• Title/Summary/Keyword: Diffusion mechanism

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The Carrier Mechanism in the Disperse Dyeing of Poly(ethylene terephthalate) (폴리에스테르 섬유의 분산염색에 있어서 캐리어의 작용기구)

  • 이일건;윤남식;임용진
    • Textile Coloration and Finishing
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    • v.2 no.4
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    • pp.231-236
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    • 1990
  • The diffusion coefficient of C.I. Disperse Red 4 in the dyeing of carrier-pretreated poly (ethylene terephthalate) film was Investigated by Sekido's film-rolled method. From the result it was shown that the diffusion coefficient increases exponentially with the content-ration of carrier in the film, and, for the films containing same concentration of carrier, the carrier effect was enhanced with the molar volume of the carriers. The greater carrier effect was accompanied by the decrease in diffusion activation energy and entropy, which shows that the carrier with larger molar volume plasticizes PET film to more extent.

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Flammability Limits Variation of Opposed Flow Diffusion Flames for Different Channel Gap (채널 간격에 따른 대향류 확산화염의 가연 영역의 변화)

  • Lee, Min Jung;Kim, Nam Il
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.323-324
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    • 2012
  • Flammability limits of opposed flow diffusion flame in a narrow channel was investigated experimentally and theoretically. There were three different extinction modes corresponding to high strain rate (HSR), low strain rate (LSR) and dilution ratio (DR) limits. To investigate these limits, a theoretical study was followed by focusing on flow and heat transfer characteristics. Consequently, a dead space concept that has been used for premixed flames was important to reveal the heat loss mechanism in a narrow channel especially for LSR conditions even in the case of diffusion flames.

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The Study on Surface Modification of Alumina Membrane by CVD (CVD에 의한 알루미나 멤브레인의 표면개질에 관한 연구)

  • 이동호;최두진;현상훈;고광백
    • Journal of the Korean Ceramic Society
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    • v.32 no.12
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    • pp.1349-1356
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    • 1995
  • The change of permeation mechanism from Knudsen diffusion to micropore diffusion was observed after CVD modification of an alumina-sol coated alumina support which was prepared by slip coating process. Permselectivities of He/N2, H2/N2, and CO2/N2 were 5.67, 5.02, and 1.44, respectively. These values were higher than those under Knudsen diffusion controlled region.

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Hydroxide diffusion rates in amorphous solid water

  • Lee, Du Hyeong;Bang, Jaehyeock;Kang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.142.1-142.1
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    • 2016
  • We present bulk diffusion rates of hydroxide ions in amorphous solid water (ASW) at 135 ~ 160 K. Previous researches showed that the diffusion mechanism of hydroxide is different from one of hydronium ions, and this implies that they have different diffusion rates. In ultra-high vacuum (UHV) chamber, low-energy scattering (LES) was used to measure ion population and temperature-programmed desorption (TPD) was conducted for measuring ASW thicknesses. To determine the diffusion rates, a simple model for $H_2O/NaOH/H_2O$ sandwich films was developed using Fick's second law. The measured surface population of hydroxide ions as a function of time was well fitted to the model, and the rates were well agreed to an Arrhenius equation.

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A Experimental Study on the Chloride Diffusion Properties in Concrete (콘크리트 중의 염소이온 확산 특성에 관한 실험적 연구)

  • 박승범;김도겸
    • Journal of the Korea Concrete Institute
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    • v.12 no.1
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    • pp.33-44
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    • 2000
  • Since the mechanism of chloride diffusion and its ratio in concrete depend on structural conditions and concrete as a micro-structure, if these are analyzed quantitatively, the long-term ageing of structures can be predicted. Although, a quantitative analysis of concrete micro-structure, in which the results are affected by various parameters, is very difficult, this can be done indirectly by the durability test of concrete. In this study, the compressive strength, void ratio and air permeability of concrete. In this study, the compressive strength, void ratio and air permeability of concrete are chosen as the parameters in concrete durability test, and these effects on test results are analysed according to changes of mixing properties. The relationships between parameters and chloride diffusion velocity is used for prediction models of chloride diffusion. The developed prediction models for the chloride diffusion according to mixing and physical properties, can be used to estimate the service life and corrosion initiation of reinforcing bars in marine structures.

The Penetration and Diffusivity of Chloride ion into Concrete using Blended Cement (혼합계시멘트를 사용한 콘크리트의 염화물이온 침투 및 확산특성)

  • Yang, Seung-Kyu;Kim, Dong-Seuk;Um, Tai-Sun;Lee, Jong-Ryul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.489-492
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    • 2006
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon and numerous methods have been proposed to determine the diffusion coefficient of chloride ion quickly. In this study, electrically accelerated experiments were carried out in order to evaluate diffusion coefficient of the chloride ion into concrete. The methods were diffusion cell test method in which the voltage of 15V(DC) was applied. The type of cement is blended cement in which the admixtures of blast-furnace slag and fly ash were used. In conclusion, the diffusion coefficient of chloride ion is much affected according to mineral admixtures and the diffusion coefficient of ternary blended cement showed very low values. it is presumably said that this result is due to highly densified pore structures by the aid of slag substitution and pozzolanic activity of fly ash.

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The Role of Message Content and Source User Identity in Information Diffusion on Online Social Networks

  • Son, Insoo;Kim, Young-kyu;Lee, Dongwon
    • Asia pacific journal of information systems
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    • v.25 no.2
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    • pp.239-264
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    • 2015
  • This study aims to investigate the effect of message content and source user identity on information diffusion in Twitter networks. For the empirical study, we collected 11,346 tweets pertaining to the three major mobile telecom carriers in Korea for three months, from September to December 2011. These tweets generated 59,111 retweets (RTs) and were retweeted at least once. Our analysis indicates that information diffusion in Twitter in terms of RT volume is affected primarily by the type of message content, such as the inclusion of corporate social responsibility activities. However, the effect of message content on information diffusion is heterogeneous to the identity of the information source. We argue that user identity affects recipients' perception of the credibility of focal information. Our study offers insights into the information diffusion mechanism in online social networks and provides managerial implications on the strategic utilization of online social networks for marketing communications with customers.

A Review of Corrosion and Hydrogen Diffusion Behaviors of High Strength Pipe Steel in Sour Environment

  • Kim, Sung Jin;Kim, Kyoo Young
    • Journal of Welding and Joining
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    • v.32 no.5
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    • pp.13-20
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    • 2014
  • A brief overview is given of the corrosion and hydrogen diffusion behaviors of high strength pipe steel in sour environment. Firstly, hydrogen adsorption and diffusion mechanism of the pipe steel is introduced. Secondly, the effect of iron sulfide film precipitated as a result of the corrosion reaction on the steel surface on hydrogen reduction reaction and subsequent hydrogen permeation through the steel is discussed. Moreover, the hydrogen diffusion behavior of the pipe steel under tensile stress in both elastic and plastic ranges is reviewed based on a number of experimental permeation data and theoretical models describing the hydrogen diffusion and trapping phenomena in the steel. It is hoped that this paper will result in significant academic contributions in the field of corrosion and hydrogen related problems of the pipe steel used in sour environment.

Diffusion Model of Aluminium for the Formation of a Deep Junction in Silicon (실리콘에서 깊은 접합의 형성을 위한 알루미늄의 확산 모델)

  • Jung, Won-Chae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.4
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    • pp.263-270
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    • 2020
  • In this study, the physical mechanism and diffusion effects in aluminium implanted silicon was investigated. For fabricating power semiconductor devices, an aluminum implantation can be used as an emitter and a long drift region in a power diode, transistor, and thyristor. Thermal treatment with O2 gas exhibited to a remarkably deeper profile than inert gas with N2 in the depth of junction structure. The redistribution of aluminum implanted through via thermal annealing exhibited oxidation-enhanced diffusion in comparison with inert gas atmosphere. To investigate doping distribution for implantation and diffusion experiments, spreading resistance and secondary ion mass spectrometer tools were used for the measurements. For the deep-junction structure of these experiments, aluminum implantation and diffusion exhibited a junction depth around 20 ㎛ for the fabrication of power silicon devices.