• 제목/요약/키워드: Diffusion rate

검색결과 1,745건 처리시간 0.031초

당근의 삼투건조시 물질이동 특성 (Mass Transfer Characteristics in the Osmotic Dehydration Process of Carrots)

  • 윤광섭;최용희
    • 한국식품과학회지
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    • 제27권3호
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    • pp.387-393
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    • 1995
  • 삼투건조시 물질이동 특성을 알아보기 위하여 수분과 용질의 이동을 확산식으로 평가하여 침지온도와 농도에 따른 영향을 조사하였으며 또한 품질변화 정도는 carotene 함량을 지표로 하여 반응속도식으로 구명하고자 하였으며 삼투공정시 수분의 이동을 기존의 건조모델로 표현하고자 적합도를 알아보았다. 수분손실이나 용질의 증가는 온도와 농도가 증가함에 따라 높은값을 보였으며 농도보다는 온도의 영향을 많이 받는 것으로 나타났다. 확산계수 또한 고온과 고농도에서 높은 값을 가져 확산이 빠르게 일어남을 알 수 있었다. 고온에서는 수분 손실이 용질의 증가보다 높아 용질의 확산계수가 수분의 확산계수보다 높았으며, 품질변화를 나타내는 반응속도상수는 온도의 증가보다 농도의 증가에 따라 더 큰 값을 가져 고농도에서 파괴가 많이 일어남을 알 수 있었다. 확산계수와 품질변화 속도상수에 대한 온도의 영향을 알아보고자 Arrhenius 식에 적합시켜 본 결과 낮은 농도인 $20^{\circ}Brix$에서 확산에 많은 활성화에너지가 필요하고 고농도인 $60^{\circ}Brix$에서는 상대적으로 낮은 활성에너지로도 용질의 확산이 일어난다는 것을 알 수 있었고 활성화 에너지의 크기로 보아 수분의 이동은 $40^{\circ}Brix$에서, 용질의 이동은 $60^{\circ}Brix$에서 이동이 효과적으로 일어남을 알 수 있었다. 침지온도와 농도를 독립변수로 하여 확산계수와 반응속도상수를 예측하고자 각 독립 변수의 최적함수를 구하여 수립한 최적 함수 모델식과 polynomial 형태로 모델화 하였을 경우 수분이나 용질의 확산계수는 높은 적합도를 결정계수를 가지나 품질변화를 나타내는 반응속도강수는 다소 낮아 온도와 농도의 함수로 예측하기에는 미흡한 것으로 나타났다. 삼투건조 공정 중 수분의 이동을 시간의 함수로 표현하기 위한 가장 적합한 모델은 quadratic 모델의 $R^{2}$값이 침지온도와 농도에 관계없이 전반적으로 0.99 이상으로 나타나 다른 모델보다 더 높은 적용 가능성을 보였다. 따라서 quadratic 모델을 이용하여 삼투건조공정에서의 시간에 따른 수분함량을 예측할 수 있으며 확산계수와 아울러 물질이동 특성을 나타낼 수 있을 것으로 생각된다.

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금속의 고온 산화동안 포물선 속도상수의 이론적 계산 (Theoretical Calculation of Parabolic Rate Constant for High-Temperature Oxidation of Metals)

  • 김인수;조월동
    • 열처리공학회지
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    • 제14권5호
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    • pp.282-285
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    • 2001
  • Based on the mass balance of anion and cation fluxes, the parabolic rate constant ($K_p$) of oxide grown during the high-temperature oxidation of metal is theoretically calculated. It is assumed that the diffusion of oxygen anion and metal cation through oxide scale obeys the Fick's 1st law, the growth of oxide is controlled by the diffusion of ions, electrical potential gradient as driving force for diffusion of ions is ignored, and oxidation occurs within an existing oxide layer. Then, the parabolic rate constant can be expressed by $K_p=[2{\rho}_{MmOn}{M^2}_{MmOn}(mD_oC_o{^e}+nD_MC_M{^e})/nm]$.

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시간에 따라 변화는 회전 각속도를 가지는 원통용기내의 스핀업 (Spin-up in a Cylinder with a Time-Dependent Rotation Rate)

  • 김경석;곽호상;현재민
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집E
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    • pp.456-462
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    • 2001
  • Comprehensive numerical computations are made of a homogenous spin-up in a cylindrical cavity with a time-dependent rotation rate. Numerical solutions are acquired to the governing axisymmetric cylindrical Navier-Stokes equation. A rotation rate formula is ${\Omega}_f={\Omega}_i+{\Delta}{\Omega}(1-{\exp}(-t/t_c))$. If $t_c$ is large, it implies that a rotation change rate is small. The Ekman number, E, is set to $10^{-4}$ and the aspect ratio, R/H, fixed to I. For a linear spin-up(${\epsilon}<<$), the major contributor to spin-up in the interior is not viscous-diffusion term but inviscid term, especially Coriolis term, though $t_c$ is very large. The viscous-diffusion term only works near sidewall. But for spin-up from rest, when $t_c$ is very large, viscous-diffusion term affects interior area as well as sidewall, initially. So azimuthal velocity of interior for large $t_c$ appears faster than that of interior for relatively small $t_c$. However, the viscous-diffusion term of interior decreases as time increases. Instead, inviscid term appears in the interior.

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디지털융합서비스의 수용, 사용, 확산에 관한 연구 : 혁신확산에 관한 수용-확산 및 사용-확산의 통합적 접근 (Innovative Converged Service and It's Adoption, Use and Diffusion : A Holistic Approach to Diffusion of Innovations, Combining Adoption-Diffusion and Use Diffusion Paradigms)

  • 송영화;임명환;김승호;원교일지
    • Journal of Information Technology Applications and Management
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    • 제17권2호
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    • pp.187-205
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    • 2010
  • This study takes a holistic approach to understand the diffusion of IPTV services by combining the adoption-diffusion model and the use-diffusion model of innovation. IPTV service, a leading digital converged application coupling media content with telecommunications, has been recently launched commercially in Korea. We created a structural model of adoption-diffusion, using the perceived easeof-use and usefulness of TAM(Technology Acceptance Model) as mediating variables, and a structural model of use-diffusion, with the rate of use and the variety of use as mediating variables. To empirically analyze these models, non-users of IPTV were surveyed using the adoption-diffusion model to identify factors influencing their intention to subscribe to the service. Meanwhile, users of IPTV were surveyed using the use-diffusion model to determine the factors that influence their satisfaction with the service and their intention to re-use it. Under the adoption-diffusion model, we found that trialability, household innovativeness and perceived risk were the determinants of user satisfaction with IPTV, and perceived ease-of-use, the mediating factors. Under the use-diffusion model, complementarity and communication were shown to be the determinants of users' satisfaction with IPTV, and variety of use, the mediating factor. We also found that consumers' intention to re-use IPTV was strongly influenced by its relative advantage and perceived risk.

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상호작용하는 $H_2$-CO 예혼합 화염에서 $H_2$선호확산의 영향에 관한 수치적 연구 (Effects of Preferential Diffusion on Downstream Interaction in Premixed $H_2$/CO Syngas-air Flames)

  • 오상훈;박정;권오붕
    • 한국연소학회지
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    • 제17권3호
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    • pp.17-29
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    • 2012
  • The effects of strain rate and preferential diffusion of $H_2$ on flame extinction are numerically studied in interacting premixed syngas-air flames with fuel compositions of 50% $H_2$ + 50% CO and 30% $H_2$ + 70% CO. Flame stability diagrams mapping lower and upper limit fuel concentrations at flame extinction as a function of strain rate are examined. Increasing strain rate reduces the boundaries of both flammable lean and rich fuel concentrations and produces a flammable island and subsequently even a point, implying that there exists a limit strain rate over which interacting flame cannot be sustained anymore. Even if effective Lewis numbers are slightly larger than unity on extinction boundaries, the shape of the lean extinction boundary is slanted even at low strain rate, i.e. $a_g=30s^{-1}$ and is more slanted in further increase of strain rate, implying that flame interaction on lean extinction boundary is strong and thus hydrogen (as a deficient reactant) Lewis number much less than unity plays an important role of flame interaction. It is also shown that effects of preferential diffusion of $H_2$ cause flame interaction to be stronger on lean extinction boundaries and weaker on rich extinction boundaries. Detailed analyses are made through the comparison between flame structures with and without the restriction of the diffusivities of $H_2$ and H in symmetric and asymmetric fuel compositions. The reduction of flammable fuel compositions in increase of strain rate suggests that the mechanism of flame extinction is significant conductive heat loss from the stronger flame to ambience.

CONCENTRATION CONTOURS IN LATTICE AND GRAIN BOUNDARY DIFFUSION IN A POLYCRYSTALLINE SOLID

  • Kim, Yongsoo;Wonmok Jae;Saied, Usama-El;Donald R. Olander
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1995년도 추계학술발표회논문집(2)
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    • pp.707-712
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    • 1995
  • Grain boundary diffusion plays significant role in the fission gas release, which is one of the crucial processes dominating nuclear fuel performance. Gaseous fission products such as Xe and Kr generated inside fuel pellet have to diffuse in the lattice and in the grain boundary before they reach open space in the fuel rod. In the mean time, the grains in the fuel pellet grow and shrink according to grain growth kinetics, especially at elevated temperature at which nuclear reactors are operating. Thus the boundary movement ascribed to the grain growth greatly influences the fission gas release rate by lengthening or shortening the lattice diffusion distance, which is the rate limiting step. Sweeping fission gases by the moving boundary contributes to the increment of the fission gas release as well. Lattice and grain boundary diffusion processes in the fission gas release can be studied by 'tracer diffusion' technique, by which grain boundary diffusion can be estimated and used directly for low burn-up fission gas release analysis. However, even for tracer diffusion analysis, taking both the intragranular grain growth and the diffusion processes simultaneously into consideration is not easy. Only a few models accounting for the both processes are available and mostly handle them numerically. Numerical solutions are limited in the practical use. Here in this paper, an approximate analytical solution of the lattice and stationary grain boundary diffusion in a polycrystalline solid is developed for the tracer diffusion techniques. This short closed-form solution is compared to available exact and numerical solutions and turns out to be acceptably accurate. It can be applied to the theoretical modeling and the experimental analysis, especially PIE (post irradiation examination), of low burn up fission. gas release.

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전개확산제트화염과 정체점 확산화염과의 유사성 (Similarity between a stagnant point diffusion flame and an evolving jet diffusion flame)

  • 박정;신현동
    • 대한기계학회논문집B
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    • 제21권4호
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    • pp.494-502
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    • 1997
  • Experiments on corresponding jet flames with stagnant point diffusion flames have been carried out in initial injection periods. A compensated measurement of maximum flame temperature, which is based on the ion signal, has been employed to inspect flame responses to time-varying strain rates. The flame responses are obtained at two conditions for the slowly time-varying strain rate and the case of flame extinction, and analyzed to confirm similarity between a stagnant point diffusion flame and an evolving jet diffusion flame. Nonsteady effects are addressed via the comparison between several time scales. The time variation with low strain rates, in which illustrates the flame behavior of the upper branch far from extinction in the well-known S-curve, is confirmed to produce a quasi-steady flame response through the nonsteady experiments. The time variation with strain rates in the case of flame extinction indicates an unsteady effect of flame response. It is therefore found that the flame responses near jet tip depend on time histories of characterized strain rates in the developing process.

기술 및 수요속성에 따른 정보통신서비스 확산 패턴

  • 김문수;김호
    • 기술혁신연구
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    • 제11권2호
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    • pp.71-89
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    • 2003
  • Since technological innovation, adoption, and diffusion is a fundamental engine for a company's competitiveness and in turn a nation's industrial development, diffusion of technological innovation has been one of popular research themes to many researchers and scholars for decades. Especially, in today's knowledge-based economy, the IT technology became a fundamental infrastructure for a nation and thus their impact on a nation's economy has grown to be tremendous. This paper investigates the patterns of technological diffusion of 16 telecommunications services. Firstly, we identify the optimal diffusion model which represents the 15 IT innovation best in terms of goodness-of-fit. Secondly, based on the best model identified we cluster the 16 IT innovations according to their diffusion characteristics such as penetration rate and diffusion speed. Lastly, we categorize the innovations in terms of technology (voice-based innovation and data-based innovation) and demand (household-use and business-use) attributes, and compare their diffusion patterns and found some meaningful difference in diffusion patterns. We hope the result helpful to corporate managers as well as policy makers in relevant areas.

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SPECKLE NOISE SMOOTHING USING AN MODIFIED MEAN CURVATURE DIFFUSION FILTER

  • Ye, Chul-Soo
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2008년도 International Symposium on Remote Sensing
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    • pp.159-162
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    • 2008
  • This paper presents a modified mean curvature diffusion filter to smooth speckle noise in images. Mean curvature diffusion filter has already shown good results in reducing noise in images while preserving fine details. In the mean curvature diffusion, the rate of smoothing is controlled by the local value of the diffusion coefficient chosen to be a function of the local image gradient magnitude. In this paper, the diffusion coefficient is modified to be controlled adaptively by local image surface slope and heterogeneity. The local surface slope contributes to preserving details (e.g.edges) in image and the local surface heterogeneity helps the smoothing filter consider the amount of noise in both edge and non-edge area. The proposed filter's performance is demonstrated by quantitative experiments using speckle noised aerial image and TerraSAR-X satellite image.

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낙구식 점도계를 이용한 점탄성 유체의 특성시간에 관한 실험적 연구 (An experimental study on the characteristic times of viscoelastic fluids by falling ball viscometer)

  • 전찬열;유상신
    • 대한기계학회논문집
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    • 제14권1호
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    • pp.241-250
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    • 1990
  • 본 연구에서는 낙구식 점도계를 이용하여 낮은 농도의 용액을 실험할 때 종말 속도측정의 어려움을 해결하기 위하여 레이저와 특수 타이머를 설치하였으며 정확한 특성시간을 결정하기 위하여 실린더 내부의 시험유체를 교란시키지 않고, 떨어뜨린 구 를 회수하는 장치를 제작하였다. 또한 주로 rheogoniometer에 의존하던 영 전단률 점성계수를 측정하기 위하여 속이 빈 알루미늄 구(hollow aluminium ball)의 밀도를 시험 유체와 거의 같은 정도까지 변화시켜가며 종말 속도를 측정하였으며 점탄성 유체 로써 Separan AP-273의 낮은 농도인 300에서 2000wppm까지의 저농도 용액에 대한 특성 시간을 여러모델에 의하여 실험적으로 결정하고 저농도 폴리머 용액에서 퇴화로 인한 점탄성유체의 특성 변화를 분석하였다.