• Title/Summary/Keyword: Diffusion rate

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Mass Transfer Characteristics in the Osmotic Dehydration Process of Carrots (당근의 삼투건조시 물질이동 특성)

  • Youn, Kwang-Sup;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.27 no.3
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    • pp.387-393
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    • 1995
  • Diffusion coefficients of moisture and solid, reaction rate constants of carotene destruction, and the fitness of drying models for moisture transfer were determined to study the characteristics of mass transfer during osmotic dehydration. Moisture loss and solid gain were increased with increase of temperature and concentration; temperature had higher osmotic effect than concentration. Diffusion coefficient showed similar trend with osmotic effect. Diffusion coefficients of solids were larger than those of moisture because the movement of solid was faster than that of moisture at the high temperature. Reaction rate constants were affected to the greater extent by concentration changes than by temperature changes. Arrhenius equation was applied to determine the effect of temperature on diffusion coefficients and reaction rate constants. Moisture diffusion required high activation energy in $20^{\circ}Brix$, while relatively low in $60^{\circ}Brix$. To predict the diffusion coefficients and reaction rate constants, a model was established by using the optimum functions of temperature and concentration. The model had high $R^2$ value when applied to diffusion coefficients, but low when applied to reaction rate constants. Quadratic drying model was most fittable to express moisture transfer during drying. In conclusion, moisture content of carrots could be predictable during the osmotic dehydration process, and thereby mass transfer characteristics could be determined by predicted moisture content and diffusion coefficient.

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Theoretical Calculation of Parabolic Rate Constant for High-Temperature Oxidation of Metals (금속의 고온 산화동안 포물선 속도상수의 이론적 계산)

  • Kim, Insoo;Cho, Weol Dong
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.5
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    • pp.282-285
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    • 2001
  • Based on the mass balance of anion and cation fluxes, the parabolic rate constant ($K_p$) of oxide grown during the high-temperature oxidation of metal is theoretically calculated. It is assumed that the diffusion of oxygen anion and metal cation through oxide scale obeys the Fick's 1st law, the growth of oxide is controlled by the diffusion of ions, electrical potential gradient as driving force for diffusion of ions is ignored, and oxidation occurs within an existing oxide layer. Then, the parabolic rate constant can be expressed by $K_p=[2{\rho}_{MmOn}{M^2}_{MmOn}(mD_oC_o{^e}+nD_MC_M{^e})/nm]$.

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Spin-up in a Cylinder with a Time-Dependent Rotation Rate (시간에 따라 변화는 회전 각속도를 가지는 원통용기내의 스핀업)

  • Kim, Kyung-Seok;Kwak, Ho-Sang;Hyun, Jae-Min
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.456-462
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    • 2001
  • Comprehensive numerical computations are made of a homogenous spin-up in a cylindrical cavity with a time-dependent rotation rate. Numerical solutions are acquired to the governing axisymmetric cylindrical Navier-Stokes equation. A rotation rate formula is ${\Omega}_f={\Omega}_i+{\Delta}{\Omega}(1-{\exp}(-t/t_c))$. If $t_c$ is large, it implies that a rotation change rate is small. The Ekman number, E, is set to $10^{-4}$ and the aspect ratio, R/H, fixed to I. For a linear spin-up(${\epsilon}<<$), the major contributor to spin-up in the interior is not viscous-diffusion term but inviscid term, especially Coriolis term, though $t_c$ is very large. The viscous-diffusion term only works near sidewall. But for spin-up from rest, when $t_c$ is very large, viscous-diffusion term affects interior area as well as sidewall, initially. So azimuthal velocity of interior for large $t_c$ appears faster than that of interior for relatively small $t_c$. However, the viscous-diffusion term of interior decreases as time increases. Instead, inviscid term appears in the interior.

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Innovative Converged Service and It's Adoption, Use and Diffusion : A Holistic Approach to Diffusion of Innovations, Combining Adoption-Diffusion and Use Diffusion Paradigms (디지털융합서비스의 수용, 사용, 확산에 관한 연구 : 혁신확산에 관한 수용-확산 및 사용-확산의 통합적 접근)

  • Sawng, Yeong-Wha;Rim, Myung-Hwan;Kim, Seong-Ho;Motohashi, Kazuyuki
    • Journal of Information Technology Applications and Management
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    • v.17 no.2
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    • pp.187-205
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    • 2010
  • This study takes a holistic approach to understand the diffusion of IPTV services by combining the adoption-diffusion model and the use-diffusion model of innovation. IPTV service, a leading digital converged application coupling media content with telecommunications, has been recently launched commercially in Korea. We created a structural model of adoption-diffusion, using the perceived easeof-use and usefulness of TAM(Technology Acceptance Model) as mediating variables, and a structural model of use-diffusion, with the rate of use and the variety of use as mediating variables. To empirically analyze these models, non-users of IPTV were surveyed using the adoption-diffusion model to identify factors influencing their intention to subscribe to the service. Meanwhile, users of IPTV were surveyed using the use-diffusion model to determine the factors that influence their satisfaction with the service and their intention to re-use it. Under the adoption-diffusion model, we found that trialability, household innovativeness and perceived risk were the determinants of user satisfaction with IPTV, and perceived ease-of-use, the mediating factors. Under the use-diffusion model, complementarity and communication were shown to be the determinants of users' satisfaction with IPTV, and variety of use, the mediating factor. We also found that consumers' intention to re-use IPTV was strongly influenced by its relative advantage and perceived risk.

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Effects of Preferential Diffusion on Downstream Interaction in Premixed $H_2$/CO Syngas-air Flames (상호작용하는 $H_2$-CO 예혼합 화염에서 $H_2$선호확산의 영향에 관한 수치적 연구)

  • Oh, Sanghoon;Park, Jeong;Kwon, Ohboong
    • Journal of the Korean Society of Combustion
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    • v.17 no.3
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    • pp.17-29
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    • 2012
  • The effects of strain rate and preferential diffusion of $H_2$ on flame extinction are numerically studied in interacting premixed syngas-air flames with fuel compositions of 50% $H_2$ + 50% CO and 30% $H_2$ + 70% CO. Flame stability diagrams mapping lower and upper limit fuel concentrations at flame extinction as a function of strain rate are examined. Increasing strain rate reduces the boundaries of both flammable lean and rich fuel concentrations and produces a flammable island and subsequently even a point, implying that there exists a limit strain rate over which interacting flame cannot be sustained anymore. Even if effective Lewis numbers are slightly larger than unity on extinction boundaries, the shape of the lean extinction boundary is slanted even at low strain rate, i.e. $a_g=30s^{-1}$ and is more slanted in further increase of strain rate, implying that flame interaction on lean extinction boundary is strong and thus hydrogen (as a deficient reactant) Lewis number much less than unity plays an important role of flame interaction. It is also shown that effects of preferential diffusion of $H_2$ cause flame interaction to be stronger on lean extinction boundaries and weaker on rich extinction boundaries. Detailed analyses are made through the comparison between flame structures with and without the restriction of the diffusivities of $H_2$ and H in symmetric and asymmetric fuel compositions. The reduction of flammable fuel compositions in increase of strain rate suggests that the mechanism of flame extinction is significant conductive heat loss from the stronger flame to ambience.

CONCENTRATION CONTOURS IN LATTICE AND GRAIN BOUNDARY DIFFUSION IN A POLYCRYSTALLINE SOLID

  • Kim, Yongsoo;Wonmok Jae;Saied, Usama-El;Donald R. Olander
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05a
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    • pp.707-712
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    • 1995
  • Grain boundary diffusion plays significant role in the fission gas release, which is one of the crucial processes dominating nuclear fuel performance. Gaseous fission products such as Xe and Kr generated inside fuel pellet have to diffuse in the lattice and in the grain boundary before they reach open space in the fuel rod. In the mean time, the grains in the fuel pellet grow and shrink according to grain growth kinetics, especially at elevated temperature at which nuclear reactors are operating. Thus the boundary movement ascribed to the grain growth greatly influences the fission gas release rate by lengthening or shortening the lattice diffusion distance, which is the rate limiting step. Sweeping fission gases by the moving boundary contributes to the increment of the fission gas release as well. Lattice and grain boundary diffusion processes in the fission gas release can be studied by 'tracer diffusion' technique, by which grain boundary diffusion can be estimated and used directly for low burn-up fission gas release analysis. However, even for tracer diffusion analysis, taking both the intragranular grain growth and the diffusion processes simultaneously into consideration is not easy. Only a few models accounting for the both processes are available and mostly handle them numerically. Numerical solutions are limited in the practical use. Here in this paper, an approximate analytical solution of the lattice and stationary grain boundary diffusion in a polycrystalline solid is developed for the tracer diffusion techniques. This short closed-form solution is compared to available exact and numerical solutions and turns out to be acceptably accurate. It can be applied to the theoretical modeling and the experimental analysis, especially PIE (post irradiation examination), of low burn up fission. gas release.

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Similarity between a stagnant point diffusion flame and an evolving jet diffusion flame (전개확산제트화염과 정체점 확산화염과의 유사성)

  • Park, Jeong;Shin, Hyun-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.4
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    • pp.494-502
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    • 1997
  • Experiments on corresponding jet flames with stagnant point diffusion flames have been carried out in initial injection periods. A compensated measurement of maximum flame temperature, which is based on the ion signal, has been employed to inspect flame responses to time-varying strain rates. The flame responses are obtained at two conditions for the slowly time-varying strain rate and the case of flame extinction, and analyzed to confirm similarity between a stagnant point diffusion flame and an evolving jet diffusion flame. Nonsteady effects are addressed via the comparison between several time scales. The time variation with low strain rates, in which illustrates the flame behavior of the upper branch far from extinction in the well-known S-curve, is confirmed to produce a quasi-steady flame response through the nonsteady experiments. The time variation with strain rates in the case of flame extinction indicates an unsteady effect of flame response. It is therefore found that the flame responses near jet tip depend on time histories of characterized strain rates in the developing process.

기술 및 수요속성에 따른 정보통신서비스 확산 패턴

  • Kim, Mun-Su;Kim, Ho
    • Journal of Technology Innovation
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    • v.11 no.2
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    • pp.71-89
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    • 2003
  • Since technological innovation, adoption, and diffusion is a fundamental engine for a company's competitiveness and in turn a nation's industrial development, diffusion of technological innovation has been one of popular research themes to many researchers and scholars for decades. Especially, in today's knowledge-based economy, the IT technology became a fundamental infrastructure for a nation and thus their impact on a nation's economy has grown to be tremendous. This paper investigates the patterns of technological diffusion of 16 telecommunications services. Firstly, we identify the optimal diffusion model which represents the 15 IT innovation best in terms of goodness-of-fit. Secondly, based on the best model identified we cluster the 16 IT innovations according to their diffusion characteristics such as penetration rate and diffusion speed. Lastly, we categorize the innovations in terms of technology (voice-based innovation and data-based innovation) and demand (household-use and business-use) attributes, and compare their diffusion patterns and found some meaningful difference in diffusion patterns. We hope the result helpful to corporate managers as well as policy makers in relevant areas.

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SPECKLE NOISE SMOOTHING USING AN MODIFIED MEAN CURVATURE DIFFUSION FILTER

  • Ye, Chul-Soo
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.159-162
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    • 2008
  • This paper presents a modified mean curvature diffusion filter to smooth speckle noise in images. Mean curvature diffusion filter has already shown good results in reducing noise in images while preserving fine details. In the mean curvature diffusion, the rate of smoothing is controlled by the local value of the diffusion coefficient chosen to be a function of the local image gradient magnitude. In this paper, the diffusion coefficient is modified to be controlled adaptively by local image surface slope and heterogeneity. The local surface slope contributes to preserving details (e.g.edges) in image and the local surface heterogeneity helps the smoothing filter consider the amount of noise in both edge and non-edge area. The proposed filter's performance is demonstrated by quantitative experiments using speckle noised aerial image and TerraSAR-X satellite image.

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An experimental study on the characteristic times of viscoelastic fluids by falling ball viscometer (낙구식 점도계를 이용한 점탄성 유체의 특성시간에 관한 실험적 연구)

  • 전찬열;유상신
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.241-250
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    • 1990
  • Characteristic relaxation time and characteristic diffusion time of viscoelastic fluids are determined experimentally by measuring the zero-shear-rate viscosity by falling ball viscometer and the infinite-shear-rate viscosity by capillary tube viscometer. Fluids used in experiments are aqueous solutions of polyacrylamide Separan AP-273 and the polymer concentrations range from 300 to 2000 wppm. A newly designed laser beam and timer system is employed to overcome the difficulty in measuring terminal velocities of the low concentration solutions. Ball removal device is prepared to remove the dropped ball from the bottom of cylinder without disturbing the testing fluid. In order to measure the zero-shear-rate viscosity, densities of hollow aluminium balls are adjusted very close to the densities of testing fluids. Characteristic diffusion time, which is ball viscometer. However, terminal velocity of a needle by falling ball viscometer is not affected by the time interval of dropping needles and characteristic diffusion time is not measured with a dropping needle. Powell-Eyring model predicts the highest values of the characteristic relaxation times among models used for heat transfer experimental works for a given polymer solution. As degradation of a polymer solution continues, the zero-shear-rate viscosity decreases more seriously than the infinite-shear-rate viscosity. Characteristic relaxation times of polymer solutions decreases as degradation continues.