• Macromolecular Research
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• 제11권5호
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• pp.311-316
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• 2003

The kinetics of photoinitiated polymerization of dimethacrylate macromonomers have been studied to determine the diffusion-controlled reaction parameters using attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). A predicted kinetic rate expression with a diffusion control factor was employed to estimate an effective rate constant and to define the reaction-controlled and diffusion-controlled regimes in the photopolymerization. An effective rate constant, k$_{e}$, can be obtained from the predicted kinetic rate expression. At the earlier stages of polymerization, the average values of kinetic rate constants do not vary during the reaction time. As the reaction conversion, $\alpha$, reaches the critical conversion, $\alpha$$_{c}$, in the predicted kinetic expression, the reaction becomes to be controlled by diffusion due to the restricted mobility of dimethacrylate macromonomers. A drop in value of effective rate constant causes a drastic decrease of reaction rate at the later stages of polymerization. By determining the effective rate constants, the reaction-controlled and diffusion-controlled regimes were properly defined even in the photopolymerization reaction system.m.m.

• 한국안전학회지
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• 제17권3호
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• pp.43-49
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• 2002

The NOx emission characteristics of double-concentric diffusion flames and normal diffusion flames fueled with CH$_4$ were studied. Experimental and numerical investigations were carried out for double-concentric diffusion flame with varying central air flow rate and normal diffusion flame. The Emission indices of NOx(EINOx) were measured by chemiluminescent method and calculated by numerical model based on detailed chemistry. From the comparison between double-concentric diffusion flames and normal diffusion flames, the results show that EINOx of double-concentric diffusion flames are lower than normal diffusion flame, because of Prompt EINOx was decreased. EINOx of double-concentric diffusion flames increase with central air flow rate increasing.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.140-149
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• 2006

Characteristics of a laminar diffusion flame placed near wall in microgravity have been numerically analyzed in a two-dimension. The fuel for the flame is $C_2H_4$. The flame is initiated by imposing a high temperature ignition source. The flow field, temperature field, and flame shape in microgravity diffusion flame are detailed. Especially, effects of surrounding air velocity and fuel injection velocity on the microgravity diffusion flame have been discussed accounting for standoff distance. And, the effect of curvature rate has been also studied. The results showed that velocities in a diffusion flame were overshoot because of volumetric expansion and distribution of temperature showed regularity by free-buoyancy This means that the diffusion flame in microgravity is very stable, while the flame in normal gravity is not regular and unstable due to buoyancy. Standoff distance decreases with increase in surrounding air velocity and with decrease in fuel injection velocity. With increasing curvature rate, the position of reaction rate moves away the wall.

• East Asian Economic Review
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• 제24권1호
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• pp.61-87
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• 2020

Five diffusion models are estimated using three different foreign exchange rates to find an appropriate model for each. Daily spot exchange rates expressed as the prices of 1 euro, 1 British pound and 100 Japanese yen in US dollars, respectively denoted by USD/EUR, USD/GBP, and USD/100JPY, are used. The maximum likelihood estimation method is implemented after deriving an approximate log-transition density function (log-TDF) of the diffusion processes because the true log-TDF is unknown. Of the five models, the most general model is the best fit for the USD/GBP, and USD/100JPY exchange rates, but it is not the case for the case of USD/EUR. Although we could not find any evidence of the mean-reverting property for the USD/EUR exchange rate, the USD/GBP, and USD/100JPY exchange rates show the mean-reversion behavior. Interestingly, the volatility function of the USD/EUR exchange rate is increasing in the exchange rate while the volatility functions of the USD/GBP and USD/100Yen exchange rates have a U-shape. Our results reveal that more care has to be taken when determining a diffusion model for the exchange rate. The results also imply that we may have to use a more general diffusion model than those proposed in the literature when developing economic theories for the behavior of the exchange rate and pricing foreign currency options or derivatives.

• 대한화학회지
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• 제42권1호
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• pp.22-27
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• 1998

여러 가지 용매에서 N,N-dimethylaniline에 의한 coumarin 153과 coumarin 481분자의 형광소광효과를 조사하였다. 소광속도상수와 분자의 확산속도상수간의 관계로부터 소광과정이 분자의 확산과 어느정도 상호연관성을 갖고 있음을 알 수 있었다. slip boundary조건 보다stick boundary 조건을 적용하였을 때 분자확산 속도상수와 실험적인 소광속도상수와의 차이가 작게 나타났다. cyclohexane 과 같은 비극성용매에서의 소광속도 상수는 이론적인 확산속도상수 값과 오차범위 내에서 거의 일치하였으나 acetonitrile과 같은 극성용매에서는 소광속도상수는 확산속도상수보다 일관되게 작게 나타났다. 이것은 coumarin 분자의 형광소광이 분자간 확산에 의한 충돌 뿐만 아니라 분자내 전하분리와 같은 과정에 의해서도 진행되는 것으로 해석할 수 있다.

• 대한지리학회지
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• 제36권1호
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• pp.52-65
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• 2001

1985-1997년 사이에 자가용 승용차는 소득수준이 높고 서비스업이 발달한 서울.부산.대수시 등 대도시등 서울시의 위성도시에서 보급이 먼저 이루어지고 점차 공업도시와 지상 중심도시로 확산하는 한편, 대도시에서의 보급률 증가는 둔화되었다. 이와 같은 현상은 1985년과 1991년 모두 금융, 보험, 부동산 및 사업 서비스업 종사율이 가장 크게 영향을 주었다 1997년에는 농업, 수렵업, 임업 및 어업 종사율이 새롭게 가장 큰 영향력을 미쳤다. 자가용 승용차 보급의 시.공간적 분포패턴은 1991년을 기준으로, 1985-1990년은 서울시나 그 위성도시 및 지방 중심도시에서 보급률이 높았고 보급률의 지역간 격차가 켰던 시기이며, 1991-1997년은 지역적 보급이 평준화되면서 수도권지역 및 지방 주요 도시에 보급률이 높았던 시기이다. 자가용 보급 지역 유형의 결정에 영향을 미친 중요한 요인은 대도시에서는 서비스업 종사율과 소득이, 군 지역에서의 서울시로부터의 거리와 인구규모이다.

• Korean Journal of Mathematics
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• 제27권1호
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• pp.1-8
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• 2019

We will deal with an n locus model in which mutation and gene conversion are taken into consideration. Also random partitions of the number n determined by chromosomes with n loci should be investigated. The diffusion process describes the time evolution of distributions of the random partitions. In this paper, we find the probability of distribution of the diffusion process with special diffusion operator $L_1$ and we show that the average probability of genes at different loci on one chromosome can be described by the rate of gene frequency of mutation and gene conversion.

• Archives of Pharmacal Research
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• 제8권1호
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• pp.7-14
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• 1985

Membrane-coated tablet of isonicotinic acid hydrazide (INAH) which releases INAH at the zero-order kinetics was deveoped. It consisted of a soluble tablet core surrounded by a porous membrane which controls the diffusion rate. Tablet cores were prepared by compressing granules of INAH and polyvinyl chloride (PVC) dissolved in methyl ethyl ketone in which micronized sucrose were suspended. Diffusion rate of INAH from the tablet through the membrane was constant until the loaded INAH in the core was almost released. The rate was independent of pH of the dissolution medium. Water-soluble sucrose particles behaved as a poreproducing material in the water-insoluble PVC film coat. The pH independency of the rate was probably due to the high solubility of INAH in the water of wide pH range. The diffusion rate of INAH could be controlled by chnaging the composition of the membrane or the coat weight. This membrane-coated INAH tablet seemed to be a powerful candidate for the controlled release drug delivery system (DDS) of INAH or other highly watersoluble drugs.

• 대한기계학회논문집B
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• 제25권1호
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• pp.29-35
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• 2001

Radiation-induced oscillatory instability in CH$_4$/Air diffusion flames is numerically investigated by adopting detailed chemistry. Counterflow diffusion flame is employed as a model flamelet and optically thin gas-phase radiation is assumed. Attention is focused on the extinction regime induced by radiative heat loss, which occurs at low strain rate. Once a steady flame structure is obtained for a prescribed value of initial strain rate, transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed on the steady flame. Depending on the initial strain rate and the amount of perturbed strain rate, transient evolution of the flame exhibits various types of flame-evolution behaviors. Basically, the dynamic behaviors can be classified into two types, namely oscillatory decaying solution and diverging solution leading to extinction.

• Journal of Pharmaceutical Investigation
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• 제20권2호
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• pp.79-88
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• 1990

A numerical model for diffusion and dissolution controlled transport from dispersed matrix is presented. The rate controlling process for transport is considered to be diffusion of drug through a concentration gradient coupled with time-dependent surface change and/or disappearance of the dispersed drug in response to the dissolution. The transport behavior of drug was explained in terms of ${\nu}$ parameter: ${\nu}$ value means a ratio of diffusion time constant and dissolution time constant. This general model has wide range of application from where release is controlled by the diffusion rate to where release is governed by the dissolution rate. Based on this model, theoretical drug concentration, particle size distributions in the polymer matrix system and the resulting release rate were also investigated.