• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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• pp.109-110
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• 2005

We have suggested sputtered W-C-N thin film for preventing thermal budget between semiconductor and metal. These results show that the W-C-N thin film has good thermal stability and low resistivity. In this study we newly suggested sputtered W-B-C-N thin diffusion barrier. In order to improve the characteristics, we examined the impurity behaviors as a function of nitrogen gas flow ratio. This thin film is able to prevent the interdiffusion during high temperature (700 to $1000^{\circ}C$) annealing process and has low resistivity ($\sim$200$\mu{\Omega}-cm$). Through the analysis of X-Ray diffraction, resistivity and XPS, we studied structure behavior of W-B-C-N diffusion barrier.

• 한국표면공학회지
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• 제28권5호
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• pp.320-328
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• 1995

The electroplated steel sheets were heated during the short periods(10~60 seconds) at high temperature ($360^{\circ}C$～$500^{\circ}C$) in order to investigate thermal diffusion behaviors. When the steel sheets were heated for 10 seconds, all the coated layers were alloyed at $420^{\circ}C$ but at temperature lower than $400^{\circ}C$ the $\eta$ phase partially remained on the coated surface. At higher temperature, the longer the time for heat treatment the iron contents were increased in coated layer but the glossiness and whiteness of the coated surface were decreased. While the alloying phases of $\eta$, $\zeta$, $\delta_1$ and $\Gamma$ were appeared in the coated layer at the heat treatment temperature of $360^{\circ}C$, the phase was disappeared at $420^{\circ}C$ but the rests grew in size at the temperature of $440^{\circ}C$. When the heat treatment temperature and heating time were increased, the thickness of $\Gamma$ phase was rapidly increased to 0.8 $\mu\textrm{m}$. The optimum conditions for the heat treatment to prevent powdering of coated layer were obtained to heat it for 30 seconds at $400^{\circ}C$ and 10 seconds at $440^{\circ}C$, and the iron content in coated layer was suited to be 10 percents.

• Corrosion Science and Technology
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• 제9권3호
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• pp.129-136
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• 2010

The corrosion behaviors of 316L stainless steel were investigated in simulated anodic and cathodic environments for proton exchange membrane fuel cell (PEMFC) by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the stainless steel and gas diffusion layer(GDL) was also measured. The possibility of 316L was evaluated as a substitute material for the graphite bipolar plate of PEMFC. The value of ICR decreased with an increase in compaction stress(20 N/$cm^2$~220 N/$cm^2$) showing the higher values than the required value in PEMFC condition. Although 316L was spontaneously passivated in simulated cathodic environment, its passive state was unstable in simulated anodic environment. Potentiostatic and electrochemical impedance spectroscopy (EIS) measurement results showed that the corrosion resistance in cathodic condition was higher and more stable than that in anodic condition. Field emission scanning electron microscopy (FE-SEM), and inductively coupled plasma(ICP) were used to analyze the surface morphology and the metal ion concentration in electrolytes.

• 한국세라믹학회지
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• 제50권6호
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• pp.523-527
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• 2013

Ti-based coatings following laser ablation were studied to compare degradation behaviors by thermomechanical stress. TiN, TiCN, and TiAlN coatings were degraded by a Nd:YAG pulsed laser with an increase in the laser pulses. A decrease in the hardness was identified as the pulses increased, and the hardness levels were in the order of TiAlN > TiCN > TiN. The TiN showed cracks on the surface, and cracks with pores formed along the cracks were observed in the TiCN. The dominant degradation behavior of the TiAlN was surface pore formation. EDS results revealed that diffusion of substrate atoms to the coating surface occurred in the TiN. Delamination occurred in the TiN and TiCN, while the TiAlN which has higher thermal stability than the TiN and TiCN maintained adhesion to the substrate. It was considered that the decrease in the hardness of the Ti-based hard coatings is attributed to surface cracking and the diffusion of substrate atoms.

• 한국수산과학회지
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• 제23권3호
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• pp.215-224
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• 1990

포화상태인 물질의 역학적, 수리학적 거동을 연구할 수 있는 유한요소법적 수치해석모델을 개발하여 부산 남항 인근해역의 미고결 퇴적물의 거동을 분석하였다. 하중재하에 의한 상부세립 퇴적물의 역학적 변형은 공극수의 확산에 따른 공극수압의 수리학적 변화에 크게 영향을 받는 것으로 나타났다. 하중이 일정지역에 편재되어 있을 경우 포아송효과 및 과잉공극수압의 영향에 의해 하중을 직접 받지 않는 표층부분이 융기되며, 하중경계지역에서 멀어질수록 점근적으로 증가한다. 세립점토층에 비해 높은 투수성을 갖는 하부 모래층은 공극수확산의 통로역할을 하여 과잉공극수압의 소멸을 촉진시키며, 결과적으로 상부점토층 변형의 시간적 변화에도 영향을 끼친다.

• 대한기계학회논문집B
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• 제27권9호
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• pp.1209-1219
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• 2003

The dynamic behaviors of the single vortex interacting with $CH_4-Air$ jet diffusion flame are investigated numerically. The numerical method is based on a predict-corrector scheme for a low Mach number flow. A two-step global reaction mechanism is adopted as a combustion model. Studies are conducted in fixed initial velocities for the three cases according as where $CO_2$ is added; (1) without dilution, (2) dilution in fuel stream and (3) dilution in oxidizer stream. A single vortex is generated by an axisymmetric jet, which is made by an impulse of a cold fuel when a flame is developed entirely in a computational domain. The simulation shows that $CO_2$ dilution in fuel stream results in somewhat larger vortex radius, and greater amount of entrainment of surrounding fluid than in other cases. Thus, the dilution of $CO_2$ in fuel stream enhances the mixing in single vortex and increases the stretching of the flame surface. The budgets of the vorticity transport equation are examined to reveal the mechanism of vortex formation when $CO_2$ is added. It is found that, in the case of $CO_2$ dilution in fuel stream, the vortex destruction due to volumetric expansion and the vortex production due to baroclinic torque are more dominant than in other cases.

• 폴리머
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• 제31권3호
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• pp.177-183
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• 2007

본 연구에서는 라벤더 오일을 심물질로 이용하여 나노크기의 폴리(비닐 아세테이트)(poly(vinyl acetate), PVAc) 방향 입자를 유화-확산법으로 제조하였다. 방향 물질의 방출 시기와 속도 조절로 방향 캡슐의 지속성과 내구성을 얻기 위하여 제조 조건에 따른 나노 방향 입자의 특성과 방출 거동을 주사 전자 현미경, 전기 영동 광산란 분광 분석기, 자외선-가시광선 분광 분석기 및 고성능 액체 크로마토그래피를 이용하여 고찰하였다. 제조된 방향 입자는 실험 조건을 조절함에 따라 평균 입자 크기가 224 nm인 구상 나노 입자로 제조하는 것이 가능하였으며, 170시간 동안의 방출 거동을 비교.평가한 결과 PVA로 코팅한 방향 입자가 더 지속적이고 안정적인 초기 방출 거동을 보임을 확인할 수 있었다. 본 연구의 PVAc 나노 방향 입자는 직물 및 피혁제품 등에 대한 내구성 방향가공에 적용될 수 있을 것으로 기대된다.

• 한국구조물진단유지관리공학회 논문집
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• 제23권6호
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• pp.9-17
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• 2019

콘크리트의 수화물 및 이와 관련된 특성치들은 재령에 따라 변화하며 이는 염화물 확산성과 큰 관련이 있다. 본 연구에서는 세 가지 수준의 물-결합재 비와 플라이 애시 및 고로슬래그 미분말을 30% 혼입한 콘크리트 대하여 2년간 장기 양생을 수행하였다. 5번의 측정 시점(28일, 56일, 180일, 365일, 730일)에 대하여 촉진실험을 통하여 촉진 염화물 확산계수를 평가하였으며, DUCOM을 통하여 도출된 공극률, 염화물 구속능, 투수계수의 변화와 비교하였다. 염화물 확산성과 투수성의 변화 패턴이 가장 유사하였는데, 이는 투수성이 공극률의 제곱에 비례하기 때문이다. 또한, 각 재령 기간 동안 변화하는 비율을 분석하였는데, 초기 재령(재령 28일~56일)에서 공극률, 투수성 및 염화물 확산성의 변화가 지배적이었고, 낮은 물-결합재 비를 가진 OPC 콘크리트에서는 180일까지 확산성의 변화가 지속적으로 크게 평가되었다.

• 한국대기환경학회지
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• 제26권2호
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• pp.219-233
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• 2010

Understanding the Nano size particles is of great interest due to their chemical and physical behaviors such as compositions, size distributions, and number concentrations. Therefore, accurate measurements of size distributions and number concentrations in ultrafine particles are getting required because expected losses such as diffusion for the instrument system from ambient inlet to detector are a significant challenge. In this study, the data using the computed settling losses, impaction losses, diffusion losses for the sampling lines (explored different sampling line diameters, horizontal length, number of bending, line angles, flow rates with and without a bypass), and diffusion losses for the Scanning Mobility Particle Sizers are examined. As expected, the settling losses and impaction losses are very minor under 100 nm, however, diffusion loss corrections for the sampling lines and the size instrument make a large difference for any measurement conditions with high numbers of particles smaller mobility size. Both with and without the loss corrections, which can affect to size distributions and number concentrations are described. First, 80% or more of the smallest particles (less than 10 nm) can be lost in the condition of a flow rate of 0.3 liter per minute and the length of sampling line of 1.0 m, second, total number concentrations of measurements are quite significantly affected, and the mode structure of the size distribution changes dramatically after the loss corrections applied. With compared to the different measurements, statistically diffusion loss corrections yield a required process of the ambient particle concentrations. Based on the current study, as an implication, a possibility of establishing direct revelation mechanisms is suggested.

• 한국안전학회지
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• 제30권3호
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• pp.123-134
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• 2015

This study was conducted with the following three study objectives. First, effects of safety awareness level of lab researchers to the improvement of safety culture in the organization Second, effects of organizational safety behaviors to the improvement of safety culture Third, test of mediating effects of organizational safety behaviors in the relationship between safety awareness level and the improvement of safety culture. The results show that organizational safety behavior is an indispensable factor for the improvement level of safety culture. Especially, the factors in safety training activities, safety compliance and management system are mediating variables which affect the safety awareness level and improvement level of safety culture, which shows these variables are very important factors in reducing safety accidents through the improvement of safety culture. Therefore, safety behaviors in the organization should be considered with priority. If the organization leads to improve safety awareness through regular safety training and rewards and punishes according to the test results, safety awareness could be improved. This study was conducted to identify the necessary factors to improve the overall safety culture in the organization and contribute to the diffusion of safety culture by improving the safety training awareness of the researchers.