• 제목/요약/키워드: Diffusion theory

검색결과 482건 처리시간 0.025초

Nonequilibrium Distribution Function Theory of Many-Particle Effects in the Reversible Reactions of the Type A+B ↔ C+B

  • Lee, Jin-Uk;Uhm, Je-Sik;Lee, Woo-Jin;Lee, Sang-Youb;Sung, Jae-Young
    • Bulletin of the Korean Chemical Society
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    • 제26권12호
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    • pp.1986-1990
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    • 2005
  • We study the relaxation kinetics of reversible reactions of the type A + B $^\leftarrow_\rightarrow$ C + B by applying the manyparticle kernel theory, which we have developed to investigate many particle effects on general diffusioninfluenced reactions. It is shown that for the target model, where A and C molecules are immobile and their interconversion is induced by the encounter with the B molecules that are present in much excess, the manyparticle kernel theory gives a result that coincides with the known exact result.

극초음속 희박유동 해석을 위한 축대칭 다화학종 GH 방정식의 개발 (EVELOPMENT OF AXISYMMETRIC MULTI-SPECIES GH EQUATION FOR HYPERSONIC RAREFIED FLOW ANALYSES)

  • 안재완;김종암
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.84-91
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    • 2008
  • Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; O$_2$, N$_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.

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극초음속 희박유동 해석을 위한 축대칭 다화학종 GH 방정식의 개발 (EVELOPMENT OF AXISYMMETRIC MULTI-SPECIES GH EQUATION FOR HYPERSONIC RAREFIED FLOW ANALYSES)

  • 안재완;김종암
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년 추계학술대회논문집
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    • pp.84-91
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    • 2008
  • Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; $O_2,\;N_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.

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인지적 몰입이 개인의 기술 수용에 미치는 영향: MP3 플레이어에 대한 실증 연구 (The Effect of Cognitive Absorption on the Individual Intention of Technology Acceptance: An Empirical Study on the MP3 Player)

  • 김보연;이상근;강민철
    • Asia pacific journal of information systems
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    • 제16권1호
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    • pp.45-69
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    • 2006
  • Technology Acceptance Model (TAM) has been widely used to predict user's behavior to accept the technology. Prior researches have been mainly focused on innovation constructs such as perceived usefulness and perceived ease of use. However, very little research has been conducted to understand individual mental beliefs in technology acceptance and imitation influence. This study integrates Technology Acceptance Model (TAM), Flow Theory (FT) and Diffusion of Innovation Theory (DIT). This paper indicates that imitation context, cognitive absorption (CA) based Flow theory and innovation context are the three important factors influencing user acceptance of information technologies. The proposed model has been tested among 232 users of MP3 players. Results showed that innovation context and cognitive absorption have positive influences on intention to use technology. Not all factors of the imitation context have direct effect on intention to use. However, we found that imitation context has positive influence on intention to use technology through cognitive absorption.

표본(標本)·근결(根結) 이론과 임상응용에 관한 고찰(考察) (A Literature Study on PyoBon·GeunGyul Theory)

  • 장준혁;김경호
    • Journal of Acupuncture Research
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    • 제17권1호
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    • pp.175-187
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    • 2000
  • PyoBon GeunGyul - one of the twelve regular meridians theory - play a important role on the principle of point selection and point prescription in acumoxibustion. PyoBon explain the connection of the concentration and diffusion of channel qi, GeunGyul explain the relation of both poles of channels flow. So, Geun and Bon means the starting point of channel qi, and Pyo and Gyul means the terminal point of channel qi. But the flow of channel qi on PyoBon GeunGyul different from today's circulation courses of twelve regular channels based on Kyungmaek(經脈) chapter of Youngchu. Thus this study investigate the contents of PyoBon GeunGyul and consider its connection with channel flow. The results are as follows : 1. PyoBon GeunGyul theory explain that the relation of the limbs and trunk at meridian and emphasize that the connection of meridian and the importance of the limb acupoints. 2. PyoBon GeunGyul theory can be understandable in the view of the primordial qi and explain that the primordial qi of twelve regular channels acts from the limbs to the trunk. 3. PyoBon GeunGyul theory is based on the system of primordial qi channel which circulates from fingers and toes facing toward heart or the head, different from today's circulation courses of twelve regular meridians. 4. PyoBon GeunGyul theory act as a basis of principle of a part or distant point selection which applicated widely in acumoxibustion.

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선단과냉을 고려한 이원합금의 주상 수지상응고 모델 (A model for columnar-dendritic solidification of binary alloys accounting for dendrite tip undercooling)

  • 유호선
    • 대한기계학회논문집B
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    • 제22권5호
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    • pp.698-707
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    • 1998
  • A simplified model for predicting microsegregation during columnar-dendritic solidification of binary alloys is developed, in which back diffusion, dendrite arm coarsening and dendrite tip undercooling are simultaneously incorporated. The inclusion of tip undercooling is accomplished by modifying the initial conditions of the existing solute diffusion model, in such forms that tip undercooling depresses the beginning of solidification below the liquidus temperature, and that the secondary arm spacing evolves in accordance with the minimum undercooling theory. Sample calculations for the well-known benchmark system show that the present predictions not only consist with the extablished limiting cases, but also agree favorably with the available experimental data within a reasonable tolerance. In particular, a typical decreasing trend in the eutectic fraction at high cooling rates is successfully resolved. Comparison of the individual and combined effects of characteristic parameters in reference with the limiting cases reveals the interactions among parameters. Every parameter plays the role of reducing the eutectic fraction, and the degree of influence depends primarily on the cooling rate. Coarsening enhances the effect of tip undercooling, while suppressing that of back diffusion. A vigorous back diffusion seems to restrain the apperance of the undercooling effect. Overall, each contribution of the three parameters to microsegregation is estimated to be of the same order, which suffices to justify the present study.

CCIGC 기법을 사용한 SBS/cyclic solvent 시스템에서의 확산계수 측정 및 해석 (Measurement and Analysis of Diffusivity for SBS/cyclic Solvent Systems Using CCIGC Technique)

  • 김지의;홍성욱
    • 공업화학
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    • 제25권2호
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    • pp.147-151
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    • 2014
  • 많은 고분자 공정에서 고분자에서의 유기 용매와 같은 저분자 물질의 확산은 중요하다. 고분자에서의 저분자 물질의 이동은 중합 반응기의 효율성과 제조된 고분자의 특성을 결정한다. 공정을 설계하고 최적화하는데 중요한 물성값은 고분자/용매 상호확산 계수이다. 용매의 농도가 매우 낮은 무한희석 상태에서의 고분자/용매 계의 무한확산계수를 측정하기 위해서 capillary column inverse gas chromatography (CCIGC) 기법이 흔히 사용된다. 이 기법을 사용하면 비교적 짧은 시간에 확산계수와 분배계수를 측정하는 것이 가능하다. 본 연구에서는 CCIGC 기법을 사용해서 styrene/butadiene/styrene (SBS) 블록 공중합체에서 환형 구조를 가지는 용매의 확산계수와 분배계수를 다양한 온도 범위에서 측정하였다.

레이저 및 열전대를 이용한 동축류 확산화염에서의 매연입자 측정에 관한 연구 (A Study on the Soot Particle Measurement in Co-Flow Diffusion Flame Using a Laser Diagnostics and a Thermocouple)

  • 한용택;이기형;이원남
    • 대한기계학회논문집B
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    • 제28권7호
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    • pp.863-870
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    • 2004
  • The temperature and soot particle measurement technique in a laminar diffusion flame has been studied to investigate the characteristics of soot particle with temperature using a co-flow burner. The temperature distribution in the flame were measured by rapid insertion of a R-type thermocouple and the soot particles by LEM/LIS techniques. In these measurement, soot volume fraction, number density and soot diameters were analyzed experimentally. As a results, the spacial distributions of particle volume fraction, soot diameter, and number density are mapped throughout the flame using the Rayleigh theory for the scattering of light by particles. A laser extinction method was used to measure the soot volume fraction and laser induced scattering method was used to measure the soot particle diameter and number density. Also, we measured temperature without the effect of soot particles attached to the thermocouple junction, which is close to the nozzle. In this result, we found that upstream zone has a unstable flowing in co-flow diffusion flame and the y-axis temperature of flame has a uniform temperature distribution in the most soot volume fraction zone.

레이저 및 열전대를 이용한 동축류 확산화염에서의 매연입자 측정에 관한 연구 (A Study on the Soot Particle Measurement in Co-flow Diffusion Flame Using a Laser Diagnostics and a Thermocouple)

  • 한용택;이기형;이원남
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1267-1273
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    • 2004
  • The temperature and soot particle measurement technique in a laminar diffusion flame have been studied to investigate the characteristics of soot particle with temperature using a co-flow burner. The temperature distributions in the flame were measured by rapid insertion of a R-type thermocouple and the soot particles were detected were detected by LEM/LIS techniques. In these measurement, soot volume fraction, number density and soot diameters were analyzed experimentally. As a results, the spacial distributions of particle volume fraction, soot diameter, and number density are mapped throughout the flame using the Rayleigh theory for the scattering of light by absorbing particles. A laser extinction method was used to measure the soot volume fraction and Laser induced scattering method was used to measure the soot particle diameter and number density. Also, we measured temperature without the effect of soot particles attached to the thermocouple junction, which is close to the nozzle. In this result, we found that upstream zone has a unstable flowing in co-flow diffusion flame and the y-axis temperature of flame has a uniform temperature distribution in the most soot volume fraction zone.

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조직 내 빅데이터 시스템 확산에 영향을 주는 요인에 대한 연구 (Factors for the Intra-organizational Diffusion of Big Data Systems)

  • 박성관;김청
    • 한국IT서비스학회지
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    • 제18권2호
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    • pp.97-121
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    • 2019
  • In this paper, factors affecting intra-organizational diffusion of Big Data systems from the perspective of the Big Data system vendors have been analyzed. In particular, the theory of resistance against innovation that exists in some form before the adoption or rejection of innovation has been focused on. In order to do that, the resistance has been divided into three categories : postponement, rejection and opposition. The variables affecting each type are also divided into four independent variables : perceived risk, innovation characteristics, user attributes, and organizational attributes. As a result of the survey, it was confirmed that the influences of each variable are different according to the type of resistance. As the strength of the resistance was increased, the influence of the trialability was increased as well. As the strength of the resistance was decreased, the satisfaction with the existing system became more influential on the resistance. The time risk and the satisfaction with the existing system were found to affect all types of resistance. From the vendor's point of view, strategic implications are presented in terms of marketing or system development for diffusion, depending on the degree of resistance of the adopter.