• 한국구조물진단유지관리공학회 논문집
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• 제26권6호
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• pp.120-127
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• 2022

질소산화물(NOx)은 대기오염의 주요 인자로 일산화질소와 이산화질소의 형태로 존재하며 인체에 유해하다. 최근 대기 중 NOx를 제거하기 위한 많은 연구가 진행되고 있으며, 이러한 노력은 건설재료 분야에서도 동일하다. NOx는 광촉매 반응을 이용하여 효율적으로 제거할 수 있는 것으로 알려져 있다. 본 연구에서는 활성탄(AC)과 이산화타이타늄(TiO₂)을 이용한 폼 복합재의 NOx 제거성능을 조사하였다. AC는 폼 복합체의 비표면적을 증가시켜 TiO₂의 광촉매 반응 효율을 향상시켰다. 본 연구에서는 AC의 혼합율을 주요 변수로 하여 폼 복합체를 제조하였다. 제조된 시험체를 이용하여 ISO-22197-1에 제시된 시험방법에 따라 NOx 제거성능을 평가하였다. 폼 복합체의 비표면적은 AC 함량에 따라 증가하는 경향을 나타내었으나 15% 이상에서는 감소하였다. 또한 AC 혼입률이 15%일 때 NOx 제거 효율이 가장 높았다.

• 한국환경보건학회지
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• 제30권5호
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• pp.417-426
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• 2004

We investigate changing characteristics and concentration distribution of ambient air quality using data from which obtained local ambient air monitoring network and local meterological measuring sites in Gwangju area from January to December in 2003. Sulfur dioxide ($SO_2$) showed that increase from 8 AM and decrease in 6 PM but, it was not drastically changed concentration. it also 0.010 ppm in 1995 from at this time it's decrease step by step and than some constant in year 2001 to 2003. Nitrogen dioxide ($NO_2$) concentration was showed highest peak in 10 AM and increase again at 6 PM. And also it showed peak concentration (0.026 ppm) in 2001 and decreased from after that times. Ozone was showed peak concentration in 1 PM and Nitrogen dioxide was ditto in 10 AM from this data, we can conclude that this two article ws showed chemical reaction by 3 to 5 hours. There was no case of Ozone alarm in Gwangju area since 1995, but it showed highest ozone concentration (over 0.070 ppm) in May and June of the year and 2 to 4 PM of the day and sometimes it showed increase at the dawn. Ozone product optimum condition was that air temperature is over $25^{\circ}C$, no rain and increase solar radiation (over $20MJ/m^2$) and no wind or below 2.0 m/s wind speed.

• 공학논문집
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• 제2권1호
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• pp.147-149
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• 1997

이산화질소는 Linde Molecular Sieve 칼럼에 흡수된 물에 의해 일산화질소로 급속히 전환된다. 합성된 파형은 칼럼에 도입된 순수 일산화질소의 것과 구별할 수 없는 것이다. 따라서 저비점 일산화질소로 전환함으로써 유기분배액의 산화의 복잡성은 미연에 방지된다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.117-121
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• 2006

Non-thermal plasma technology has many applications in various areas. One of the applications is regenerating diesel particulate filter (DPF). DPF is a widely applied device to control the particulate emission of diesel engines. But it needs periodic removal of clogged soot for the smooth running of engine. Conventional high-temperature removal processes easily leads to the breakage of DPF. Herein, low-temperature plasma formed in a dielectric barrier discharge (DBD) reactor was used to form active oxidants such as ozone and nitrogen dioxide. Experimentally, the effects of discharge power and frequency on the performance of DBD reactor were studied. Two oxidants, $O_3$ and $NO_2$, were synthesized and used for incinerating soot in the used DPF. Performances of the two oxidants on the reduction of soot were compared, and it was found that $NO_2$ is more effective than $O_3$ for getting rid of soot

• 한국대기환경학회지
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• 제20권5호
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• pp.583-591
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• 2004

In this study, methodologies for the rational organization of air pollution monitoring network were examined by understanding the characteristics of temporal and spatial distribution of secondary air pollution, whose significance would increase hereafter. The data on $O_3$ and $NO_2$ concentrations during high ozone period in 1998~1999 recorded at the nine air pollution monitoring station in Busan were analysed using principal component analysis (PCA) and cumulative semivariogram. It was found that the ozone concentration was deeply associated with the daily emission characteristics or the $O_3$ precusors, and nitrogen dioxide concentration largely depends on the emission strength of regional sources. According to the spatial distribution analysis of ozone and nitrogen dioxide in Busan using cumulative semivariograms, the number of monitoring stations for the secondary air pollution can be reduced in east-west direction, but reinforced in north-south direction to explain the spacial variability. More scientific and rational relocation of air pollution monitoring network in Busan would be needed to investigate pollution status accurately and to plan and implement the pollution reduction policies effectively.

• 한국대기환경학회지
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• 제24권2호
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• pp.143-152
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• 2008

This study investigates the variation and spatial distribution of nitrogen dioxide($NO_2$) concentrations measured with passive diffusive samplers at 40 curbside points in Daejeon. Average $NO_2$ concentration was $39.8{\pm}18.0\;ppb$ (n=1,127) and the significant difference in concentrations by regional groups (Dong-gu, Jung-gu, Seo-gu, Daedeok-gu, Yuseong-gu) was not observed. The frequency distribution of $NO_2$ concentration was found to be a normal distribution with the high frequency in the concentration range of 30 to 40 ppb (20 to 25%). Average $NO_2$ concentration measured during the rainy periods was lower than that measured during the non-rainy periods and the decrease of concentration by rainfall was about 16% (7 ppb). The variation of $NO_2$ concentrations measured by passive diffusive samplers during the sampling period was similar to that continuously measured at the air quality monitoring station.

• 한국대기환경학회지
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• 제17권3호
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• pp.251-258
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• 2001

Indoor and outdoor nitrogen dioxide(NO$_2$) concentrations of 122 houses were measured and compared with measurements of personal NO$_2$ exposure simultaneously . Time activity patterns were used to determine the impacts on NO$_2$ exposure assessment and time weighed average model to estimate the personal NO$_2$ exposure. Most people spent their times more than 80% of indoor and more than 50% in home, respectively. Personal NO$_2$ esposure was found to be significantly associated with both indoor NO$_2$ concentration(r=0.70) and outdoor NO$_2$ concentration (r=0.68). Using time weighted average model, personal NO$_2$ exposure was estimated with NO$_2$ measurements in indoor home, indoor workplace and outdoor home. The estimated NO$_2$ measurements were significantly correlated with measured personal exposures(r=0.69, N=122). For the difference between measured and estimated NO$_2$ exposures by multiple regression analysis showed that NO$_2$ concentrations in near workplace and other outdoors of no NO$_2$ measurements affected the personal NO$_2$ exposures(p=0.023).

• 환경위생공학
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• 제15권4호
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• pp.134-141
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• 2000

The person' spending time in underground s[aces within indoor environment show a tendency to increase every year, but in Korea, levels and sources of pollutant in underground spaces have not been well-characterized. Therefore, as part or a larger indoor environmental study, conducted at subway station in Seoul, nitrogen dioxide was measured using passive samplers in 16 subway stations, 2 tunnels and 70 workers of subway station. The mean concentrations of nitrogen dioxide in subway stations were $27.87{\pm}7.15$ ppb at station office, $35.76{\pm}8.35$ ppb at platform, $52.60{\pm}13.04$ ppb at outdoor, respectively, and the Indoor/Outdoor ratio were 0.49~0.93. The mean concentrations of nitrogen dioxide in tunnels were $44.91{\pm}4.67$ ppb in Chunggye-Nowon tunnel with a single track, $42.55{\pm}3.33$ ppb in Mokkol-Taenung tunnel with double track, respectively, and as a result of t-test, a single track levels were higher than double track levels(p<0.05). The mean personal exposure of the subject of station workers was $29.40{\pm}9.75$ ppb.

• 한국환경보건학회지
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• 제34권3호
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• pp.183-187
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• 2008

Indoor air quality can be affected by indoor sources, ventilation, decay, and outdoor levels. Various indoor and out-door combustion sources produce nitrogen dioxide ($NO_2$), which is a by-product of high temperature fossil fuel combustion. Especially, the presence of gas ranges and smoking have been identified as major factors contributing to indoor $NO_2$ exposures. In this study, we compared an industrial complex area with a country area by assessing the personal exposure to $NO_2$with measurements of indoor and outdoor $NO_2$ levels in residences and by house characteristics and questionnaire. Personal exposure concentrations were significantly correlated with indoor $NO_2$ concentrations of residences in both the industrial complex area and the country area with correlation coefficients of 0.561 and 0.664, respectively, compared to outdoors. Multiple regression analysis, indicated that indoor $NO_2$ levels in residences were only affected by outdoor levels (p = 0.000) in spite of higher indoor sources such as smoking. Therefore, it is suggested that outdoor air quality as well as indoor air quality should be considered in the reduction of the personal exposure to air pollutants.

• 멤브레인
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• 제17권2호
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• pp.134-139
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• 2007

동일 운전 조건에서 폴리이서술폰 중공사 분리막을 이용하여 혼합 기체로부터 이산화탄소 분리 실험과 수치해석으로 얻어진 결과를 비교하였다. 순수한 기체의 투과도로부터 구한 이상 선택도를 활용한 예측값과 실험값이 많은 차이 가 있음을 확인할 수 있었다. 그러나 이산화탄소 투과도와 선택도를 혼합 기체 분리 실험 결과로부터 구한 후 공급 이산화탄소 몰 분율, 공급 압력과 투과측 압력의 함수로서 투과도와 선택도를 얻을 경우 수치해석 예측값과 실험값이 잘 일치하는 것을 확인하였다.