• 제목/요약/키워드: Diffusion Transformation

검색결과 148건 처리시간 0.021초

FDM과 FEM의 해석 데이터 변환에 의한 탄소성 열응력 해석 (Thermal Stress Analysis by Field Data Conversion between FDM and FEM)

  • 곽시영;조종두
    • 열처리공학회지
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    • 제14권4호
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    • pp.228-234
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    • 2001
  • The present study was an attempt for systematic data conversion between FDM and FEM in order to evaluate the thermal stress distribution during quenching process. It has been generally recognized that FDM is efficient in flow and temperature analysis and FEM in that of stress. But it induced difficulty and tedious work in analysis that one uses both FDM and FEM to take their advantages because of the discrepancy of nodes between analysis tools. So we proposed field data conversion procedure from FDM to FEM in 3-dimensional space, then applied this procedure to analysis of quenching process. The simulation procedure calculates the distributions of temperature and microstructure using FDM and microstructure evolution equations of diffusion and diffusionless transformation. FEM was used for predicting the distributions of thermal stress. The present numerical code includes coupled temperaturephase transformation kinetics and temperature-microstructure dependent material properties. Calculated results were compared with previous experimental data to verify the method, which showed good agreements.

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입자의 크기와 유속에 따른 섬유질 여과포에 의한 부유입자 제거 연구 (Removal of Aerosol Through Fibrous Filter as a Function of Particle Size and Velocity)

  • Sang Hoon Lee;Kwan Sik Chun;Hoo Keun Lee
    • Nuclear Engineering and Technology
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    • 제16권1호
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    • pp.29-35
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    • 1984
  • 유리섬유 여과포에 의한 0.1~0.45$\mu\textrm{m}$ 크기의 DOP 부유입자의 제거효율시험을 1~10cm/sec의 유속범위에서 수행하였다. 섬유여과포에 의한 미세입자의 여과는 여과속도에 의하여 결정되는데, 최소제거 효율을 나타내는 DOP 입자의 크기는 여과속도가 증가함에 따라 감소한다. Kuwabara Cell Model과 Von Mises Transformation을 사용하여 유리섬유 여과포내에서 화산에 의한 입자 제거효율을 수치해석적으로 전개하여 구하였으며, 이 계산치는 실험치와 잘 일치하였다. 본 실험의 결과는 여과포의 입자제거효율을 예측하고 최적 운전조건을 추구하는데 기여할 수 있을 것이다.

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연소합성 TiO2 나노입자의 고온 상변환 특성에 관한 연구 (Phase Transformation Characteristics of Combustion-Synthesized TiO2 Nanoparticles)

  • 최상민;이교우
    • 대한기계학회논문집B
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    • 제32권3호
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    • pp.224-230
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    • 2008
  • In this article, $TiO_2$ nanoparticles were synthesized by using $O_2$-enriched coflow, hydrogen, diffusion flames. We investigated the thermal stability of the flame-synthesized $TiO_2$ nanoparticles by examining the crystalline structures of the nanoparticles. Also, the results were compared with those of commercial P-25 nanoparticles. $TiO_2$ nanoparticles, which were spherical with diameters approximately ranging from 30 to 60nm, were synthesized. From the XRD analyses, about 96wt% of the synthesized nanoparticles were anatase-phase. After the heat-treatment at $800^{\circ}C$ for 30 minutes, the synthesized $TiO_2$ nanoparticles showed no significant changes of their shapes and crystalline phases. On the other hand, most of the commercial particles sintered with each other and changed to the rutile-phase. Based on the result of XRD analysis it is believed that the flame-synthesized $TiO_2$ nanoparticles have higher thermal stability at $800^{\circ}C$ than the commercial particles.

기계적합금화법에 의해 제조된 NiAl 나노금속간화합물 소결체의 인성 및 제진특성 (Toughness and Damping Properties of Nanostructured Ni-Al Alloys Produced by Mechanical Alloying Methods)

  • 안인섭;김형범;김영도;김지순
    • 한국분말재료학회지
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    • 제7권3호
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    • pp.143-148
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    • 2000
  • NiAl alloy powders were prepared by mechanical alloying method and bulk specimens were produced using hot isostatic pressing techniques. This study focused on the transformation behavior and properties of Ni-Al mechanically alloyed powders and bulk alloys. Transformation behavior was investigated by differential scanning calorimeter (DSC), XRD and TEM. Particle size distribution and microstructures of mechanically alloyed powders were studied by particle size analyzer and scanning electron microscope (SEM). After 10 hours milling, XRB peak broadening appeared at the alloyed powders with compositions of Ni-36at%Al to 40at%Al. The NiAl and $Ni_3Al$ intermetallic compounds were formed after water quenching of solution treated powders and bulk samples at $1200^{\circ}C$, but the martensite phase was observed after liquid nitrogen quenching of solution treated powders. However, the formation of $Ni_3Al$ intermetallic compounds were not restricted by fast quenching into liquid nitrogen. It is considered to be caused by fast diffusion of atoms for the formation of stable $\beta$(NiAl) phase and $Ni_3Al$ due to nano sized grains during quenching. Amounts of martensite phase increased as the composition of aluminium component decreased in the Ni-Al alloy, which resulted in the increasing damping properties.

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용매를 매체로 한 Hexanitrohexaazaisowurtzitane(HNIW)의 상전이 속도에 관한 연구 (Study on Solvent Mediated Phase Transformation Kinetics of Hexanitrohexaazaisowurtzitane(HNIW))

  • 김준형;임유진
    • 한국추진공학회지
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    • 제4권4호
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    • pp.9-17
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    • 2000
  • 준안정상인 $\beta$형 HNIW의 용해와 안정상인 $\varepsilon$형 HNIW의 성장 특성을 고려한 모델식을 물질수지와 한께 계산하는 방법으로 결정성장 속도와 용해 속도를 계산하였다. 제시된 모델은 용액을 매체로 하여 진행되는 $\beta$$\longrightarrow$$\varepsilon$전이 현상에 대한 속도론적 데이터를 모사 하는데 유용하였다. 2 단 모델을 이용한 유효 인수로부터, 격정성장 과정에서 표면 축적 단계의 영향은 작으며, 확산 의존성은 ethyl acetate와 chloroform의 혼합 용매 중 chloroform의 함량이 증가함에 따라 감소함을 보였다. 이들 속도론 적 계수들을 이용한 수치모사를 통하여 $\varepsilon$-HNIW의 입자 크기를 예측하는 것이 가능하였다.

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Modern Housing Complexes in South Korea. An Educational Analysis to Evaluate the Typological Evolution and Urban Adaptations

  • Pedrabissi, Dario
    • 실천공학교육논문지
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    • 제9권1호
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    • pp.85-90
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    • 2017
  • The contemporary South Korean landscape is characterised by a massive display of modern apartment buildings. They are omnipresent in their monotonous manifestation and represent the dream of the Korean population. Serial mass housing is a typology that has had a great diffusion all over the world, but how has modern housing developed in South Korea? To this end, what are the resulting local adaptations?. This paper retraces these key evolutional aspects. Methodologically, it draws on a scholarly literature review as well as on-site photographic surveys, developed in connection with an educational program at the Korea Tech University. The result is the analysis of both the urban and architectural transformation from the early modernisation period to the present condition of contemporary housing. A historical background introduces Korean traditional urban houses, to be used as a context to describe the contemporary modern city that has developed since the 1960s. The main emphasis is then placed on the urbanisation process that fully matured during the 1980s together with a focus on the mass housing typology as the main pivot in the urban transformation. Finally, the paper will draw a parallel between modern Western theories and Korean applications.

하이브리드 습식 공정을 통한 PVDF 섬유의 제조 및 특성에 관한 연구 (Characterization of the PVDF Fibers Fabricated by Hybrid Wet Spinning)

  • 정건;김성수
    • Composites Research
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    • 제29권4호
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    • pp.145-150
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    • 2016
  • Polyvinylidene fluoride (PVDF)는 압전성을 나타내는 대표적인 고분자로 1960년대부터 많은 연구가 진행되어 왔다. PVDF는 반결정의 고분자로써 5가지의 결정 구조(${\alpha}$, ${\beta}$, ${\gamma}$, ${\delta}$, 그리고 ${\varepsilon}$형)로 구성되어 있다. ${\alpha}$형과 ${\delta}$형 결정은 전기적으로 반응하지 않는 무극성 결정구조이나 ${\beta}$형, ${\gamma}$형 그리고 ${\varepsilon}$형은 전기적으로 반응하는 극성 결정구조이다. 그 중에서도 ${\beta}$형 결정구조는 트랜스 형 분자 쇄가 평행으로 충진 된 형태로서 PVDF 단위체가 갖는 영구 쌍극자가 모두 한 방향으로 배열되어 있는 구조이기 때문에 자발 분극이 커지게 되고 압전성을 나타내게 된다. 일반적으로 ${\beta}$형 결정구조는 연신을 통한 ${\alpha}$형 결정구조의 변환을 통하여 얻을 수 있고, 연신 후 후처리 공정을 통해 그 양을 증가시킬 수 있다. 습식방사로 제조된 PVDF 섬유는 응고욕에서 극성 용매의 확산 메커니즘에 의해 ${\beta}$형 결정구조가 형성되는 장점을 가지고 있지만 극성 용매가 빠져나감과 동시에 섬유 고화가 진행되기 때문에 용매의 확산 경로가 섬유 내부 기공으로 남게 되는 단점을 가지고 있다. 이 기공은 폴링(Poling) 공정에서 전기장에 의한 분극을 방해하여 그 효과를 감소시키는 역할을 한다. 또한, PVDF 섬유가 압전 특성을 필요로 하는 응용분야에 사용되기 위해서는 섬유 가공 후에 전극이 반드시 부착되어야 하는데 섬유 형태로 제조된 PVDF에 전극을 형성하기는 매우 어렵다. 본 연구에서는 압전성을 갖는 PVDF 섬유를 습식 방사와 건식 방사의 혼합 공정으로 제조하여 기공 문제를 해결하였고, 전극이 섬유 내부에 삽입된 Core/Shell 형태의 PVDF 섬유를 제조하여 까다로운 전극형성 문제를 해결하였다.

Effect of Phosphoric Acid on the Electronic and Diffusion Properties of the Anodic Passive Layer Formed on Pb-1.7%Sb Grid of Lead-acid Batteries

  • El-Rahman, H.A. Abd;Salih, S.A.;El-Wahab, A.M. Abd
    • Journal of Electrochemical Science and Technology
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    • 제2권2호
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    • pp.76-84
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    • 2011
  • Potentiostatic oxidation of Pb-1.7%Sb alloy used in the manufacture of grids of lead-acid batteries over the potential range from -1.0V to 2.3V in 5M $H_2SO_4$ in the absence and the presence of 0.4M $H_3PO_4$ and the self-discharge characteristics of the oxide layer formed is studied by electrochemical impedance spectroscopy (EIS). Depending on the potential value, sharp variations in resistance and capacitance of the alloy are recorded during the oxidation and they can be used for identification of the various substances involved in passive layer. Addition of $H_3PO_4$ is found to deteriorate the insulating properties of the passive layer by the retardation of the formation of $PbSO_4$. $H_3PO_4$ completely inhibits the current and impedance fluctuations recorded in $H_3PO_4$-free solutions in the potential range 0.5 V-1.7 V. These fluctuations are attributed to the occurrence of competitive redox processes that involve the formation of $PbSO_4$, $PbOSO_4$, PbO and $PbO_2$ and the repeated formation and breakdown of the passive layer. Self-discharge experiments indicate that the amount of $PbO_2$ formed in the presence of $H_3PO_4$ is lesser than in the $H_3PO_4$-free solutions. The start of transformation of $PbSO_4$ into $PbO_2$ is greatly shortened. $H_3PO_4$ facilitates the diffusion process of soluble species through the passive layer ($PbSO_4$ and basic $PbSO_4$) but impedes the diffusion process through $PbO_2$.

왕권과 교권의 대립을 통해 본 신대륙의 가톨릭 전파과정 연구 (The study on the diffusion of Catholicism in the New World: focused on the relationship between the king and the pope)

  • 이성훈
    • 비교문화연구
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    • 제37권
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    • pp.7-29
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    • 2014
  • The 'discovery' or 'conquest' of the New World in 1492 was the starting point of world history that irrevocably changed the fate of the Latin American continent. The global stream known as 'Columbian Exchange', which was the widespread inter-continental contacts, inter-civilizational conflicts, or bilateral communication, has rendered multifarious effects throughout many historical periods up to the very contemporary time. The propagation of Catholicism initiated along with this 'discovery' transformed Latin America of nowadays in the region that has the biggest Catholic population in the world. The previous studies in Korea regarding Latin American Catholicism has focused on the spread of Catholicism in relation to the European colonization, rather than analyzing the concrete and detailed ways in which Catholicism exerted tremendous influences in the whole continent. They were less attentive to various historical contexts in which the diffusion of Catholicism differed greatly according to cultural landscapes and political specificities. Thus, this essay attempts to examine the diffusion of Catholicism from the perspective of confrontation between royal authorities and the power of church. The essay points out that the royal communities and institutional authorities which facilitated the intial process of Catholic evangelization maintained antagonistic relationship with ecclesial powers. By delving into the gradual transformation of church systems, it reveals that Catholicism in Latin America became a major field for conquerors in power to attain economic and political dominance. And unlike the initial submission and hospitality, the religious convert of the indigenous people attested to the violent inhumanity and opposition. Therefore, the essay aims to pave a clearer way to the understanding of complicated dynamics and conflicts between Catholicism in Latin America and the establishment of Spanish colonization.

4~8%Mn 열연 TRIP강의 잔류오스테나이트 생성과 기계적 성질 (Formation of Retainted Austenite and Mechanical Properties of 4~8%Mn Hot Rolled TRIP Steels)

  • 김동은;박영구;이오연;진광근;김성주
    • 한국재료학회지
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    • 제15권2호
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    • pp.115-120
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    • 2005
  • The aim of this research is to develop the TRIP aided high strength low carbon steels using reverse transformation process. The $4\~8\%$ Mn steel sheets were reversely transformed by slow heating to intercritical temperature region and furnace cooling to room temperature. The stability of retained austenite depends on the enrichment of carbon and manganese by diffusion during the reverse transformation. The amount of retained austenite formed after reversely transformed at $625^{\circ}C$ for 6 hrs was about $50\;vol.\%$ in the $8\%Mn$ steel. The change in volume fraction of retained austenite with a holding temperature was consistent with the changes in elongation and the strength-ductility combination. The maximum strength-ductility combination of 40,000 $MPa{\cdot}\%$ was obtained when the $8\%Mn$ steel reversely transformed at $625^{\circ}C$ for 12 hrs. However, it's property was significantly decreased at higher holding temperature of $675^{\circ}C$ resulting from the decrease of ductility.