• 제목/요약/키워드: Dip

검색결과 1,381건 처리시간 0.022초

Hydrogen Permeation of SiC-CeO2 Composite Membrane by Dip-coating Process

  • Park, Jihye;Jung, Miewon
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.485-488
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    • 2013
  • A SiC-$CeO_2$ composite membrane was successfully fabricated using an ally-hydridopolycarbosilane (AHPCS) binder and treated by dip-coating at 60 times with a $CeO_2$ sol solution. The dip-coated SiC membrane was calcined at 773 K and then sintered at 1173 K under an air atmosphere. The coated membrane was characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and a BET surface analysis. The difference in permeation performance between $H_2$ and CO gases was measured by varying the temperature. The permeation flux of $H_2$ on the SiC membrane with layered $CeO_2$ was obtained as $8.45{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The CO permeation flux was $2.64{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The reaction enthalpy (${\Delta}H^{\circ}$) for the hydrogen permeation process was calculated as -7.82 J/mol by Arrhenius plots.

염료감응형 태양전지 투명전도성 막의 표면처리를 통한 계면 접촉 향상 및 재결합 방지 연구 (A Study on the Improvement of the Interface Contact and the Prevention of the Charge Recombination by the Surface Treatment of Transparent Conductive Oxide in Dye-sensitized Solar Cell)

  • 서현웅;홍지태;손민규;김진경;신인영;김희제
    • 전기학회논문지
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    • 제58권11호
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    • pp.2214-2218
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    • 2009
  • Dye-sensitized solar cell (DSC) has been considered as a possible alternative to current silicon based p-n junction photovoltaic devices due to its advantages of high efficiency, simple fabrication process and low production cost. Numerous researches for high efficient DSC in the various fields are under way even now. Among them, the compact layer, which prevents the back electron transfer between transparent conductive oxides and the redox electrolyte, is fabricated by various methods such as a ZnO dip-coating, $TiCl_4$ dip-coating, and Ti sputtering. In this study, we tried to fabricate the $TiO_2$ compact layer by the spin-coating method using aqueous $TiCl_4$ solution. The effect of the spin-coating method was checked as compared with conventional dip-coating method. As a result, DSC with a spin-coated compact layer had 33.4% and 6% better efficiency than standard DSC and DSC with a dip-coated compact layer.

평판형 광-바이오센서 (Planar-Type Optical Bio-Sensor)용 2차원 광자결정 제작을 위한 Dip-Pen Nanolithography 공정 연구 (A Study on Dip-Pen Nanolithograpby Process to Fabricate 2D Pbotonic Crystal for Planar-Type Optical Bio-Sensor)

  • 김준형;이종일;이현용
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.381-383
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    • 2005
  • 바이오센서 응용을 위한 대칭 및 비대칭 마하젠더 간섭계 광도파로 소자의 설계, 제작 및 광학적 응답특성을 평가하였다. 설계 제작된 광도파로 소자의 압력광원은 각각 1550nm와 632.8nm이고, 코어와 클래딩의 굴절률차는 0.45 $\Delta$%로 설계 제작하였다. 센서부(상위 클래드)의 금 박막의 미소 굴절률 변화에 따른 TE, TM모드의 특성을 분석하였다. 센서의 보다 높은 감도 개선을 위한 나노-광자결정 구조가 주목받고 있는데, 광자결정 구조의 구현를 위한 리소그래피 공정은 높은 분해능과 신뢰성 있는 나노스케일의 공정이 요구된다. 광-바이오센서의 감도 개선을 위해 센서부 표면에 2차원 나노-광자결정 배열을 제안하고 이를 구현하기 위한 Dip-Pen Nanolithography 공정에 대해 고찰하였다.

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Favorable driving direction of double shield TBM in deep mixed rock strata: Numerical investigations to reduce shield entrapment

  • Wen, Sen;Zhang, Chunshun;Zhang, Ya
    • Geomechanics and Engineering
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    • 제17권3호
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    • pp.237-245
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    • 2019
  • In deep mixed rock strata, a double shield TBM (DS-TBM) is easy to be entrapped by a large force during tunneling. In order to reduce the probability of the entrapment, we need to investigate a favorable driving direction, either driving with or against dip, which mainly associates with the angle between the tunneling axis and strike, ${\theta}$, as well as the dip angle of rock strata, ${\alpha}$. We, therefore, establish a 3DEC model to show the changes of displacements and contact forces in mixed rock strata through LDP (longitudinal displacement profile) and LFP (longitudinal contact force profile) curves at four characteristic points on the surrounding rock. This is followed by a series of numerical models to investigate the favorable driving direction. The computational results indicate driving with dip is the favorable tunneling direction to reduce the probability of DS-TBM entrapment, irrespective of ${\theta}$ and ${\alpha}$, which is not in full agreement with the guidelines proposed in RMR. From the favorable driving direction (i.e., driving with dip), the smallest contact force is found when ${\theta}$ is equal to $90^{\circ}$. The present study is therefore beneficial for route selection and construction design in TBM tunneling.

담지 방법을 통해 유리 기판 위에 형성된 탄소나노튜브 네트워크의 전기적 및 광학적 특성 (Electrical and Optical Properties of Carbon Nanotube Networks Formed on Glass Substrate by Dip-Coating Method)

  • 장의윤;강태준;임형욱;김대원;김용협
    • Composites Research
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    • 제21권1호
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    • pp.8-15
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    • 2008
  • 담지 방법을 통해 유리 기판 위에 단일벽탄소나노튜브 네트워크를 형성하였고, 코팅 공정변수(담지 횟수, 콜로이드 용액의 농도, 기판의 인출 속도)에 따른 탄소나노튜브 네트워크의 전기적 및 광학적 특성 변화를 관찰하였다. 그 결과 네트워크의 면저항 및 투과도는 코팅 공정변수들에 의해 민감하게 조절됨을 확인할 수 있었다. 탄소나노튜브 네트워크는 매우 균일한 면저항을 보이는 동시에, 가시광선 영역에서 우수한 투과도 특성을 보였다.

솔-젤 Dip Coating에 의한 Sb-doped $SnO_2$ 투명전도막의 제조 및 특성 (Fabrication of Sb-doped $SnO_2$ transparent conducting films by sol-gel dip coating and their characteristics)

  • 임태영;오근호
    • 한국결정성장학회지
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    • 제13권5호
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    • pp.241-246
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    • 2003
  • ATO(antimony-doped tin oxide) 투명전도막을 sol-gel dip coating 방법에 의해 $SiO_2$/glass 기판 위에 성공적으로 제조하였다 ATO막의 결정상은 $SnO_2$상임을 확인하였고, 막의 두께는 withdrawal speed를 50 mm/minute로 코팅시 약 100 nm/layer였다. $SiO_2$/glass 기판 위에 코팅한 400 nm두께의 ATO 박막을 질소분위기에서 annealing한 후, 측정한 광 투과율과 전기 저항치는 각각 84%와 $5.0\times 10^{-3}\Omega \textrm{cm}$였다. 이러한 특성은 $SiO_2$막이 Na 이온의 확산을 제어하여 $Na_2SnO_3$ 및 SnO와 같은 불순물의 형성을 억제하고, 막 내부의 Sb의 농도와 $Sb^{3+}$에 대한 $Sb^{5+}$의 비를 증가시키는데 기여했기 때문으로 확인되었다. 또한, $N_2$ annealing은 $Sb^{5+}$뿐만 아니라 $Sn^{4+}$를 환원시킴으로써 전기전도도를 향상시킴을 확인하였다.

카테너리 각도를 이용한 가공송전도체의 이도 추정 (Dip Estimation for Overhead Transmission Conductor using Catenary Angle)

  • 김성덕;손홍관;장태인
    • 조명전기설비학회논문지
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    • 제21권5호
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    • pp.112-119
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    • 2007
  • 가공송전 도체는 정상 동작조건 하에서 전력회사의 선로 설계지침에 규정된 지상고를 안정범위 내에서 항상 유지할 수 있어야 한다. 따라서 새로운 선로를 건설하거나 노화도체의 장력을 다시 조정하거나 또는 전력용량을 최대화하기 위해 동적송전용량을 모니터링하는 경우에, 도체 이도를 측정/또는 모니터링하는 것은 매우 중요하다. 본 연구에서는 도체의 카테너리 각도로 이도 및 장력을 추정하기 위한 새로운 방법을 제안한다. 가공송전선로의 대부분의 도체들은 전형적인 카테너리 곡선을 나타내므로 철탑 측의 카테너리 각도로부터 도체의 카테너리 곡선을 유일하게 결정할 수 있다. 이 카테너리 곡선을 토대로 도체의 이도나 수평장력을 쉽게 추정할 수 있다. 몇 가지 시뮬레이션과 간단한 실험 결과를 통하여 제안된 방법이 가공송전선의 도체 이도와 장력을 측정/또는 모니터링하는데 효과적으로 사용될 수 있음을 확인하였다.

물질순환 모델을 이용한 마산만의 질소, 인 수지 산정 (The Estimation of N, P mass Balance in Masan Bay using a Material Cycle Model)

  • 김동명;박청길;김종구
    • 한국환경과학회지
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    • 제7권6호
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    • pp.833-843
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    • 1998
  • It is noted that the red tides and the oxygen-deficient water mass are extensively developed in Masan Bay during summer. The nutrients mass balance was calculated in Masan Bay, using the three-dimensional numerical hydrodynamic model and the material cycle model. The material cycle model was calibrated with the data obtained on the field of the study area in June 1993. The nutrients mass balance calculated by the combination of the residual currents and material cycle model results showed nutrients of surface and middle levels to be transported from the inner part to the outer part of Masan Bay, and nutrients of bottom level to be transported from outer part to inner part of Masan Bay. The uptake rate of DIN in the box A1(surface level of inner part) was found to be 337. 5mg/$m^3$ㆍday, the largest value in all 9 boxes and that of DIP was found to be 18.6mg/$m^3$ㆍday in box A1, and the regeneration rate of DIN was found to be 78.2mg/$m^3$ㆍday in the box A3(bottom level of inner part), and that of DIP was found to be 18.6mg/$m^3$ㆍday in box A1. The regenerations of DIN and DIP in the water column of the entire Bay were found to be 7.66ton/day and 760kg/day, respectively. And the releases of DIN and DIP from the sediments of the entire Bay were found to be 2.86ton/day and 634kg/day, respectively. The regeneration rate was 2.5 times as high as the release rate in DIN, and 1.2 times in DIP. The results of mass balance calculation showed not only the nutrients released from the sediments but the nutrients regenerated in water column to be important in the control and management of water quality in Masan Bay.

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Stepwise Inertial Control of a Doubly-Fed Induction Generator to Prevent a Second Frequency Dip

  • Kang, Mose;Lee, Jinsik;Hur, Kyeon;Park, Sang Ho;Choy, Youngdo;Kang, Yong Cheol
    • Journal of Electrical Engineering and Technology
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    • 제10권6호
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    • pp.2221-2227
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    • 2015
  • To arrest a frequency nadir, a stepwise inertial control (SIC) scheme generates a constant active power reference signal of a wind turbine generator (WTG) immediately after a disturbance and maintains it for the predetermined time. From that point, however, the reference of a WTG abruptly decreases to restore the rotor speed for the predefined period. The abrupt decrease of WTG output power will inevitably cause a second frequency dip. In this paper, we propose a modified SIC scheme of a doubly-fed induction generator (DFIG) that can prevent a second frequency dip. A reference value of the modified SIC scheme consists of a reference for the maximum power point tracking control and a constant value. The former is set to be proportional to the cube of the rotor speed; the latter is determined so that the rotor speed does not reach the minimum operating limit by considering the mechanical power curve of a DFIG. The performance of the modified SIC was investigated for a 100 MW aggregated DFIG-based wind power plant under various wind conditions using an EMTP-RV simulator. The results show that the proposed SIC scheme significantly increases the frequency nadir without causing a second frequency dip.

수치모델을 이용한 와편모조류 Alexandrium tamarense, Gymnodinium catenatum 및 규조류 Skeletonema costatum의 종간 경쟁에 미치는 용존태 유기인의 영향 (Use of n Mathematical Model to Assess the Effects of Dissolved Organic Phosphorus on Species Competition Among the Dinoflagellates Alexandrium tamarense and Gymnodinium catenatum and the Diatom Skeletonema costatum)

  • 오석진;양한섭;산본민차
    • 한국수산과학회지
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    • 제40권1호
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    • pp.39-49
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    • 2007
  • Species competition among the toxic dinoflagellates Alexandrium tamarense and Gymnodinium catenatum and the diatom Skeletonema costatum was simulated using a mathematical model. Prior to the model simulation competition experiments using the three species were conducted to obtain data for validation by the simulation model. S. costatum dominated at a density of ${\sim}10^{4}\;cells/mL$ compared to the other species in the medium with dissolved inorganic phosphorus (DIP). The growth of S. costatum was also stimulated by the addition of dissolved organic phosphorus (DOP), such as uridine-5-monophosphate (UMP) or glycerophosphate (Glycero-P), although this species is unable to take up DOP. This implies that the growth of S. costatum may be supported by DIP, which is hydrolyzed by alkaline phosphatase produced from A. tamarense and G. catenatum. The species competition model was run assuming the environmental conditions of northern Hiroshima Bay, Japan, during spring and summer. G. catenatum increased in cell density and neared the level of S. costatum at the end of the calculation. In the sensitivity analyses by means of doubling and halving parameters, depleted DIP had little effect on the cell density of G. catenatum. However the growth of A. tamarense and S. costatum was significantly affected by changes in the parameter values. These results indicate that if DIP depletion is ongoing, species that have a large phosphate pool in their cells, such as G. catenatum, will predominate in the community.