• Title/Summary/Keyword: Diffusion Acceleration

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Corrosion Properties of Reinforced Concrete with Types of Surface Cover and Covering Depth under the Combined Deterioration Environments (복합열화 환경하에서 표면피복종류 및 피복두께에 따른 철근콘크리트의 부식특성)

  • Kim, Moo-Han;Kwon, Young-Jin;Kim, Young-Ro;Kim, Jae-Hwan;Jang, Jong-Ho;Cho, Bong-Suk
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.1
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    • pp.119-126
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    • 2004
  • Generally, reinforced concrete is one of the most commonly used structural materials and it prevents corrosion of steel bar by high pH of interior, But, as time elapsed, reinforced concrete structure become deteriorated by many of combined deterioration factors and environmental conditions. And, there are large number of deteriorate mechanism of the reinforced concrete structure and it acts complexly. It is recognized that steel bar corrosion is the main distress behind the present concern regarding concrete durability. In this study, to institute combined deterioration environments, established acceleration condition and cycle for combined deterioration environments has a resemblance to environments which are real structures placed. After that to confirm corrosion properties of reinforced concrete due to permeability with covering depth and types of surface cover under combined deterioration environments, measured carbonation velocity coefficients, chloride ion diffusion coefficients, water absorption coefficients, air permeability coefficients and electric potential, corrosion area ratio, weight reduction, corrosion velocity of steel bar. The results showed that an increase in age also decrease carbonation velocity coefficients, increase Chloride ion diffusion coefficients and increases water absorption coefficients. As well, an increase in age also increases corrosion of steel bar. Data on the development of corrosion velocity of steel bar with types of surface cover made with none, organic B, organic A, inorganic B, and inorganic A is shown. As well, permeability and corrosion velocity of steel bar with covering depth is superior to 10mm than 20mm. And it is confirmed permeability and corrosion properties of steel bar are closely related.

Development of Chloride Penetration Analysis Program Considering Environmental Conditions (환경조건을 고려한 염소이온 침투해석 프로그램 개발)

  • Kim, Ki Hyun;Jang, Seung Yup;Cha, Soo Won;Chang, Sung Pil
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5A
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    • pp.709-718
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    • 2008
  • Developed is a chloride penetration analysis program in which changes of environmental conditions such as temperature, humidity and external chloride concentration, and the diffusion, convection and binding of chlorides are considered. In order to consider the changes of environmental conditions, analyses for temperature and moisture distribution are implemented simultaneously, and variation of diffusion coefficients due to temperature, humidity and age is also considered. By comparing the calculated total chloride contents with some experimental data, it has been confirmed that the proposed analysis program can trace measured chloride distribution well. Also, through some example analyses, the mechanism of accumulation of chlorides at near surface and acceleration of corrosion of steel reinforcement in case that the moisture distribution changes according to repeated drying and wetting cycles have been verified.

Application of Diffusion Models to Anomalous Sorption in Fluoropolymer-aromatic Solvent Systems (불소고분자-방향족 용매계의 비이상적 흡수에 대한 확산 모델식의 적용)

  • 이상화
    • Membrane Journal
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    • v.10 no.3
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    • pp.139-147
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    • 2000
  • Non-Fickian (or anomalous) diffusion was observed in transient sorption of aromatic solvents(such as benzene, toluene, and chlorobenzene) in fluoropolymers (such as ETFE, ECTFE and PVDF). In this study, five other transient sorption models (Crank, Long & Richman, Berens & Hopfenberg, Neogi, Li) based on Fick's law were employed to fit the anomalous sorption data for aromatic solvents. The adjustable parameters were determined by least square analysis of the measured and predicted fractional uptake. For ETFE sorption data slightly deviating from Fickian behavior, all the models exhibited satisfactory results in fitting the anomalous sorption data. In particular, Neogj model predicted intrinsic diffusivity (0.4~0.8$\times$10$^{-5}$ $\textrm{cm}^2$/day) and equilibrium diffusivity (0.13~0.31$\times$10$^{-4}$ $\textrm{cm}^2$/day) as well as relaxation kinetics related to non-Fickain diffusion. For a typical sigmoidal sorption behavior in PVDF, only Crank's model could give the reasonable evaluation on transport properties. The ratio of intial diffusivity (D$_{i}$) to final equilibrium diffusivity (D$_{\infty}$) was ranged from 80 to 200. For the final stage of uptake In ECTFE with drastic acceleration, all the models exhibited significant deviations from the sorption data. New diffusion models based on thermodynamics and continuum mechanics should be employed to get valuable information on transport properties as well as relaxation kinetics coupled with non-Fickian diffusion.

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5G Mobile Traffic Forecast (5G 모바일 트래픽 전망)

  • Jahng, J.H.;Park, S.K.
    • Electronics and Telecommunications Trends
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    • v.35 no.6
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    • pp.129-136
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    • 2020
  • Korea launched the world's first commercial 5G services in April 2019. Mobile traffic is expected to increase further with the acceleration of mobile-centric data utilization. It is one of the most important indexes of the growth of the mobile communications market, and it has a close relationship with frequency demand and supply, network management, and information communication policy. To overcome the limitations of an analytical solution due to the high complexity of the real world, this paper estimates the diffusion of 5G users using systemic thinking and the behavior of individual agents. Based on these demand forecasts, contributions to the establishment of strategic policies are suggested. For better understanding, global 5G predictions of subscribers and mobile traffic are also compared.

Effects of Sintering Atmosphere and Dopant Addition on the Densifcation of $SnO_2$ Ceramics (첨가제와 소결분위기가 $SnO_2$ 요업체의 치밀화에 미치는 영향)

  • 정재일;김봉철;장세홍;김정주
    • Journal of the Korean Ceramic Society
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    • v.34 no.12
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    • pp.1221-1226
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    • 1997
  • The effects of sintering atmosphere and dopant addition on the behavior of densification and grain growth of SnO2 ceramics were investigated with consideration of defect chemistry. CoO and Nb2O5 were chosen as dopants, and oxygen and nitrogen were used for controlling of sintering atmospheres. With the decrease of oxygen partial pressure, densification was depressed due to evaporation of SnO2 ceramics. In the case of SnO2 sintering, the addition of CoO, which produced oxygen vacancy in SnO2 ceramics, led to acceleration of densification and grain growth. On the contrary, when Nb2O5 as a dopant producing Sn vacancy was added to SnO2 ceramics, densification and grain growth were simultaneously retarded. As results, it was conformed that diffusion of oxygen ions was rate determinant in densification and grain growth of SnO2 ceramics.

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Fabrication of transition metal doped sapphire single crystal by high temperature and pressure acceleration method

  • Park, Eui-Seok;Jung, Choong-Ho;Kim, Moo-Kyung;Kim, Yoo-taek;Hong, Jung-Yoo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.77-79
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    • 1998
  • Metallic chromium was diffused in the{0001},{1120} white sapphires which were grown by the Verneuil method to enhance the physical properties of the sapphires. Chromium metal vapour pressure and {{{{ { N}_{2 } }}}} pressure were kept by {{{{ { 1$\times$10}^{-4 } }}}} torr at 21 50 $^{\circ}C$ and 6 atm in the quartz-tube, respectively. The color do the Cr-doped sapphires was changed to light red. Chromium was diffused faster in the {1120} than 수 the {0001} plane. It was speculated that the planar density was one the factors determining diffusion coeffcient

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Experimental and Numerical Study on Characteristics of Air-assisted Spray and Spray Flames (2유체 분무의 연소특성에 관한 실험 및 수치 해석적 연구)

  • Kim, Dong-Il;Oh, Sang-Huen
    • Journal of the Korean Society of Combustion
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    • v.3 no.2
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    • pp.51-63
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    • 1998
  • Air-assisted atomizer flames are investigated numerically to study spray structures in nonburning and burning conditions based on experimental data. A PDA is used to measure droplet size, velocity, and number density for both nonburning and burning spray. Computations utilize time-averaged gas-phase equations and $k-{\varepsilon}$ turbulence model for simplicity. The major features of the liquid-phase model are that a SSF approach is used to represent the effect of gas-phase turbulence on droplet trajectories and vaporization, an infinite-diffusion model is employed to represent the transient liquid-phase process. Computation and experiment results show that the droplet acceleration and evaporation proceed quickly in near the atomizer, characterizing high number densities and a strong convective effect. The primary combustion zone, however, is dorminated by the gas phase reaction and exhibits a sheath combustion.

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Reliability Assessment and Improvement of MEMS Vacuum Package with Accelerated Degradation Test (ADT) (가속열화시험을 적용한 MEMS 진공패키지의 신뢰성 분석 및 개선)

  • 최민석;김운배;정병길;좌성훈;송기무
    • Journal of Applied Reliability
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    • v.3 no.2
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    • pp.103-116
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    • 2003
  • We carry out reliability tests and investigate the failure mechanisms. of the wafer level vacuum packaged MEMS gyroscope sensor using an accelerated degradation test. The accelerated degradation test (ADT) is used to evaluate reliability (and/or life) of the MEMS vacuum package and to select the accelerated test conditions, which reduce the reliability testing time. Using the failure distribution model and stress-life model, we are able to estimate the average life time of the vacuum package, which is well agreed with the measured data. After improving several package reliability issues such as prevention of gas diffusion through package, we carry out another set of accelerated tests at the chosen acceleration level. The results show that reliability of the vacuum packaged gyroscope has been greatly improved and can survive without degradation of performance, which is the Q-factor in gyroscope sensor, during environmental stress reliability tests.

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Seasonal and Spatial Variations of Nutrient Fluxes in the Intertidal Flat of Keunso Bay, the Yellow Sea (서해 근소만 갯벌에서 영양염 플럭스의 계절 변화)

  • Kim, Kyung-Hee;Kim, Dong-Seon
    • Ocean and Polar Research
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    • v.30 no.3
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    • pp.225-238
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    • 2008
  • In order to investigate the effects of intertidal sediments on the nutrient cycle in coastal environments, the benthic fluxes of ammonium, nitrate, nitrite, phosphate, and silicate at two stations on the intertidal flat of Keunso Bay were determined during each season. The efflux of ammonium was observed at S1 and resulted from the diffusion of remineralized ammonium and acceleration caused by the bioirrigation of macrofauna. The influx of ammonium at S2 was probably due to nitrification in the water column. The influx of nitrate was observed at both stations during all seasons, indicating that the nitrate in the pore water was removed by denitrification. Vigorous bioirrigation led to the efflux of dissolved inorganic nitrogen (DIN) at S1, whereas the influx of DIN at S2 was predominantly caused by denitrification. Contrary to the diffusive and bio-irrigated release of remineralized phosphate from the sediment at S1, the influx of phosphate was observed at S2, which may be attributable to adsorption onto iron oxides in the aerobic sediment layer. Silicate, which is produced by the dissolution of siliceous material, was mostly released from the sediment by molecular diffusion and bioirrigation. However, the influx of silicate was observed at S2 during spring and winter, which was ascribed to adsorption by particulate matter or assimilation by benthic microphytes. The annual fluxes of DIN were 328 mmol $m^{-2}yr^{-1}$ at S1 and -435 mmol $m^{-2}yr^{-1}$ at S2. The annual fluxes of phosphate were negative at both sites (-2.8 mmol $m^{-2}yr^{-1}$ at S1 and -28.9 mmol $m^{-2}yr^{-1}$ at S2), whereas the annual fluxes of silicate were positive at both sites (843 mmol $m^{-2}yr^{-1}$ at S1 and 243 mmol $m^{-2}yr^{-1}$ at S2).

Effect of accelerational perturbations on physical vapor transport crystal growth under microgravity environments

  • Choi, Jeong-Gil;Lee, Kyong-Hwan;Kwon, Moo-Hyun;Kim, Geug-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.5
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    • pp.203-209
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    • 2006
  • For $P_B=50,\;{\Delta}T=10K$, Ar=5, Pr=2.36, Le=0.015, Pe=1.26, Cv=1.11, the intensity of solutal convection (solutal Grashof number $Grs=3.44x10^4$) is greater than that of thermal convection (thermal Grashof number $Grt=1.81x10^3$) by one order of magnitude, which is based on the solutally buoyancy-driven convection due to the disparity in the molecular weights of the component A($Hg_2Cl_2$) and B(He). With increasing the partial pressure of component B from 10 up to 200 Torr, the rate is decreased exponentially. The convective transport decreases with lower g level and is changed to the diffusive mode at 0.1 $g_0$. In other words, for regions in which the g level is 0.1 $g_0$ or less, the diffusion-driven convection results in a parabolic velocity profile and a recirculating cell is not likely to occur. Therefore a gravitational acceleration level of less than 0.1 $g_0$ can be adequate to ensure purely diffusive transport.