• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.374.2-374.2
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• 2016

Volatile organic compounds (VOCs) in the atmosphere are harmful materials which influence indoor air environment and human health. Titanium dioxide ($TiO_2$) is photocatalyst extensively used in degradation of organic compound. To improve the photocatalytic activity in the visible light region, doping with non-metals element or loading noble metals on the surface of $TiO_2$ is generally proposed. In this study, N- doped $TiO_2$ having photocatalytic activity in visible light region was attached noble metal such as Pt, Ag, Pd, Au by coupling method. Catalytic activities of Noble metal coupled $N-TiO_2$ powders were evaluated by the improvement of their photocatalytic activities and the degradation of VOC gas. A UV-Vis spectrophotometer was used to measure the diffuse reflectance spectra of coupled $N-TiO_2$ sample. The photocatlytic activities of as prepared samples were characterized by the decoloration of aqueous MB solution under Xenon light source (UV and visible light). To measure of decomposition VOCs, ethylbenzene was selected for target VOC material and the concentration was monitored under UVLED irradiation in a closed chamber system. Adjusting the initial concentration of 10~12 ppm, to evaluate the removal characteristics by using the coupled $N-TiO_2$.

• 천문학논총
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• 제32권1호
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• pp.105-107
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• 2017

We present results of AKARI/IRC near-infrared (NIR) slit-spectroscopy ($2.5-5.0{\mu}m$, R ~ 100) of Galactic sources, focusing on ice absorption features. We investigate the abundance of $H_2O$ and $CO_2$ ices and other ice species (CO and XCN ices) along lines of sight towards Galactic H $\small{II}$ regions, massive YSOs, and infrared diffuse sources. Even among those different kinds of astronomical objects, the abundance ratio of $CO_2$ to $H_2O$ ices does not vary significantly, suggesting that the pathway to $CO_2$ ice formation driven by UV irradiation is not effective at least among the present targets.

• Bulletin of the Korean Chemical Society
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• 제35권8호
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• pp.2512-2518
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• 2014

The praseodymium-doped $TiO_2$ photocatalyst samples, which could degrade methyl orange under UV irradiation, were prepared by sol-microwave method for improving the photocatalytic activity of $TiO_2$. The resulting materials were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Raman spectra, Fourier transform infrared spectra (FTIR) and Ultraviolet-visible diffuse reflectance spectra (UV-vis DRS). It was found Pr doping retarded the growth of crystalline size and the phase transformation from anatase to rutile, and narrowed the band gap energy. Praseodymium doping brought about remarkable improvement in the photoactivity. The optimal dopant amount of Pr was 2% by molar of cement and the calcination temperature was $500^{\circ}C$ for the best photocatalytic activity. The improvement of photocatalytic activity was ascribed to the occurrence of lattice distortion and the effective containment of the recombination of the electron-hole by $Pr^{3+}$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.54-55
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• 2010

Vacancy defects in graphene can be created by electron or ion irradiation and those induce ripples which can change the electronic properties of graphene. Recently, the formation of defect structures such as vacancy defects and non-hexagonal rings has been reported in the high resolution transmission electron microscope (HR-TEM) of reduced graphene oxide [1]. In those HR-TEM images, it is noticed that the dislocations with pentagon-heptagon (5-7) pairs are formed and diffuses. Interestingly, it is also observed that two 5-7 pairs are separated and diffuse far away from each other. The separation of 5-7 pairs has been known to be due to their self-diffusion. However, from our tight-binding molecular dynamics simulation, it is found that the separation of 5-7 pairs is due to the diffusion of single vacancy defects and coalescence with 5-7 pairs. The diffusion and coalescence of single vacancy defects is too fast to be observed even in HR-TEM. We also implemented Van der Waals interaction in our tight-binding carbon model to describe correctly bi-layer and multi-layer graphene. The compressibility of graphite along c-axis in our tight-binding calculation is found to be in excellent agreement with experiment. We also discuss the difference between single layer and bi-layer graphene about vacancy diffusion and reconstruction.

• 한국분말재료학회지
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• 제22권6호
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• pp.432-437
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• 2015

The en-riched $^{58}Ni$ powders are dissolved in acid solution and coated on a Cu target for proton irradiation at cyclotron to produce $^{57}Co$ radioisotope. The condition of the plating bath and the coating process are determined using the en-riched powders. To establish the coating conditions for $^{57}Co$, non-radioactive Co ions are dissolved in an acid solution and electroplated on to a rhodium plate. The thermal diffusion of electroplated Co into a rhodium matrix was studied to apply a $^{57}Co$ Mssbauer source. The diffusion depth from surface to matrix of Co is depended on the annealing temperature and time. The deposited Co atoms diffuse completely into a rhodium (Rh) matrix without substantial loss at an annealing temperature of 1200 for 4 hours.

• 한국세라믹학회지
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• 제50권6호
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• pp.504-509
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• 2013

In this study, ZnSe-$TiO_2$ composites were synthesized by a facile hydrothermal-assisted sol-gel process and characterized by nitrogen adsorption isotherms (77 K), X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM) and UV-vis diffuse reflectance spectrophotometry. The photocatalytic activity was investigated by decoloration methylene blue (MB), methyl orange (MO), and rhodamine B (Rh.B) in an aqueous solution under visible light irradiation. The results revealed that the photocatalytic activity of the ZnSe-$TiO_2$ photocatalyst was much higher than that of pure$TiO_2$. The ZnSe nanoparticles, which act as a photosensitizer, not only extend the spectral response of $TiO_2$ to the visible region but also reduce charge recombinations.

• 한국입자에어로졸학회지
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• 제6권1호
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• pp.29-35
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• 2010

Transition metals such as V, Fe, and Ni were used to synthesize doped zinc oxide nanoparticles from mixed liquid precursors by using the flame spray pyrolysis (FSP). The effects of dopants on the powder properties such as morphology, specific surface area, crystal structure, and light adsorption were analyzed by TEM, BET, XRD, and UV-Vis diffuse reflection spectrum (DRS), respectively. The results showed that hexagonal wurtzite structured ZnO:M (M = V, Fe, Ni) nanoparticles were successfully synthesized by the FSP. The transition metal-doping resulted in the decrease in its particle size and crystallite size. The UV-vis absorption spectra of ZnO:M nanoparticles were also red-shifted. ZnO:V showed the highest MB degradation of 99.4% under the UV irradiation after 3 hrs.

• 한국군사과학기술학회지
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• 제17권2호
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• pp.197-203
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• 2014

In this paper, the effect of unsteady radiation on the horizontal fin of an external fuel tank by flame of a flying flare was analysed to see the temperature increase of the fin and the thermal impact on the fin. Radiation between two surfaces was calculated using the concept of radiation resistance of surface and space including radiation, irradiation and shape factor for two flying trajectories of a flare, maximum temperature of 2200 K, emissivity of 0.95, flying velocity of 30 m/s, and thermal surface area of $0.01m^2$. The result shows that the temperature increase of the fin is 0.236 K, and the thermal effect on the fin is ignorable. And it was found that temperature is increased a little because small amount of heat energy can be radiated due to the short exposure time to the heat source.

• 대한화학회지
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• 제67권1호
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• pp.33-41
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• 2023

Nanocrystallne WO₃ and MoO₃ with several different sizes and crystal structures were prepared by simple acid precipitation and subsequent heat treatment. The photochromic (PC) properties of these samples were comparatively investigated in powder state by monitoring diffuse reflectance spectral changes after bandgap irradiation. The PC effect of hexagonal WO₃ and monoclinic WO₃ strongly depended upon crystallite size rather than crystal structure. The smaller the crystallite size, the better the PC effect. However, orthorhombic WO·H₂O and MoO₃ having hexagonal and orthorhombic structures did not follow this trend. One consistent result for all WO₃ and MoO₃ samples is that the heat treatment in air, which changes crystallinity, whether it changes the crystal structure or only the crystallite size, reduces the PC effect. Since the thermal treatment reduces the surface oxygen defect sites, we believe that the PC effect of WO₃ and MoO₃ depends critically on the surface oxygen defect sites that serve as deep trap sites for photogenerated electrons and oxygen radical holes. We also found that the proton insertion claimed by double charge injection model is not critical for the PC effect.

• 한국농림기상학회지
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• 제21권4호
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• pp.358-365
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• 2019

영농형 태양광 발전은 기존 농지에 태양광 패널을 설치하여 농지 보존과 일정 수확량 유지를 전제로 전기 생산도 병행하는 시스템이다. 최근 태양광 부지 수요 충족 및 농촌 경쟁력 제고를 위한 방안으로 주목 받고 있다. 따라서, 본격적인 개발에 앞서 영농형 태양광 패널 하부에서의 경작지 차광 정도를 분석하는 것이 작물 생육·수확량 변동 예측에 반드시 필요할 것이다. 본 실험은 연구용 영농형 태양광 건설에 앞서, 영농형 태양광 시설 규격과 유사한 모의 차광 시설을 설치하고 하부의 광합성유효복사량 특성을 분석하였다. 차광막 하부와 외부의 광합성유효복사량 차이는 일사광에서 산란광 비율이 낮아질수록 증가하였는데, 최대 17.08 mol/㎡/day (맑은 날), 최소 3.03 mol/㎡/day (흐린 날)이었다. 이러한 광 조건 변화는 벼의 초기 생육에 있어 초장의 증가와 주당경수의 감소를 가져왔다.