• Title/Summary/Keyword: Diffusion magnitude

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Seasonal Variations of the Heat Flux in Muddy Intertidal Sediments near the Jebu Island during the Ebb Tides in the West Coast of Korea (서해 제부도 해역의 간조시 갯벌 퇴적층내 지온 및 열수지의 계절변화)

  • Na, Jung-Yul;Yu, Sung-Hyup;Seo, Jang-Won
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.1
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    • pp.1-9
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    • 2000
  • Vertical temperature distributions in muddy intertidal sediments near the Jebu Island on the west coast of Korea were obtained during the period of ebb tide which occurred in day time. The observations of mud temperature were made with thermistor embedded probe at 2cm interval for 18cm-layer of sediment for five different months of the year. Temporal changes in the vertical profile of the sediment temperature are strongly depend on the air temperature, the previous time of flood tide and the time of ebb tide. Heat exchanges in the surface layer (0-2 cm) in terms of magnitude and direction are greater than and opposite to those in the deeper sediment layer (8-12 cm), respectively and do not show any significant seasonal variations. In general, the surface layer gains heat while the deeper layer loses the heat. By using the 1-D diffusion equation temporal vertical profiles of the sediment temperature were obtained and were compared with the observed ones. The results show that in the sediment layer below 4 cm-depth the heat transport is predominantly by molecular diffusion. The average magnitude of heat flux into the sediment layer (0-18 cm) during the ebb tide when the mudflats were exposed in the middle of the day were between 4.1 and $28.9\;W/m^2$.

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Modeling Residual Water in the Gas Diffusion Layer of a Polymer Electrolyte Membrane Fuel Cell and Analyzing Performance Changes (고분자 전해질막 연료전지의 기체확산층 내부 잔류수 모델링 및 성능변화해석)

  • Jiwon Jang;Junbom Kim
    • Applied Chemistry for Engineering
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    • v.35 no.1
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    • pp.16-22
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    • 2024
  • Polymer electrolyte membrane fuel cells have the advantage of low operating temperatures and fast startup and response characteristics compared to others. Simulation studies are actively researched because their cost and time benefits. In this study, the resistance of water residual in the gas diffusion layer (GDL) of the unit cell was added to the existing equation to compare the actual data with the model data. The experiments were conducted with a 25 cm2 unit cell, and the samples were separated into stopping times of 0, 10, and 60 minutes following primary impedance measurement, activation, and polarization curve data acquisition. This gives 0, 10, and 60 minutes for the residual water in the GDL to evaporate. Without the rest period, the magnitude of the performance improvement was not significantly different at the same potential and flow rate, but the rest period did improve the performance of the membrane electrode assembly when measuring impedance. By changing the magnitude of the resistance reduction to an overvoltage, the voltage difference between the fuel cell model with and without residual water was compared, and the error rate in the high current density region, which is dominated by concentration losses, was reduced.

Manufacture of the Prealloyed Powder for Powder Metallurgy by the Ion-diffusion Process (이온확산법에 의한 분말야금용 합금강분의 제조)

  • Yun, Seong-Ryeol;Han, Seung-Hui;Na, Jae-Hun;Kim, Chang-Uk
    • Korean Journal of Materials Research
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    • v.8 no.3
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    • pp.206-213
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    • 1998
  • Cu, Ni, and Mo were ion-diffused into the pure steel powder in the aqueous solution of $(CuNO_3)_2$, $Ni(NO_3)_2)_2$, and $(NH_4)_6Mo_7O_{24}$, to form partial diffusion bond prealloyed steel powder. The mechanical properties, and compacting and sintering characteristics were investigated as a function of Cu. Ni and Mo contents. The results of the this research, it was found that the smallest change of size was observed, and the good degree of hardness and tensile strength was observed when 1.50wt%Cu, 1.75wt%Ni and 0.50wt%Mo was added each other. The powder metallurgy characteristics of partial diffusion bond prealloyed steel powder containing 1.50wt% of Cu, 1.75wt% of Ni and 0.5wt% of Mo were compared to those of distalloy $AB\textregistered$ which was manufactured in Hogani Corporation of Sweden. Partial diffusion bond prealloyed steel powder of this study had good degree of hardness and density, and its dimensional stability was same to that of pure steel powder. Under the same sintering density and temperature, the tensile strength of the ion powder from this research was $15~20Kg/\textrm{mm}^2$ larger than that of distalloy AB'. also the hardness was larger in the magnitude of Hv20-30. When the powder metallurgy heat-treated, hardness and tensile strength were substantially increased.

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Deposition of ZrO$_2$ and TiO$_2$ Thin Films Using RF Magnet ron Sputtering Method and Study on Their Structural Characteristics

  • Shin, Y.S.;Jeong, S.H.;Heo, C.H.;Bae, I.S.;Kwak, H.T.;Lee, S.B.;Boo, J.H.
    • Journal of Surface Science and Engineering
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    • v.36 no.1
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    • pp.14-21
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    • 2003
  • Thin films of ZrO$_2$ and TiO$_2$ were deposited on Si(100) substrates using RF magnetron sputtering technique. To study an influence of the sputtering parameters, systematic experiments were carried out in this work. XRD data show that the $ZrO_2$ films were mainly grown in the [111] orientation at the annealing temperature between 800 and $1000^{\circ}C$ while the crystal growth direction was changed to be [012] at above $1000^{\circ}C$. FT-IR spectra show that the oxygen stretching peaks become strong due to $SiO_2$ layer formation between film layers and silicon surface after annealing, and proved that a diffusion caused by either oxygen atoms of $ZrO_2$ layers or air into the interface during annealing. Different crystal growth directions were observed with the various deposition parameters such as annealing temperature, RF power magnitude, and added $O_2$ amounts. The growth rate of $TiO_2$ thin films was increased with RF power magnitude up to 150 watt, and was then decreased due to a sputtering effect. The maximum growth rate observed at 150 watt was 1500 nm/hr. Highly oriented, crack-free, stoichiometric polycrystalline $TiO_2$<110> thin film with Rutile phase was obtained after annealing at $1000^{\circ}C$ for 1 hour.

The Interaction of Gaseous Diffusion Flames (기체확산 화염간의 상호작용)

  • 김호영;전철균
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.1
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    • pp.355-365
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    • 1991
  • New definition for the interaction of flames is introduced and interacting turbulent diffusion flames issuing from two rectangular nozzles are investigated on the basis of the definition. Theoretical study through numerical model is carried out and experiment for validation is conducted. The characteristics of interaction due to the variation of major parameters such as nozzle spacing, Reynolds number and nozzle aspect ratio are studied. Results show that strong interaction occurs for small nozzle spacing, small Reynolds number and large aspect ratio. In order of their magnitude, the intensity of interactions on the individual transport mechanism is momentum, heat and mass. It is also found that interaction makes flames longer, tilted and finally merged. Increase of velocities and temperature, decrease of oxygen concentration and depression of turbulence are occurred in the region between flames.

Plasma nitriding on chromium electrodeposit

  • Wang Liang;K.S. Nam;Kim, D.;Kim, M.;S.C. Kwon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.11a
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    • pp.29-30
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    • 2001
  • This paper presents some results of plasma nitriding on hard chromium deposit. The substrates were C45 steel and $30~50{\;}\mu\textrm{m}$ of chromium deposit by electroplating was formed. Plasma nitriding was carried out in a plasma nitriding system with $95NH_3{\;}+{\;}SCH_4$ atmosphere at the pressure about 600 Pa and different temperature from $450^{\circ}C{\;}to{\;}720^{\circ}C$ for various time. Optical microscopy and X-ray diffraction were used to evaluate the characteristics of surface nitride layer formed by nitrogen diffusion from plasma atmosphere inward iCr coating and interface carbide layer formed by carbon diffusion from substrate outward Cr coating. The microhardness was measured using microhareness tester at the load of 100 gf. Corrosion resistance was evaluated using the potentiodynamic measurement in 3.5% NaG solution. A saturated calomel electrode (SiCE) was used as the reference electrode. Fig.1 shows the typical microstructures of top surface and cross-section for nitrided and unnitrided samples. Aaer plasma nitriding a sandwich structure was formed consisting of surface nitride layer, center chromium layer and interface carbide layer. The thickness of nitride and carbide layers was increased with the increase of processing temperature and time. Hardness reached about 1000Hv after nitriding while 900Hv for unnitrided hard chromium deposit. X-ray diffraction indicated that surface nitrided layer was a mixture of $Cr_2N$ and CrN at low temperature and erN at high temperature (Fig.2). Anodic polarization curves showed that plasma nitriding can greatly improve the corrosion resistance of chromium e1ectrodeposit. After plasma nitriding, the corrosion potential moved to noble direction and passive current density was lower by 1 to 4 orders of magnitude compared with chromium deposit(Fig.3).

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CIRCULATION DYNAMICS OF THE KEUM RIVER ESTYARY (금강 하구의 해수순환역학)

  • Chung, Jong Yul;Lee, Jae Hak;An, Hui Soo
    • 한국해양학회지
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    • v.18 no.2
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    • pp.142-148
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    • 1983
  • In order to understand the circulation dynamics of the Keum River estuary, an extensive study was conducted; (i) variability of salinity boundary layer (ii) fluid dynamic characteristics (iii) tides and tidal currents (iv) circulation, diffusion, and dispersion (v) numerical modelling. As first part of this series of work, the salinity data obtained at six sites by using instantaneous profil]ing technique were analyzed in detail. it is found that the amplitude of salinity variation increases toward the upstream direction and its magnitude is greater at neap tide than spring tide. And also duration of salinity boundary layer is much longer during the neap tide than the spring tide, As a result of this study, the Keum River estuary is classified as a typical standing wave type estuary. Finally, we present a schematic diagram for the duration of the salinity boundary layer, which will be useful for further study on flocculation phenomena and sedimentation dynamics.

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Three Component Velocity Field Measurements of Turbulent Wake behind a Marine Propeller Using a Stereoscopic PIV Technique (Stereoscopic PIV 기법을 이용한 선박용 프로펠러 후류의 3차원 속도장 측정)

  • Lee, Sang-Joon;Paik, Nu-Geun;Yoon, Jong-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.12
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    • pp.1716-1723
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    • 2003
  • A stereoscopic PIV(Particle Image Velocimetry) technique was employed to measure the 3 dimensional flow structure of turbulent wake behind a marine propeller with 5 blades. The out-of-plane velocity component was determined using two CCD cameras with the angular displacement configuration. Four hundred instantaneous velocity fields were measured for each of four different blade phases and ensemble averaged to investigate the spatial evolution of the propeller wake in the near-wake region from the trailing edge to one propeller diameter(D) downstream. The phase-averaged velocity fields show the potential wake and the viscous wake developed along the blade surfaces. Tip vortices were generated periodically and the slipstream contraction occurs in the near-wake region. The out-of-plane velocity component and strain rate have large values at the locations of tip and trailing vortices. As the flow goes downstream, the turbulence intensity, the strength of tip vortices and the magnitude of out-of-plane velocity component at trailing vortices are decreased due to viscous dissipation, turbulence diffusion and blade-to-blade interaction.

Effect of Morphology on Electron Transport in Dye-Sensitized Nanostructured $TiO_2$ Films

  • Park, Nam-Gyu;Jao van de Lagemaat;Arthur J. Frank
    • Journal of Photoscience
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    • v.10 no.2
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    • pp.199-202
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    • 2003
  • The relationship between the morphology of nanostructured TiO$_2$ films and the photo-injected electron transport has been investigated using intensity-modulated photocurrent spectroscopy (IMPS). For this purpose, three different TiO$_2$ films with 5 ${\mu}{\textrm}{m}$ thickness are prepared: The rutile TiO$_2$ film with 500 nm-sized cluster-like spherical bundles composed of the individual needles (Tl), the rutile TiO$_2$ film made up of non-oriented, homogeneously distributed rod-shaped particles having a dimension of approximately 20${\times}$80 nm (T2), and the anatase TiO$_2$ film with 20 nm-sized spherically shaped particles (T3). Cross sectional scanning electron micrographs show that all of the TiO$_2$films have a quite different particle packing density: poorly packed Tl film, loosely packed T2 film and densely packed T3 film. The electron transport is found to be significantly influenced by film morphology. The effective electron diffusion coefficient D$_{eff}$ derived from the IMPS time constant is an order of magnitude lower for T2 than for T3, but the D$_{eff}$ for the Tl sample is much lower than T2. These differences in the rate of electron transport are ascribed to differences in the extent of interparticle connectivity associated with the particle packing density.ity.

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Two-Dimensional Analysis of Unsteady Flow through One Stage of Axial Turbine (I) (1단 축류 터빈의 비정상 내부유동특성에 관한 2차원 해석(I))

  • Park, Jun Young;Um, InSik;Baek, Je Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1371-1378
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    • 1999
  • Flow through turbomachinery has a very complex structure and Is Intrinsically unsteady. In addition, trend to highly loaded turbomachinery makes the flow extremely complex due to the interaction between rotor and stator. In this study, flows through UTRC LSRR turbine are numerically analyzed using 2 dimensional Navier-Stokes equations. The convective terms of the governing equations are discretized using the Van-Leer's FVS(Flux vector splitting) with an upwind TVD scheme. The conventional central differencing is used to discretize the diffusion terms on the finite volume. The accurate unsteady motion is achieved by using a 2nd order accurate, 3-point Euler implicit scheme. The quasi-conservative zonal scheme is used for calculating the flow variables on the zonal interface between the rotor and stator. The axial gap between stator and rotor has been configured in two variations, 15% and 65% of average chord length. The analysis program is validated using experimental results and the effect of axial gap is examined. The numerical analysis results are presented by time averaged pressure coefficient and pressure magnitude coefficient and compared with experimental results.