• 제목/요약/키워드: DfD

검색결과 177건 처리시간 0.02초

mPW1PW91 Calculated and Experimental UV/IR Spectra of Unsymmetrical trans-Stilbenes

  • Choe, Jong-In;Park, Seong-Jun;Cho, Chul-Hee;Kim, Chul-Bae;Park, Kwang-Yong
    • Bulletin of the Korean Chemical Society
    • /
    • 제31권8호
    • /
    • pp.2175-2179
    • /
    • 2010
  • Quantum mechanical properties of unsymmetrical and unfunctionalized trans-stilbene derivatives 1-3, which had been prepared by solid-phase parallel syntheses, were characterized using mPW1PW91/6-311G(d,p) (hybrid HF-DF) calculations. The total electronic energies, normal vibrational modes, Gibbs free energies, and HOMOs and LUMOs of sixteen different structures from three different groups were analyzed. The energy differences between the HOMOs and LUMOs of the various unsymmetrical trans-stilbenes are in accord with the maximum absorption peaks of the experimental UV spectra of 1-3. The calculated normal vibrational modes of 21 were comparable with its experimental IR spectrum. The $\pi$-conjugation in the para-connected biphenyl group of 2 is better than the one in the metaconnected biphenyl group on the shorter side of 3.

간호사의 조직내 대인관계 역량에 관한 구조모형 (The Structural Modeling for Nurses' Interpersonal Competence within an Organization)

  • 이지은
    • 간호행정학회지
    • /
    • 제21권4호
    • /
    • pp.366-374
    • /
    • 2015
  • Purpose: This study was designed to identify a path model that anticipates the interpersonal competence of nurses by anticipating factors that explain interpersonal competence within an organization, and analyzing the effects of these factors. A hypothetical model was formulated based on a literature review of interpersonal competence. For the study, influential factors were divided into two variables: exogenous variables including communication style, coaching leadership, and social support, and endogenous variables of self-efficacy, job satisfaction, and organizational commitment. Methods: The sample included 202 hospital nurses. Data were collected through questionnaires and analyzed using SPSS and AMOS. Results: The overall fitness was good ($x^2=74.707$, p<.001), d.f=19, $x^2/df=3.932$, GFI=.940, AGFI=.826, RMR=.009). Social support, self-efficacy, horizontal communication and organizational commitment directly affected the interpersonal competence of the nurses, and informal type of communication, horizontal, upward communication and coaching leadership indirectly effected the interpersonal competence of the nurses. Horizontal communication, social support, self-efficacy, and organizational commitment explained 46.5% of the variance in interpersonal competence of nurses. Conclusion: Based on the study results, nurses in hospitals need informal types of communication, horizontal, upward communication and coaching leadership to increase their interpersonal competence.

Credit Management Guidelines to Strengthen Thai Industrial Sector

  • KULCHITTIVEJ, Chittikhun;PORNPUNDEJWITTAYA, Pairat;SILPCHARU, Thanin
    • The Journal of Asian Finance, Economics and Business
    • /
    • 제7권9호
    • /
    • pp.351-362
    • /
    • 2020
  • This research investigates the credit management guidelines to strengthen Thai industrial sector. The research has been simulated from the findings of both qualitative and quantitative of 500 questionnaires distributed to industrial business executives in Thailand. The data were analyzed by descriptive analysis categorized into SME and large enterprises, and SEM to conduct the model in consistent with the empirical data. The results show that: (1) the credit management guidelines consist of 4 factors: a) characteristics management b) financial management c) operations management and d) assets management. The business executives gave overall importance on the guidelines at a high level with an average of 3.86. (2) The development of SEM shows that the model fits with the empirical data at Chi-Square probability level = 0.084, CMIN/DF = 1.164, GFI = 0.965 and RMSEA = 0.018. (3) The characteristics management directly influences the financial management and the operation management. The financial management directly influences on the assets management. The assets management has direct influence on the operations management. The findings show that the characteristics management is the essential starting component in SEM and the financial management factor has the most influence in the assets management variable with standard regression weight of 0.990.

사춘기 여성의 우울 예측모형 (The Predictive Model of Adolescent Women측s Depression)

  • 박영주;김희경;손정남;천숙희;신현정;정영남
    • 대한간호학회지
    • /
    • 제29권4호
    • /
    • pp.829-840
    • /
    • 1999
  • This study was conducted to construct a hypothetical model of depression in Korean adolescent women and validate the fit of the model to the empirical data. The data were collected from 345 high school girls in Seoul, from May 1 to June 30, 1998. The instruments were the Body Mass Index, Physical Satisfaction Scale, Family Adaptatibility and Cohesion Evaluation Scale III, Family Satisfaction Scale, CES-D and School Adptation Scale. The data were analyzed using descriptive statistics with the pc -SAS program. The Linear Structural Relationship(LISREL) modeling process was used to find the best fit model which would predict the causal relationships among the variables. The overall fit of the hypothetical model to the data was moderate [X$^2$=69.6(df=17, p=.000), GFI =0.95, AGFI=0.90, RMR=0.087, NNFI=0.86, NFI=0.90]. The predictable variables, especially menstrual symptoms, physical symptoms and family function, had a significant direct effect on depression. but school life adaptation did not have a significant direct effect. These variables explained 18.1% of the total variance.

  • PDF

OEM 수출기업의 ODM 전환 성과와 성공요인에 관한 실증연구 (An Empirical Study on the Performance and Success factors of Transformation from OEM Exporting companies to ODM)

  • 김귀옥;배정한
    • 무역상무연구
    • /
    • 제37권
    • /
    • pp.361-389
    • /
    • 2008
  • The purpose of this study is to detect the factors which have an effect on transformation level and performance and to provide the ways of successful transformation and vitalization from OEM to ODM. This study was proceeded by an empirical analysis. A model and hypotheses were set up and they were verified through the empirical analysis. Those factors were divided into four, inner company factors, strategic factors, core competence factors and purchase determining factors. In the result of the model suitability analysis on the study model of relationship among 'influencing factors of ODM transformation - ODM transformation level-export performance', every factors, $X^2=912.067$, DF=261, p value=0.000, GFI=0.737, AGFI=0.620, NFI=0.786, IFI=0.837, CFI=0.834, Q value=3.495 were rather insufficient to be a good model, but they were good enough for the general analysis. Taking these accounts into consideration, this study suggests the following implications. First, making a plan and setting up strategies in advance are required. Second, financial plan has to be prepared. Third, trends in global markets have to be analyzed. Fourth, companies have to focus on developing new materials and products through R&D. Fifth, quality competitiveness and quality control systems are required.

  • PDF

Construction of a Physical Activity Model for the Elderly

  • Kim, Nam-Hee;Park, Hyoung-Sook;Choi, Myunghan
    • 보건교육건강증진학회지
    • /
    • 제30권1호
    • /
    • pp.27-39
    • /
    • 2013
  • Objectives: The purpose of the study was to test a model of physical activity of elderly living in Korea, determine significant factors contributing the physical activity, and examine significant paths in the model. Methods: A cross-sectional study was conducted using a convenience sample of 207 elderly men and women, aged 60 and older, residing in Busan Metropolitan City. Data were collected from July to August 2009 and analyzed using Predictive Analytics Software (PASW) and Analysis of a Moment Structures (AMOS). Results: The fitness of the modified model was confirmed to be appropriate (${\chi}^2$ = 55.61, ${\chi}^2$/df = 1.32, p = .078, RMSEA = .04, GFI = .96, AGFI = .91, NFI = .90, NNFI = .94, CFI = .97, PNFI = .48). The elder's age, previous exercise behavior, and self-efficacy were significant in explaining the variance in their physical activity. We found that (a) perceived health status, perceived benefits, perceived barriers, and social support directly affected self-efficacy; (b) previous exercise behavior and perceived health status directly affected perceived benefits; (c) previous exercise behavior directly affected perceived barriers; and (d) and education level, extent of pocket money, and economic level directly affected social support. Conclusions: The younger the age, the more previous exercise experience, and the higher the self-efficacy, the more S. Korean elders demonstrated improved physical activity.

Power Allocation for Opportunistic Full-Duplex based Relay Selection in Cooperative Systems

  • Zhong, Bin;Zhang, Dandan;Zhang, Zhongshan
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • 제9권10호
    • /
    • pp.3908-3920
    • /
    • 2015
  • In this paper, performance analysis of full-duplex (FD) relay selection under decode-and-forward (DF) relaying mode is carried out by taking into account several critical factors, including the distributions of the received signal-to-noise ratio (SNR) and the outage probability of wireless links. The tradeoff between the FD and half-duplex (HD) modes for relay selection techniques is also analyzed, where the former suffers from the impact of residual self-interference, but the latter requires more channel resources than the former (i.e., two orthogonal channels are required). Furthermore, the impact of optimal power allocation (OPA) on the proposed relay-selection scheme is analyzed. Particularly, the exact closed-form expressions for outage probability of the proposed scheme over Rayleigh fading channels are derived, followed by validating the proposed analysis using simulation. Numerical results show that the proposed FD based scheme outperforms the HD based scheme by more than 4 dB in terms of coding gain, provided that the residual self-interference level in the FD mode can be substantially suppressed to the level that is below the noise power.

Surface removal of stainless steel using a single-mode continuous wave fiber laser to decontaminate primary circuits

  • Song, Ki-Hee;Shin, Jae Sung
    • Nuclear Engineering and Technology
    • /
    • 제54권9호
    • /
    • pp.3293-3298
    • /
    • 2022
  • Removing radioactive contaminated metal materials is a vital task during the decommissioning of nuclear power plants to reduce the cost of the post-dismantling process. The laser decontamination technique has been recognized as a key tool for a successful dismantling process as it enables a remote operation in radioactive facilities. It also minimizes exposure of workers to hazardous materials and reduces secondary waste, increasing the environmental friendless of the post-dismantling processing. In this work, we present a thorough and efficient laser decontamination approach using a single-mode continuous-wave (CW) laser. We subjected stainless steels to a surface-removal process that repetitively exposes the laser to a confined region of ~75 ㎛ at a high scanning rate of 10 m/s. We evaluate the decontamination performance by measuring the removal depth with a 3D scanning microscope and further investigate optimal removal conditions given practical parameters such as the laser power and scan properties. We successfully removed the metal surface to a depth of more than 40 ㎛ with laser power of 300 W and ten scans, showing the potential to achieve an extremely high DF more than 1000 by simply increasing the number of scans and the laser power for the decontamination of primary circuits.

Evaluation of decontamination factor of radioactive methyl iodide on activated carbons at high humid conditions

  • Choi, Byung-Seon;Kim, Seon-Byeong;Moon, Jeikwon;Seo, Bum-Kyung
    • Nuclear Engineering and Technology
    • /
    • 제53권5호
    • /
    • pp.1519-1523
    • /
    • 2021
  • Radioactive iodine (131I) released from nuclear power plants has been a critical environmental concern for workers. The effective trapping of radioactive iodine isotopes from the off-gas stream generated from nuclear facilities is an important issue in radioactive waste treatment systems evaluation. Numerous studies on retaining methyl iodide (CH3I131) by impregnated activated carbons under the high content of moisture have been extensively studied so far. But there have been no good results on how to remove methyl iodide at high humid conditions up to now. A new challenge is to introduce other promising impregnating chemical agents that are able to uptake enough radioactive methyl iodide under high humid conditions. In order to develop a good removal efficiency to control radioiodine gas generated from a high humid process, activated carbons (ACs) impregnated with triethylene diamine (TEDA) and qinuclidine (QUID) were prepared. In addition, the removal efficiencies of the activated carbons (ACs) under humid conditions up to 95% RH were evaluated by applying the standard method specified in ASTM-D3808. Quinuclidine impregnated activated carbon showed a much higher decontamination factor above 1,000, which is enough to meet the regulation index for the iodine filters in nuclear power plants (NPPs).

성인여성학습자의 학습성과에 대한 구조분석 (A Structural Analysis of Learner on Adult Female Learners' Learning Outcome)

  • 장은숙
    • 한국산학기술학회논문지
    • /
    • 제17권3호
    • /
    • pp.364-372
    • /
    • 2016
  • 본 연구는 평생학습에 참여하는 성인여성학습자의 학습성과에 영향을 미치는 요인들을 분석하고 관련 변인들이 학습성과와 어떠한 구조적인 관계를 형성하는지 고찰하는데 그 목적이 있다. 분석대상은 D지역 평생교육기관에서 평생학습에 참여하거나 평생학습경험이 있는 성인여성학습자 578명을 연구대상으로 하였다. 본 연구에서는 학습성과를 분석하기 위한 관련변인으로 학습자특성, 평생교육기관여건, 학습몰입, 학습만족도를 잠재변인으로 설정하여 14개의 관측변수를 두어 구조적 인과모형을 구성하였다. 연구결과, 모형의 적합도 지수의 값은 ${\chi}^2=224.267$ (df=69, p<.001), RMSEA=.062, TLI=.943, RFI=.920, CFI=.957, IFI=.957, NFI=.939로서, 모두 0.9이상으로 적합도 지수가 모두 만족되었다. 학습자특성의 학습성과에 대한 표준화계수는 .218이고 p<.001,평생교육기관여건의 학습성과에 대한 표준화계수는 .301, p<.001, 학습몰입이 학습성과에 대한 표준화계수는 -.149, p=.541, 학습만족도는 표준화계수 .405, p<.001로 학습몰입을 제외하고 모두 학습성과에 직접 영향을 주는 것으로 나타났다. 연구를 통해, 학습자특성과 평생교육기관, 학습만족도가 학습성과에 유의한 직접효과를 가지고 있음을 확인하였다. 학습몰입은 학습성과에 직접 효과를 주지 못하고, 학습만족도를 매개로 간접효과를 주는 것으로 나타났다. 본 연구는 평생학습성과를 설명할 수 있는 종합모델을 구축하고, 관련 변인들 간의 구조적 인과관계를 밝힘으로써, 성인여성학습자의 학습성과에 대한 전체적 측면에서의 구조를 설명할 수 있는 이론적 논의를 시도하였다는 점과 학습성과와 관련된 변인들간의 구조적 인과관계를 실증적으로 탐색했다는 점에서 의의가 있다.