• Journal of Korean Society for Atmospheric Environment
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• v.15 no.3
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• pp.249-255
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• 1999

We sdudied effect of additives on catalytic activity in thermal catalytic de-NOx process which was composed of thermal reduction, catalytic reduction and catalytic oxidation stage. Pd-Pt/${\gamma}$-$Al_2O_3$ catalysts with the addition of transition metals(Co, Cu, Fe, Ni, W, Zn, Zr) and rare earth metals(Ce, Sr) were prepared by the conventional washcoating method. Those catalysts were characterized by CO pulse chemisorption, ICP, $N_2$ adsorption, SEM and XRD. The effect of catalyst additives on NOx removal for diesel emission was studied in thermal catalytic de-NOx process at reduction temperature(350~50$0^{\circ}C$), space velocity(5,000~20,000 $hr^{-1}$) and the engine load(0~120kW). The concentraton of CO, $CO_2$, NO and $NO_2$ in the exhaust gas increased with the engine load. On the other hand the concentration of $O_2$ decreased. The de-NOx activityof all prepared catalysts increased with respect to high CO and low $O_2$ level in the thermal reduction stage of the process. Insertion of Ce to Pt-Pd/${\gamma}$-$Al_2O_3$ catalyst showed the best activity of all the catalysts under these experimental conditions. De-NOx catalysts are effective to remove CO in addition to NOx in the catalytic reduction stage.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.7-12
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• 2003

The purpose of this work is to investigate the effect of premixing condition on the combustion and exhaust emission characteristics in a HCCI diesel engine. To form homogeneous charge before intake manifold, the premixed fuel is injected into premixed tank by GDI injection system and the premixed fuel is ignited by direct injected diesel fuel. But in the case of high intake air temperature, premixed fuel is auto-ignited before diesel combustion and soot emission is increased. In the case of light load condition, the BSFC is improved by intake air heating because increased air temperature promoted the combustion of premixed mixture. NOx and smoke concentration of exhaust emissions are reduced compared to conventional diesel engine. The combustion characteristics of the HCCI diesel engine such as combustion pressure, rate of heat release, and exhaust emission characteristics are discussed.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.1
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• pp.79-86
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• 2003

In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated fur direct injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenated blended fuel which has seven kinds of mixed ratio. And, the effects of exhaust gas recirculation(EGR) on the characteristics of NOx emission have been investigated. Ethylene glycol mono-n-butyl ether(EGBE) contains oxygen component 27% in itself, and it is a kind of effective oxygenated fuel of mono-ether group that the smoke emission and unburned hydrocarbons of EGBE is reduced remarkably compared with commercial diesel fuel, that is, it can supply oxygen component sufficiently at higher loads and speeds in diesel engine. It was found that simultaneous reduction of smoke and NOx was achieved with oxygenated fuel and cooled EGR method.

• Journal of Power System Engineering
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• v.21 no.6
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• pp.68-78
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• 2017

Major countries have tighten their NOx regulation of diesel passenger cars. In the case of the EU, the regulation has been toughen up to 6.25 times since 2000. Despite the regulation the NOx concentration of the ambient has not been reduced proportionally. Futhermore, some manufacturers were disclosed using a defeat device for meeting the regulation illegally. As these issues, to reduce NOx emission practically, Korea and the EU introduced the real-world driving emission(RDE) regulation and the test method that will be applied after 2017. Also, the US has used the test equipment(PEMS) to detect a defeat device. In this paper, for the regulation to make a soft landing in Korea, 4 diesel passenger cars which met Euro 6a~6b regulation and were equipped with LNT/SCR were tested at a chassis dynamometer with environmental chamber applying the off-cycles(FTP, US06, SC03, HWFET and CADC) and several ambient condition(-7 and $14^{\circ}C$) as well as certification mode(NEDC, WLTC@ $23^{\circ}C$). The result of the test showed that the ambient temp. and the engine load as a test mode impacted the NOx emission of the cars while the vehicles with SCR emitted NOx lower than with LNT. Additionally, to propose an effective RDE test method, the above result was compared with the results of the other papers which tested RDE using the same cars.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.8
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• pp.4729-4735
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• 2014

To protect the environment, the regulation of emissions from off-road engines which are relatively neglected, is being reinforced. This paper deals with the robust design of off-road diesel engines considering the emission characteristics. Measurements of the NOx and PM levels based on the DOE were carried out. The injector hole number, injection timing and EGR rate were selected as the control factors. The orthogonal arrays table $L_9(3^3)$ was made from 2 or 3 levels for each factor and measurements of emissions were accomplished based on the table. The small-the-better SN ratio according to the Taguchi method was evaluated. The ANOVA (analysis of variance) for the SN ratio was conducted. The injection timing on the NOx emissions and the EGR rate on the PM have the largest effect on the low-load operation condition. The confidence levels of the control factors were more than 90%.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.6
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• pp.662-668
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• 2006

The effects of fuel injection nozzle hole on the NOx emission and fuel oil consumption of medium speed diesel engine HYUNDAI HiMSEN 6H21/32 engine are investigated by engine performance simulation. The results of performance simulation are verified by experimental results of NOx omission fuel oil consumption, cylinder pressure, and heat release rate according to the variation of the number of fuel injection nozzle hole and engine load. The performance simulations are also carried out to optimize the fuel injection nozzle of 6H21/32 engine in respect to the NOx emission and fuel oil consumption. The engine performance measurements are performed to verify the results of performance simulation and to investigate the effects of fuel injection nozzle on engine performance. The results of measurement indicate that significant NOx reduction can be achieved with minimum deterioration in fuel oil consumption by optimizing the geometry of fuel injection nozzle on 6H21/32 engine.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.1
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• pp.44-50
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• 2007

Diesel engines have high thermal efficiency, and they have less CO & HC emissions than another engines. while NOx & Soot emissions are very much. compared with exhaust emission standards. However, the limit level is more and more strengthened yearly due to the importance of environmental protection. So, the optimal countermeasures for the reduction of NOx & Soot emissions below limit level are required. Therefore. the author has investigated the effects of emulsified fuel on the characteristics of exhaust emissions. using an four-cycle, four-cylinder and direct injection diesel engine because the using of emulsified fuel among various methods for reducing NOx & Soot emissions is simple in installation low in cost and high in efficiency. The results of investigation according to various operating conditions are as follows : 1) Specific fuel consumption increase maximum 19.8% at low load. but is not affected at full load. 2) In case of emulsion ratio 25%, NOx emission decrease 32% at 75% load. 30% at full load. 3) In case of emulsion ratio 25%, Soot emission decrease 84% at 75% load, 59% at full load.

• International Journal of Automotive Technology
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• v.6 no.1
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• pp.15-21
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• 2005

The purpose of this paper is to experimentally investigate the engine pollutant emissions and combustion characteristics of diesel engine fueled with ethanol-diesel blended fuel (bio-diesohol). The experiments were performed on a single-cylinder DI diesel engine. Two blend fuels were consisted of $15\%$ ethanol, $83.5\%$ diesel and $1.5\%$ solublizer (by volume) were evaluated: one without cetane improver (E15-D) and one with a cetane improver (E15-D+CN improver). The engine performance parameters and emissions including fuel consumption, exhaust temperature, lubricating oil temperature, Bosch smoke number, CO, NOx, and THC were measured, and compared to the baseline diesel fuel. In order to gain insight into the combustion characteristics of bio-diesohol blends, the engine combustion processes for blended fuels and diesel fuel were observed using an Engine Video System (AVL 513). The results showed that the brake specific fuel consumption (BSFC) increased at overall engine operating conditions, but it is worth noting that the brake thermal efficiency (BTE) increased by up to $1-2.3\%$ with two blends when compared to diesel fuel. It is found that the engine fueled with ethanol-diesel blend fuels has higher emissions of THC, lower emissions of CO, NOx, and smoke. And the results also indicated that the cetane improver has positive effects on CO and NOx emissions, but negative effect on THC emission. Based on engine combustion visualization, it is found that ignition delay increased, combustion duration and the luminosity of flame decreased for the diesohol blends. The combustion is improved when the CN improver was added to the blend fuel.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.3
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• pp.88-97
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• 2012

To measure the traffic pollutants with high temporal and spatial resolution under real conditions, a mobile emission laboratory (MEL) was designed. The equipment of the mini-van provides gas phase measurements of CO, NOx, CO2 and THC (Total hydrocarbon), and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and a condensation particle counter (CPC). The inlet sampling port above the bumper enables the chasing of different type of vehicles. This paper introduces the technical details of the MEL and presents data from the experiment in which a MEL chases a city bus fuelled by diesel, DME and Bio-diesel. The dilution ratio was calculated by the ratio of ambient NOx and tail-pipe NOx. Most particles from the bus fuelled by diesel were counted under 300 nm and the peak concentration of the particles was located between 30 and 60 nm. However, most particles in the exhaust of the bus fuelled by DME were nano-particles (diameter: less than 50 nm). The bus fuelled by Bio-diesel shows less particle emissions compare to diesel bus due to the presence of the oxygen in the fuel.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.2
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• pp.137-143
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• 2011

This paper describes the effects of biodiesel blended fuel on the engine combustion and emission characteristics in a four cylinder CRDI(Common-rail direct injection) diesel engine. In this work, the biodiesel-diesel blended fuel(20% of biodiesel and 80% of ULSD(ultra low sulfur diesel) by volume ratio, BD20) and ULSD fuel are used under the various injection pressures and engine speeds. The experimental results of BD20 and ULSD fuel show that NOx emissions were increased and soot emissions were decreased with the increase of injection pressure. In particular, NOx emissions were slightly increased for the BD20 fuel, however, soot emissions were significantly reduced compared to the ULSD fuel. When the engine speed is increased from 1000rpm to 2000rpm, NOx emissions are decreased at all tested conditions, and soot emissions are largely increased at lower injection pressure.