• Archives of Pharmacal Research
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• v.11 no.2
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• pp.99-113
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• 1988

Quantitation of ethenzamide, isopropylantipyrine and caffeine takes about 41 hrs by conventional GC method. Quantitation of allylisoprorylacetylurea takes about 40 hrs by conventional UV method. But quantitation of them takes about 6 hrs by DRIFT developing method. Each standard and sample sieved, powdered and acquired DRIFT spectrum. Out of them peak of each component was selected and ratio of each peak to standard peak was acquired, and then linear stepwise multiple regression was performed with these data and concentration. Reflectance value, Kubelka-Munk equation and Inverse-Kubelka-Munk equation were modified by us. Inverse-Kubelka-Munk equation completed the deficit of Kubelka-Munk equation. Correlation coefficients acquired by conventioanl GC and UV against DRIFT were more than 0.95.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1522-1522
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• 2001

Beverages based on fruit juices are among the most popular commercially available drinks. There is an ever-increasing demand for these juices in the market. Orange juice is one of the most common as well as most favorite flavor. The fruit processing industries have a tremendous responsibility of quality control. For quality evaluation estimation of various components of the juice is necessary. Sucrose, glucose, fructose, citric acid and malic acid are the prime components of orange juice. Little information is available on analysis of orange juice. However, conventional and general wet chemistry procedures are currently being used which are no longer desired by the industry owing to the time involved, labor input and harmful chemicals required for each analysis. Need to replace these techniques with new, highly specific and automated sophisticated techniques viz. HPLC and spectroscopy has been realized since long time. Potential of Near Infrared Spectroscopy in quantitative analysis of different components of food samples has also been well established. A rapid, non-destructive and accurate technique based on Near Infrared Spectroscopy for determination of sugars and organic acids in orange juice will be highly useful. The current study is an investigation into the potential of Near Infrared Diffuse Reflectance Spectroscopy for rapid quantitative analysis of sucrose, glucose, fructose citric acid and malic acid in orange juice. All the Near Infrared measurements were peformed on a dispersive NIR spectrophotometer (ELICO 153) in diffuse reflectance mode. The spectral region from 1100 to 2500nm has been explored. The calibration has been performed on synthetic samples that are mixtures of sucrose, glucose, fructose, citric acid and malic acid in different concentration ranges typically encountered real orange juice. These synthetic samples are therefore considered to be representatives of natural juices. All the Near Infrared spectra of synthetic samples were subjected to mathematical analysis using Partial Least Square (PLS) algorithm. After the validation, calibration was applied to commercially available real samples and freshly squeezed natural juice samples. The actual concentrations were compared with those predicted from calibration curve. A good correlation is obtained between actual and predicted values as indicated by correlation coefficient ($R^2$) value, which is close to unity, showing the feasibility of the technique.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1132-1132
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• 2001

This work is a further development of the method created by G. Krivoshiev in 1996 for elimination of peel interference and prediction of fruit flesh optical density. In this investigation, as it was earlier, the objects are observed as being structured by three successive layer “AlongrightarrowOlongrightarrowB” denoting “peel-flesh-peel”. In the first version of the method the transmittances of the surface layers A and B were measured according to Kubelka-Munk theory by means of their diffuse reflectance. At that the overall transmittance T was approximated in the form of a multiplication approximation being valid for plane-parallel layers of a non-scattering material. In this work this approximation was done away with applying the theory of discontinuum, respectively Benfor's equations. As a result two mathematical models were created for non-destructive prediction of fruit flesh optical density. These models are different from the ones based solely on Kubelka-Munk theory, the destruction being marked by the terms 1n (1 - $R_{A}R_{0}$) and 1n (1 - $R_{A}R_{B}$), where: $R_{A}$ and $R_{B}$ are reflectance values for the surface layers A and B; $R_{0}$ is the average reflectance of the internal layer that could be obtained empirically by means of a preliminary measurement of sufficiently large number of physically peeled fruits of a given species and variety.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1998.06a
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• pp.45-48
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• 1998

For the single crystal growth of silicon, a global analysis of heat transfer in a CZ furnace was carried out using the finite element method, where the radiative heat transfer between the surfaces that possess both specular and/or diffuse reflectance components was taken into account, and then the effect of the specular reflection of the crystal and/or melt on the CZ crystal growth was numerically investigated.

• Journal of Biosystems Engineering
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• v.36 no.1
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• pp.33-39
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• 2011

An optical sensing approach based on diffuse reflectance has shown potential for rapid and reliable on-site estimation of soil properties. Important sensing ranges and the resulting regression models useful for soil property estimation have been reported. In this study, a similar approach was applied to investigate the potential of reflectance sensing in estimating soil properties for Korean paddy fields. Soil cores up to a 65-cm depth were collected from 42 paddy fields representing 14 distinct soil series that account for 74% of the total Korean paddy field area. These were analyzed in the laboratory for several important physical and chemical properties. Using air-dried, sieved soil samples, reflectance data were obtained from 350 to 2500 nm on a 3 nm sampling interval with a laboratory spectrometer. Calibrations were developed using partial least squares (PLS) regression, and wavelength bands important for estimating the measured soil properties were identified. PLS regression provided good estimations of Mg ($R^2$ = 0.80), Ca ($R^2$ = 0.77), and total C ($R^2$ = 0.92); fair estimations of pH, EC, $P_2O_5$, K, Na, sand, silt, and clay ($R^2$ = 0.59 to 0.72); and poor estimation of total N. Many wavelengths selected for estimation of the soil properties were identical or similar for multiple soil properties. More important wavelengths were selected in the visible-short NIR range (350-1000 nm) and the long NIR range (1800-2500 nm) than in the intermediate NIR range (1000-1800 nm). These results will be useful for design and application of in-situ close range sensors for paddy field soil properties.

• Journal of the Korean Association of Geographic Information Studies
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• v.19 no.2
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• pp.107-116
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• 2016

Airborne or spaceborne remote sensing can increase the efficiency of seabed material surveys compared with field surveying using a vessel. For the same seabed material, the optical remote sensing image shows variation in the reflectance depending on the water depth, which is due to the absorption and scattering by the water column. This study suggests a correction procedure to use the hyperspectral image for seabed material analysis. The study is conducted in the coastal area from Sacheonjin Port to Gyungpo Beach in Gangwon-do. The hyperspectral image is acquired using the CASI-1500 sensor. The diffuse attenuation coefficient is estimated for each band through regression models between the water reflectance and depth. Then, the coefficient is applied to each band of the image. As a result, the completely corrected image can be interpreted for a deeper area, although the interpretable area is very shallow without water column correction. Additionally, the water column corrected image shows decreased variation of reflectance with various water depths.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.84-84
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• 2007

• Bulletin of the Korean Chemical Society
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• v.14 no.2
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• pp.179-183
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• 1993

Template condensation of ${\alpha}$-diketones such as 2,3-butanedione or benzil with diaminoalkanes such as 1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,6-diaminohexane, 1,8-diaminooctane or 1,12-diaminododecane in the presence of Cr(III) results in the formation of complexes of the type $[CrI,X_2]X$ (where L = tetraazamacrocycle having 12 to 32-membered ring and $X={NO_3}^- or Cl^-).$ The complexes have been characterized by elemental analyses, magnetic measurements and IR and diffuse reflectance spectra.

• Proceedings of the PSK Conference
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• 2003.04a
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• pp.290.2-290.2
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• 2003

Skin Moisture is an important factor in skin health. Measurement of moisture content can provide diagnostic information on the condition of skin. In this study, a photo diode array type near infrared spectroscopy was used to determine skin moisture. Diffuse reflectance spectra were collected and transformed to absorbance using 1-nm stepsize over the wavelength range of 1100 nm to 2200 nm. (omitted)

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.486-492
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• 2020

The method for preparing a perovskite-type bismuth ferrite (BFO) photocatalyst which reacts to visible LED light and the characteristics of visible light photocatalysis were investigated. BFO was prepared according to the sol-gel method. The prepared BFO consisted mainly of BiFeO₃ structure and formed a nano-sized crystal including Bi₂₄Fe₂O₃₉ structure. The BFO nano crystallines were identified from the UV-visible diffuse reflectance spectra to absorb UV and visible light up to about 600 nm. The bandgap of the BFO determined from the diffuse reflectance spectrum was about 2.2 eV. Formaldehyde was decomposed by the photoreaction of BFO photocatalysts with the visible light LED lamps with wavelengths of 585 nm and 613 nm. The narrow bandgap of BFO led to elicit BFO photocatalytic activity in visible LED light.