• Title/Summary/Keyword: Diamine

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Highly Efficient Blue Organic Light-emitting Devices Based on Copper Phthalocyanine/Aromatic Diamine Composite Hole Transport Layer

  • Liao, Chi Hung;Tsai, Chih Hung;Chen, Chin H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.724-726
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    • 2004
  • Highly efficient blue organic light-emitting devices (OLEDs) utilizing the idea of copper phthalocyanine (CuPc)/N,N'-bis-(1-naphthyl)-N,N'-diphenyl,1,1'-biphenyl- 4,4'-diamine (NPB) composite hole transport layer (CPHTL) have been fabricated. The effect of inserting CPHTL upon the performance of blue OLEDs with 2-methyl-9,10-di(2-naphthyl)anthracene (MADN) as the blue emitter has been investigated. Compared with the luminous efficiency of the standard blue device without CPHTL (1.33 cd/A), that of the device with 40:60 CuPc/NPB CPHTL has been increased by more than twice up to 2.96 cd/A with a Commission Internationale d'Eclairage (CIE) coordinates of(x = 0.15, y = 0.10) and a power efficiency of 1.46 lm/W (20 mA/$cm^2$) at 6.39 V. The increased device efficiency is attributed to an improved balance between hole and electron currents arriving at the recombination zone.

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Characteristics of Organic Light-Emitting Diodes with the Variation of Hole-Transporting Layer (정공 수송층 변화에 따른 유기 발광 소자 특성)

  • Jeong, J.;Kim, G.S.;Byun, D.G.;Kim, G.Y.;Kim, T.W.;Hong, J.W.
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.134-136
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    • 2003
  • In this work, we have seen the effect of hole-transporting layer in organic light-emitting diodes using N,N'-biphenyl-N,N'-bis-(3-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine(TPD) and N,N'-biphenyl-N,N'-bis-(1-naphenyl)-[l,l'-biphenyl]-4,4'-diamine(NPB). NPB is regarded as a better hole trans porting material than TPD, since it has a higher glass transition temperature($T_g$). And current-voltage, luminance-voltage and external quantum efficiency of device were measured with the thickness variation of buffer layer using copper phathalocyanine(CuPc) am polytetrafluoroethylene (PTEE) at room temperature. We have obtained an improvement of External quantum efficiency when the CuPc 30[nm] and PTFE 1.0[nm] is used.

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Organic light emitting diodes using Iron(II) and Metal-free Phthalocyanine (Iron(II)과 Metal-free Phthalocyanine의 결정구조 변화에 따르는 유기 발광소자의 발광 특성)

  • 임은주;한우미;이정윤;김명식;이기진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.947-950
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    • 2001
  • We report the characteristics of organic light emitting diodes (OLEDS) by controlling the carrier mobility according to the crystalline of Iron(II) Phthalocyanine(Fe-Pc) and metal-free Phthalocyanine (H$_2$-Pc). In order to change the recombination zone, we controlled the hole mobility by changing the crystal structures of Fe-Pc and H$_2$-Pc. OLEDs were constructed with ITO/Fe-Pc/triphenyl-diamine (TPD)/tris-(8-hydroxyquinoline)aluminum (Alq$_3$)/Al and ITO/H$_2$-Pc/triphenyl-diamine (TPD)/tris-(8-hydroxyquinoline)aluminum (Alq$_3$)/Al. The electroluminescent properties were changed according to the heat-treatments of Fe-Pc and H$_2$-Pc. We observed that the recombination zone and the carrier mobility were changed as the higher occupied molecular orbital levels of Fe-Pc and H$_2$-Pc decreased.

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Studies on the Intracellular Localization of Polyamines and Their related Enzymes in Spinach Leaves (Polyamine과 Polyamine의 생합성에 관련된 효소들의 시금치잎 세포내 분포에 관한 연구)

  • 김성호
    • Journal of Plant Biology
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    • v.32 no.4
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    • pp.285-292
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    • 1989
  • The intracellular localizations of polyamines and their related enzymes were investigated from young spinach leaves. Polyamines were present in all parts of plant cells, both in the subcellular organelles and in the soluble fraction of cytoplasm, however, polyamines were mainly located in the cytosolic fraction. Most activities of L-arginine decarboxylase(ADC) and L-ornithine decarboxylase(ODC), two important enzymes of putrescine and polyamine biosynthesis, were detected in cytosol fraction, while in subcellular organelles the activities were very low. Activities of diamine oxidase(DAO) and polyamine oxidase(PAO), the catabolic enzyme of diamine and polyamine, were not detected in spinach leaves. It was suggested that polyamines and their related synthetic enzymes were located in the soluble fraction of cytoplasm.

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Voltage-Current-luminance Characteristics of Organic : Light-Emitting Diodes depending on Hole-Injection Buffer Layer (유기 발광 소자에서 정공 주입 버퍼층에 의한 전압-전류-휘도 특성)

  • Jeong Joon;Kim Tag-Yong;Ko Keel-Young;Lee Deok-Jin;Hong Jin-Woong
    • 한국컴퓨터산업교육학회:학술대회논문집
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    • 2003.11a
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    • pp.49-54
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    • 2003
  • In this work, we have seen the effect of hole-transporting layer in organic light-emitting diodes using N,N'-biphenyl-N,N'-bis-(3-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine(TPD) and N,N'-biphenyl-N,N'-bis-(1-naphenyl)-[1,1'-biphenyl]-4,4'-diamine(NPB). NPB is regarded as a better hole trans porting material than TPD, since it has a higher glass transition temperature$(T_g)$. And current -voltage, luminance-voltage and external quantum efficiency of device were measured with the thickness variation of buffer layer using copper phathalocyanine(CuPc) and polytetrafluoroethylene (PTFE) at room temperature. We have obtained an improvement of External quantum efficiency when the CuPc 30[nm] and PTFE 1.0[nm] is used.

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Synthesis and Characterization of Poly(amic acid)s from a Novel Aromatic Diamine with Bilaterally Attached Benzoxazole Group's

  • Kim, Ji-Heung;Lee, Jae-Kwan;Kim, Young-Jun;Won, Jong-Chan;Park, Kil-Young
    • Macromolecular Research
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    • v.10 no.5
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    • pp.241-245
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    • 2002
  • A new aromatic diamine monomer containing benzoxazole substituents was prepared by a multi-step synthesis starting from 1,4-dibromo-2,5-difluorobenzene. This bulky and disc-shaped monomer was polymerized with commercial dianhydride monomers to give several different poly(amic acid)s with their inherent viscosities in the range of 0.24-0.35 dL/g. The prepared polymers were soluble in typical polar aprotic solvents. Thermal imidization to the corresponding polyimides were investigated by using FT-IR, DSC and TGA.

Cure Kinetics of Epoxy/Diamine System Modified with Malononitrile by Barrett Method and Integral Method (Malononitrile에 의해 개질된 Epoxy/Diamine계의 경화반응 속도론: Barrett Method와 Integral Method)

  • Cheon, In-Suk;Don, Yun-Seung;Sim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.4 no.5
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    • pp.574-580
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    • 1994
  • This study is about cure kinetics of DGEBA/MDA/MN(malononitrile) system by Barrett method and Integral method using DSC dynamic run. Curing behavior was shown through DSC and the heat change involved in a reaction could be measured directly with DSC. The kinetic parameters such as activation energy, pre-exponential factor and reaction order were given by Barrett method and Integral method obtained in an assumption that the area of DSC enthalpic analysis curve was propotional to the enthalpic change.

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Alignment of smectic liquid crystals on newly synthesized photo-reactive polyimide with chalcone moiety

  • Song, Dong-Mee;Shin, Dong-Myung;Kim, Jae-Hoon;Kim, Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.479-482
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    • 2002
  • Benzylideneacetophenones are known as chalcones[1]. The chalcone has been known to be a photo-isomerizable and photo-dimerizable chromophore. The chalcone derivatives were prepared by base-catalyzed condensation of aldehydes and acetophenones, which were substituted with various alkyl chains. The synthesized chalcone was introduced into the t-BOC protected diamine through William synthesis reaction. Photocrosslinkable polyimide was prepared via one-step imidization reaction of DOCDA (5-(2,5-dioxotetrahydro furyl}-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride) and the chalcone introduced diamine using isoquinoline (5 wt%) in m-cresol. The polyimide solutions were spin-coated onto the quartz, silicone wafer and glass substrates and the obtained thin films were irradiated obliquely with linearly polarized UV light.

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