on the electrolyte and sintered at $1000^{\circ}C$. Electrolyte thickness was controlled by the number of dip-coating times. Open circuit voltage was measured depending on electrolyte thickness at $650^{\circ}C$ and found that the thicker GDC electrolyte was, the better OCV was.

The Applications of Sol-Gel Derived Tin Oxide Thin Films

  • Park, Sung-Soon;John D. Mackenzie
    • The Korean Journal of Ceramics
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    • v.2 no.1
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    • pp.1-10
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    • 1996
  • Transparent conducting $SnO_2$-based thin films have been coated on float substrates such as fused quartz, and ceramic fiber cloths such as the Nexel and E-glass cloth from tin alkoxides by the sol-gel technique. Also, thin films of alternating layers of $SnO_2$ and $SiO_2$ have been fabricated by dip coating. The sheet resistance and average visible transmittance of the films were investigated in the aspect of the applications as transparent electrodes such as liquid crystal displays, photo-detectors and solar cells. The Nextel and E-glass cloths coated with antimony-doped tin oxide (ATO) had sheet resistance of as low as $20 \;ohm/{\Box}$ and $120ohm/\;{\Box}$, respectively. The promotion effects of additives as $La_2O_3$ and Pt on the ethanol gas sensing properties of the films were investigated in the aspects of the applications as an alcohol sensor and a breath alcohol checker. Possible evidence of quantum well effects in the oxide multilayers of $SnO_2$ and $SiO_2$ was investigated.

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