• 한국연소학회:학술대회논문집
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• 한국연소학회 2001년도 제22회 KOSCI SYMPOSIUM 논문집
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• pp.31-45
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• 2001

The effect of adding carbon dioxide to methane-air flame was investigated experimentally. Measurements included extinction limits, flame temperature and photographic investigation of flame. A diffusion flame was stabilized between counterflowing streams of methane diluted with carbon dioxide and air diluted with carbon dioxide. Extinction limits and temperature for such flames were measured over a wide parametric range and were compared with those for other flames that fuel or oxidant was diluted with nitrogen or argon. The experimental results indicate that extinction phenomena can be explained by thermal effect and as an amount of carbon dioxide in fuel or oxidant increases, greatly as compared with other flames flame-temperature falls and flame-thickness is reduced.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
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• pp.33-39
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• 2002

Unsteady behaviors of counterflow flame were studied experimentally in opposing jet counterflow burner using diluted methane. To generate the unsteadiness on the flame, the counterflow diffusion flame was perturbed by velocity changes made by the pistons installed on both sides of the air and fuel stream. The velocity changes were measured by Hot wire and Laser Doppler Velocimetry, and the flame behaviors were observed by High speed ICCD and ICCD. In this investigation, the spatial irregularity of the strain rate caused the flame to extinguish from the outside to the axis during the extinction, and we found the following unsteady phenomena. First, the extinction strain rates of unsteady cases are much larger than those of the steady ones. Second, the extinction strain rates become larger as the slope of the change of the strain rate increases. Third, the unsteady extinction strain rates become smaller with the increase of the initial strain rate.

• 한국연소학회지
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• 제4권2호
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• pp.97-108
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• 1999

This numerical study was to investigate the effect of $CO_2$ addition on the structures and NOx formation characteristics in $CH_4$ counterflow diffusion flame. The importance of radiation effect was identified and $CO_2$ addition effect was investigated in terms of thermal and chemical reaction effect. Also the causes of NOx reduction were clarified by separation method of each formation mechanisms. The results were as follows : The radiation effect was intensified by $CO_2$ addition. Thermal effect mainly contributed to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. The reduction of thermal NO was dominant with respect to reduction rate, but that of prompt NO was dominant with respect to total amount.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2011년도 후기공동학술대회 논문집
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• pp.88-89
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• 2011

The study on synthesis of carbon nanomaterials by H2 mixing in counterflow methane diffusion flames has been experimentally conducted. We have also investigated on effect of catalyst and temperature in flame. The counterflow flame was formed by many kind of gas (fuel side using $CH_4-H_2-N_2$ and oxidizer side $N_2-O_2$) and nitrogen shields discharge on each other side to cut off oxidizer of the atmosphere. Ferrocene was used as a metal catalyst for CNTs synthesis. substrate was used to deposit carbon nanomaterials and these were analyzed by FE-SEM. We could find that carbon nanotubes and many kind of carbon nano materials were formed in Cu wire substrate, through this experiment.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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• pp.267-268
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• 2012

Soot formation and oxidation characteristics of air-diluted propane diffusion flames have been experimentally investigated under the elevated pressure conditions. PAH concentrations showed more pressure sensitive behavior comparing to soot volume fractions. The flame/soot temperatures in soot oxidation region were obtained using the MOLLIP technique. Under the complete soot oxidation environment, the flame/soot temperature is increased with pressure. The increased temperature could accelerate the soot oxidation process and then exothermic oxidation reaction, in turn, could further raise the flame/soot temperature, which would result in the enhancement of soot oxidation process.

• 한국안전학회지
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• 제25권6호
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• pp.9-13
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• 2010

An experimental study for characteristics of soot were conducted at the post-flame region in jet diffusion flames, where carbon dioxide was used as additives in oxidizer stream. Light-extinction method was performed using He-Ne laser with wave length at 632.8nm for the measurement of relative soot density and soot volume fraction with dimensionless extinction coefficient, $K_e$ and mass specific extinction coefficient, ${\sigma}_s$. To increase of resolution, laser light was modified for sheet-form using concave, convex lenses and slit. C/H ratio was introduced for quantitative analysis of soot growth which is expressed by carbonization and dehydrogen. Also transmission electron microscopy(TEM) was used for observation of morphological shape. The results show that the relative soot density in the post-flame region was lower when carbon dioxide was added in oxidizer stream because of reduction of flame temperature.

• 대한기계학회논문집B
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• 제34권5호
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• pp.505-513
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• 2010

삼지화염 구조는 화염 선단의 구조로서 다루어져 왔으며, 많은 연구자들에 의해 해석적인 방법과 실험적인 방법으로 연구가 되어왔다. 그러나 연료의 종류에 따른 가연한계의 차이가 삼지화염의 구조에 미치는 영향에 대한 연구는 깊이 있게 다루어지지 않았다. 본 연구에서는 화염 구조에 대한 비대칭 가연한계의 영향을 예혼합화염과 확산화염에 관한 몇 가지 층류화염 이론에 근거한 간단한 수치 기법을 통해 연구하였다. 고정된 유동장이 사용되었으며, 예혼합 화염 가지에서의 경계조건이 연계되었다. 예혼합 화염 후류의 확산화염의 형성과 소멸을 성공적으로 모사할 수 있었다. 비대칭 가연한계 조건과 열손실에 따른 확산화염의 변화가 연구되었다. 본 연구는 화염의 기초 구조에 대한 이해를 도울 수 있으며, 이후의 연구를 위한 기초로 활용될 수 있을 것이다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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• pp.85-90
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• 2004

We have presented characteristics of a transitional behavior from a premixed flame to a triple flame in a lifted flame according to the change of equivalence ratio. The experimental apparatus consisted of a slot burner and a contraction nozzle for a lifted flame. As concentration difference of the both side of slot burner increases, the shape of flame changed from a premixed flame to a triple flame, and the liftoff height is decreased to the minimum value and then increase again. Around this minimum point, it is confirmed a transition regime from premixed flame to triple flame. Consequently, the experimental results of the liftoff height, flame curvature and luminescence intensity showed that the stabilized laminar lifted flame regime is categorized by regimes of premixed flame, triple flame and critical flame. In the visualization experiment of smoke wire, the flow divergence and redirection reappeared in premixed flame as well as triple flame. Thus we cannot express the flame front of lifted flame has a behavior of triple flame with only flow divergence and redirection. To differentiate triple flame and premixed flame, ${\Phi}$ value of partially premixed fraction is employed. The partially premixed fraction ${\Phi}$ was constant in premixed flame. In critical flame small gradient appears over the whole regime. In triple flame, typical diffusion flame shape is obtained as parabolic distribution type due to diffusion flame trailing.

• Journal of Advanced Marine Engineering and Technology
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• 제32권5호
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• pp.737-746
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• 2008

Numerical study is conducted to grasp preferential diffusion effects on flame characteristics in $H_2/CO$ syn-gas diffusion flames diluted with $CO_2$. The models of Sun et al. and David et al., which have been well known to be best-fitted for $H_2/CO$ synthetic mixture flames. are evaluated for $H_2/CO$ synthetic mixture flames diluted with $CO_2$. Comparison of flame structures with mixture-averaged species diffusion and suppression of the diffusivities of $H_2$ and H was made. The behaviors of maximum flame temperatures with those species diffusion models are not explained by scalar dissipation rate but by the nature of chemical kinetics. Importantly-contributing reaction steps to heat release rate are also compared for the three species diffusion models in $H_2/CO/CO_2$ flames with and without $CO_2$ dilution.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.137-142
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• 2003

In order to investigate the effect of fuel mixing on PAH and soot formation, four species of methane, ethane, propane and propene have been mixed in counterlfow ethylene diffusion flame. Laser-induced incandescene and laser-induced fluorescene techniques were employed to measure soot volume fraction and polycyclic aromatic hydrocarbon (PAH) concentration, respectively. Results showed that the mixing of ethane (or propane) in ethylene diffusion flame produces more PAHs and soot than those of propene, even though the propene diffusion flame produces more PAHs and soot than that of propane and ethane. Considering that propene directly dehydrogenates to propargyl radical, this behavior implied that the enhancement of PAH and soot formation by the fuel mixing of ethylene and ethane (or propane) cannot be explained by propargyl radical directly dehydrogenated from ethane (or propane).