• Title/Summary/Keyword: Diffusion Plate

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Development of the Ag/Cu Ingots for Mokumegane Jewelry (모꾸메가네 장신구를 위한 은/동 접합 잉곳 소재 개발)

  • Song, Oh-Sung;Kim, Jong-Ryul;Kim, Myung-Ro
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.1
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    • pp.9-15
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    • 2008
  • Mokumegane is one of the sophisticated metal craft techniques enabling wood grain surface effect. To embody the mokumegane, an ingot of well-bonded stacked metal plates has been required. Traditionally prepared mokumegane ingots were bonded using charcoal which enables reduction atmosphere, but sometimes end up with collapse of bonding interface due to the lack of reliable process control. We proposed a systematic vacuum direct bonding process for ingots. First, we confirmed copper//copper homogeneous plate bonding at $900^{\circ}C$ by applying uniaxial press of 2.5kg. We observed 80min required to obtain 90%-bonding ratio and the diffusion coefficient would be enhanced up to 100 times due to surface effect. Second, by considering enhanced diffusion behavior, we also obtained optimum bonding condition in copper/silver heterogeneous plates that ensures 90%-bonding ratio at $700^{\circ}C$ for 10min with apply uniaxial press. A 7-layered copper/silver ingot is prepared successfully, and eventually the prototype mokumegane cases for mobile phone were fabricated with these ingot.

A Numerical Study of the Residual Hydrogen Concentration in the Weld Metal (용접금속 잔류수소농도의 수치해석 연구)

  • Yoo, Jinsun;Ha, Yunsok;S.R., Rajesh
    • Journal of Welding and Joining
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    • v.34 no.6
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    • pp.42-46
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    • 2016
  • Hydrogen assisted cracking (HAC) is one of the most complicated problem in welding. Huge amount of studies have been done for decades. Based on them, various standards have been established to avoid HAC. But it is still a chronic problem in industrial field. It is well known that the main causes of the hydrogen crack are residual stress, crack susceptible micro structures and a certain critical level of hydrogen concentration. Even though the exact generating mechanism is unclear till today, it has been reported that the hydrogen level in the weld metal should be managed less than a certain amount to prevent it. Matsuda studied that the residual hydrogen level in the weld metal can be varied even if the initial hydrogen content is same. It is also insisted in this report that the residual hydrogen concentration is in stronger correlation with hydrogen crack than the initial hydrogen content. But, in practical point of view, the residual hydrogen is still hard to consider because measuring hydrogen level is time and cost consuming process. In this regard, numerical analysis is the only solution for considering the residual hydrogen content. Meanwhile, Takahashi showed the possibility of predicting the residual hydrogen by a rigorous FE analysis. But, few commercial software suitable for solving the weld metal hydrogen has been reported yet. In this study, two dimensional thermal - hydrogen coupled analysis was developed by using the commercial FE software MARC. Since the governing equation of the hydrogen diffusion is similar to the heat transfer, it is shown that the heat transfer FE analysis in association with hydrogen diffusion property can be used for hydrogen diffusion analysis. A series of simulation was performed to verify the accuracy of the model. For BOP (Bead-On-Plate) and the multi-pass butt welding simulations, remaining hydrogen contents in the weld metal is well matched with measurements which are referred from Kim and Masamitsu.

The Stress Distribution Analysis of PEMFC GDL using FEM (유한요소법을 이용한 고분자전해질연료전지 기체확산층의 응력분포 연구)

  • Kim, Chulhyun;Sohn, Youngjun;Park, Gugon;Kim, Minjin;Lee, Jonguk;Kim, Changsoo;Choi, Yusong;Cho, Sungbaek
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.468-475
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    • 2012
  • A proper stacking force and assembly are important to the performance of fuel cell. Improper assembly pressure may lead to leakage of fuels and high interfacial contact resistance, excessive assembly pressure may result in damage to the gas diffusion layer and other components. The pressure distribution of gas diffusion layer is important to make interfacial contact resistance less for stack performance. To analyze the influence of design parameter factors for pressure distribution, and to optimize stack design, DOE (Design of Experiment) was used for polymer electrolyte membrane fuel cell stack pressure test. As commonly known, the higher clamping force improves the fuel cell stack performance. However, non-uniformity of stress distribution is also increased. It shows that optimization between clamping force and stress distribution is needed for well designed structure of fuel cell stack. In this study, stack design optimization method is suggested by using FEM (Finite Element Methode) and DOE for light-weighted fuel cell stack.

Development and Evaluation of Bipolar Plates Coated with Noble Metals for Polymer Electrolyte Membrane Fuel Cells (Noble Metal이 코팅된 금속분리판 개발 및 성능 평가)

  • Seo, Hakyu;Han, In-Su;Jung, Jeehoon;Kim, Minsung;Shin, Hyungil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.90.2-90.2
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    • 2010
  • The coated metallic bipolar plates are getting attractive due to their good feasibility of mass production, low contact resistance, high electrical/thermal conductivity, low gas permeability and good mechanical strength comparing with graphite materials. Yet, metallic bipolar plates for polymer electrolyte membrane(PEM) fuel cells typically require coatings for corrosion protection. Other requirements for the corrosion protective coatings include low electrical contact resistance between metallic bipolar plate and gas diffusion layer, good mechanical robustness, low mechanical and fabrication cost. The authors have evaluated a number of protective coatings deposited on stainless steel substrate by electroplating. The coated metallic bipolar plates are investigated with an electrochemical polarization tests, salt dipping tests, adhesion tests for corrosion resistance and then the contact resistance was measured. The results showed that the selective samples electroplated with optimized method, satisfied the DOE target for corrosion resistance and contact resistance, and also were very stabilized in the typical fuel cell environments in the long-term.

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The Effect of Mixing Region in Mixed Multiple Serpentine Flow-field to PEMFC Performance (혼합 다채널 사형 유로의 혼합영역이 PEMFC 성능에 미치는 영향)

  • Lee, Ji-Hong;Lee, Myeong-Yong;Kim, Hun-Ju;Lee, Sang-Seok;Lee, Do-Hyung
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.4
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    • pp.265-273
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    • 2009
  • Proton Exchange Membrane Fuel Cell (PEMFC) has low operating temperature and high efficiency. And PEMFC consists of many components as bipolar plate, gas diffusion layer, membrane etc.. Flow-field in bipolar plate roles path for transporting reactants to membrane. Therefore a design of flow-field has an effect on PEMFC's performance. In this study, Computational Fluid Dynamics (CFD) simulations were performed for comparing mixed multiple serpentine (MMS) flow-field and multiple serpentine (MS) flow-field. And we studied an effect according to change mixing region design in MMS flow-field. Finally the applicability of results is verified by performing CFD simulation about fixed MMS flow-field which is combined good designs.

Quantitative Visualization of Dissolved Oxygen Concentration Field in Micro Flows using PtOEP/PS Membrane (마이크로 유동에서 PtOEP/PS 박막을 이용한 용존 산소 농도장의 정량적 가시화)

  • Song, Dae-Hun;Kim, Hyun-Dong;Kim, Kyung-Chun
    • Journal of the Korean Society of Visualization
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    • v.9 no.1
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    • pp.36-41
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    • 2011
  • It is highly needed to measure the dissolved oxygen (DO) concentration field in water for a variety of purposes such as biological, industrial, environmental monitoring and medical application. Application of PSP (Pressure Sensitive Paint) which is sensitive to oxygen concentration has been carried out to measure DO concentration field using PtOEP/PS film and intensity based method under the UV-LEDs illumination. A micro round water jet having 100% of DO was obliquely impinged on to a PtOEP/PS film coated plate placed in a 0% of DO water container. DO concentration fields on the impinging plate were quantitatively visualized with a $2.94\;{\mu}m$ of spatial resolution. Through pixel-by-pixel calibration, uncertainty of each pixel by different sensitivity, different dye concentration and non-uniformity of illumination was removed. It is demonstrated that the high DO concentration region was coincided with the impingement area. The DO concentration gradient due to DO diffusion was affected by Reynolds number.

Activation Energy and Interface Reaction of Sn-40Pb/Cu & Sn-3.0Ag-0.5Cu/Cu (Sn-40Pb/Cu 및 Sn-3.0Ag-0.5Cu/Cu 접합부 계면반응 및 활성화에너지)

  • Kim, Whee-Sung;Hong, Won-Sik;Park, Sung-Hun;Kim, Kwang-Bae
    • Korean Journal of Materials Research
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    • v.17 no.8
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    • pp.402-407
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    • 2007
  • In electronics manufacturing processes, soldering process has generally been used in surface mounting technology. Because of environmental restriction, lead free solders as like a SnAgCu ternary system are being used widely. After soldering process, the formation and growth of intermetalic compounds(IMCs) are formed in the interface between solder and Cu substrate as follows isothermal temperature and time. In this studies, therefore, we investigated the effects of the Cu substrate thickness on the IMC formation and growth of Sn-40Pb/Cu and Sn-3.0Ag-0.5Cu/Cu solder joints, respectively. The effect of the Cu thickness in PCB Cu pad and pure Cu plate was analyzed as measuring of thickness of each IMC. After solder was soldered on PCB and Cu plate which have different Cu thickness, we measured the IMC thickness in solder joints respectively. Also we compared with the effectiveness of Cu thickness on the IMC growth. From these results, we calculated the activation energy.

A Study on the Fiber Laser welding of Ultra-Low Carbon Interstitial Free Steel for Automotive (자동차용 무침입형 극저탄소강의 파이버 레이저 용접에 대한 연구)

  • Oh, Yong-Seok;Shin, Ho-Jun;Yang, Yun-Seok;Hwang, Chan-Youn;Yoo, Young-Tae
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.3
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    • pp.342-349
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    • 2011
  • The purpose of this paper is to describe experimental results about the butt welding and bead on plate welding of the high power Continuous Wave (CW) Fiber laser for Ultra-low carbon Interstitial Free(IF) steel plate for gear part of car. After being welded of the gear parts by the fiber laser and electron beam Microstructures of melting zone had been mixed acicular, granular bainitic, quasi-polygonal and widmanstatten ferrite because of a radical thermal diffusion after welding, difference of critical volume and grain size. As a result of experiment, when gear parts were welded by the fiber laser and electron beam, the fiber laser welding has been stable properties without internal defects more than the electron beam welding. Therefore it has the very advantages of welding high quality and productivity more than conventional melting method. The optimal welding processing parameters for gear parts were as follows : the laser power and welding speed were 3kWatt, 30mm/sec respectively. At this time heat input was $21.2{\times}10^3J/cm^2$.

Effect of Clamping Pressure on Surface Properties of Gas Diffusion Layer in PEFCs (체결압이 고분자연료전지 기체확산층의 표면성질에 미치는 영향)

  • Ahn, Eun-Jin;Park, Gu-Gon;Yoon, Young-Gi;Park, Jin-Soo;Lee, Won-Yong;Kim, Chang-Soo
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.306-310
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    • 2007
  • Characteristics of GDL (Gas Diffusion Layer) mainly determine the gas diffusion and water removal in a cell, thereby changing the performance and affecting durability of PEFC. To optimize the water management and understand the two phase flow in a GDL, it is important to study the behaviors of GDL micro structure under the real operating condition. In the clamped condition of cell, the GDL beneath the rib is more compressed than beneath the channel. Many researches on physical, electrochemical, mechanical behaviors of gas diffusion layer has been conducted. However, changes in surface properties under clamped condition have rarely studied. In present study, the morphology of broken connections of carbon fibers and detachment of PTFE coatings on the fibers were shown from the microscopic observations. In addition, changes in wetting properties of GDL by compression were investigated by using XPS and liquid uptake methods. The hydrophobic characteristics of GDL surface beneath the rib of the flow field plate are changed due to the deformation of micro structure.

Comparison of the Modulation Transfer Function of Several Image Plate (Image Plate(IP) 영상의 MTF 비교)

  • Kim, Chang-Bok;Lee, Yang-Sup;Kim, Young-Keun;Lee, Seong-Kil;Lee, Kyung-Sup
    • Journal of radiological science and technology
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    • v.27 no.3
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    • pp.25-29
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    • 2004
  • Among the digital radiography systems, the computed radiography Image Plate Detector System is most frequently being used for the general radiography and also this system commonly diffracts the x-ray images since it is the system that is influenced by the light diffusion from the fluorescent substances. In this study, by using the X-ray Generator, a comparative analysis has been made between 2 different models of computer radiography image plate investigate each model's resolution and sharpness through the modulation transfer function(MTF) measurement. For the analysis, two image plates for general radiography one Fuji ST-VN model(more than 3years old) and one Fuji ST-VL model(less than 2years old) that are currently being used in "Hospital A" were sampled for the MTF measurement here. As the experimental method for this study, the resolution chart method has been carried out by using X-ray generator. Also all the experimental data were printed out by laser printer and measured by microdensitometer. As the results of the experiment carried out in this study, some differences have been found between the two different IP models and Fuji ST-VL has shown its excellence in both of the resolution and the sharpness fields.

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