• 제목/요약/키워드: Diastereotopic methylene

검색결과 2건 처리시간 0.016초

NOE 실험의 대용으로 응용될 수 있는 PFG Long-range COSY NMR 실험 (Application of Pulsed Field Gradient Long-range COSY-NMR for the Assignment of Geminal Protons on Rigid System: supplemental method of NOE Experiment)

  • 이석근
    • 분석과학
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    • 제18권1호
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    • pp.85-88
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    • 2005
  • Antiphase character of cross peaks in long-range COSY is modulated by changing the fixed delay time and used to assign diastereotopic methylene protons on rigid systems which could produce unpredictable NOE phenomena because of complicate coupling spins.

Ethyl Octahydro-2,3-dioxo-6a-hydroxy-1-benzyl-cyclopenta[b]pyrrole-3a-carboxylate의 부분입체이성질성 핵자기공명 스펙트럼 (Diastereotopic $^1H-NMR$ Spectrum of Ethyl Octahydro-2,3-dioxo-6a-hydroxy-1-benzyl-cyclopenta[b]pyrrole-3a-carboxylate)

  • 김동우;김태흥;박영규;윤경원;서원준
    • 약학회지
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    • 제39권2호
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    • pp.205-209
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    • 1995
  • Methylene protons of benzyl and ethyl ester in ethyl 1-benzyl-2, 3-dioxo-cyclopenta[b]-pyrrole-3a-carboxylate (A) exhibited opposite$^{1}$H-NMR spectral patterns mutually between magnetic equivalence and nonequivalence depending on concentration and temperature. The diastereotopic spectral data of compound A were reported with brief interpretation.

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