• Bulletin of the Korean Chemical Society
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• v.32 no.spc8
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• pp.3031-3038
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• 2011

Ion-coordinating ruthenium complexes [cis-Ru(dcbpy)(L)(NCS)$_2$, where dcbpy is 4,4'-dicarboxylic acid-2,2'-bipyridine and L is 1,4,7,10-tetraoxa-13-azacyclopentadecane, JK-121, or bis(2-(2-methoxy-ethoxy)ethyl) amine, JK-122] have been synthesized and characterized using $^1H$ NMR, Fourier transform IR, UV/vis spectroscopy, and cyclic voltammetry. The effect of $Li^+$ in the electrolyte on the photovoltaic performance was investigated. With the stepwise addition of $Li^+$ to a liquid electrolyte, the device shows significant increase in the photo-current density, but a small decrease in the open circuit voltage. The solar cell with a hole conductor, the addition of $Li^+$ resulted in a 30% improvement in efficiency. The JK-121 sensitized cells in the liquid and solid-state electrolyte give power conversion efficiencies of 6.95% and 2.59%, respectively, under the simulated sunlight.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.63.2-63.2
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• 2015

Controlling and sensing spin states of magnetic molecules such as metallo-porphyrins at the single molecule level is essential for spintronic molecular device applications. Axial coordinations of diatomic molecules to metallo-porphyrins also play key roles in dynamic processes of biological functions such as blood pressure control and immune response. However, probing such reactions at the single molecule level to understand their physical mechanisms has been rarely performed. Here we present on our single molecule association and dissociation experiments between diatomic and metallo-porphyrin molecules on Au(111) describing its adsorption structures, spin states, and dissociation mechanisms. We observed bright ring shapes in NO adsorbed metallo-porphyrin compelxes and explained them by considering tilted binding and precession motion of NO. Before NO exposure, Co-porphryin showed a clear zero-bias peak in scanning tunneling spectroscopy, a signature of Kondo effect in STS, whereas after NO exposures it formed a molecular complex, NO-Co-porphyrin, that did not show any zero-bias feature implying that the Kondo effect was switched off by binding of NO. Under tunneling junctions of scanning tunneling microscope, both positive and negative energy pulses. From the observed power law relations between dissociation rate and tunneling current, we argue that the dissociations were inelastically induced with molecular orbital resonances. Our study shows that single molecule association and dissociation can be used to probe spin states and reaction mechanisms in a variety of axial coordination between small molecules and metallo-porphyrins.

• Textile Coloration and Finishing
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• v.18 no.4
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• pp.11-19
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• 2006

Black-dyed PET fabrics were sputtered with stainless steel through DC-magnetron type device to investigate the possibility of coloration effect, and then considered the morphological structure and physical characteristics such as water permeation ability and washing fastness. Change in color was estimated on the basis of CIELAB color system. The color coordination of metal plated PET was shifted to yellow-red from red-blue. Colour difference$({\Delta}E^*)$ was increased by sputtering conditions with increasing ion current and treatment time. Especially, $Lightness(L^*)$ value of PET was remarkably increased by sputtering, whereas $Chroma(C^*)$ increased gradually. From SEM analysis, rough and uneven craters were found and thickened on the fiber surfaces with longer sputtering time. And washing fastness was a little poor and absorption ability slightly decreased. There were little changes of breaking load and breaking extension. It was evident that observed uneven craters in the plated thin layer resulted in the colour change of PET fabrics by sputtering treatments.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.7
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• pp.925-930
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• 2013

The fault current of the power transmission system is greater than that of the power distribution system. Therefore, the introduction of superconducting fault current limiter (SFCL) is more needed to reduce the increased fault current. The trigger-type SFCL consists of the high-temperature superconducting element (HTSC), the current limiting reactor (CLR) and the circuit breaker (CB). The trigger-type SFCL can be used to supplement the disadvantages of the resistive-type SFCL. The operation characteristics of the current ratio differential relay which is usually applied to the protection device of the power transmission system are expected to be affected under fault conditions and the applicability of the trigger-type SFCL. In this paper, we analyzed the operating characteristics, by the fault conditions, between the current ratio differential relay for line protection and the trigger-type SFCL in the power transmission system through the PSCAD/EMTDC simulation.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.59 no.2
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• pp.179-184
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• 2010

The digital substation automation system has contributed hugely to increasing the stability of power systems by providing not only protection and control of power systems but diagnostic features alongside them. Digital substation automation systems in the scale of substations consist of integrated operation systems and intelligent electronic devices. The main intelligent electronic devices currently in use are digital protection relays and the bay controllers in Gas insulated switchgears. Proficiently accomplishing the coordination of protection within the power system as a means of ensuring reliability and contriving for the stability of power supply through connection of function, the application of bay controllers is crucial, which collectively manage the protection relay at the bay level in order to achieve both. In this research, the bay controllers to be used in high-voltage Gas insulated switchgear has been localized, and in particular, the logic function and editor required in order to minimize the complicated hardware-like cable connections in the local panel have been developed. In addition, to ensure the strength and reliability of the bay controller hardware developed herein, the type tests from KERI have been successfully completed.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.63 no.3
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• pp.183-188
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• 2014

Power conversion systems used in large gas turbine power plant can be divided into two main part. Because of the initial start-up characteristic of the gas turbine combustor, the gas turbine must be accelerated by starting device(LCI : Load Commutated Inverter) up to 10%~20% of rated speed to ignite it. In addition, the ECS(Excitation Control system) is used to control the rotor field current and reactive power in grid-connected synchronous generator. These two large power conversion systems are located in the same space(container) because of coordination control. Recently, many manufactures develop high speed controller based on function block available in the LCI and ECS with the newest power semiconductor. We also developed high speed controller based on function block to be using these two system and it meets the international standard IEC61131 as using real-time OS(VxWorks) and ISaGRAF. In order to install easily these systems at power plant, main controller, special module and IO module are used with high speed communication line other than electric wire line. Before initial product is installed on the site, prototype is produced and tests are conducted for it. The performance results of Integrated controller and application program(SFC, ECS) were described in this paper. The test results will be considered as the important resources for the application in future.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.118.1-118.1
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• 2011

The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of TiO2 are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

• Journal of Mechanical Science and Technology
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• v.17 no.5
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• pp.629-636
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• 2003

This paper introduces the developed geometry PIG (Pipeline Inspection Gauge), one of several ILI (In-Line Inspection) tools, which provide a full picture of the pipeline from only single pass, and has compact size of the electronic device with not only low power consumption but also rapid response of sensors such as calipers, IMU and odometer. This tool is equipped with the several sensor systems. Caliper sensors measure the pipeline internal diameter, ovality and dent size and shape with high accuracy. The IMU (Inertial Measurement Unit) measures the precise trajectory of the PIG during its traverse of the pipeline. The IMU also provide three-dimensional coordination in space from measurement of inertial acceleration and angular rate. Three odometers mounted on the PIG body provide the distance moved along the line and instantaneous velocity during the PIG run. The datum measured by the sensor systems are stored in on-board solid state memory and magnetic tape devices. There is an electromagnetic transmitter at the back end of the tool, the transmitter enables the inspection operators to keep tracking the tool while it travels through the pipeline. An experiment was fulfilled in pull-rig facility and was adopted from Incheon LT (LNG Terminal) to Namdong GS (Governor Station) line, 13 km length.

• Proceedings of the KIEE Conference
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• 2001.11b
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• pp.340-343
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• 2001

In an electrical network, electrical power are transmitted by a various of protection, isolation and control electric circuit devices. This thesis deals with the protection function between circuit-breakers. The protective coordination concerns the behaviour of two devices placed in series in an electrical network, with a short-circuit downstream circuit-breaker. It has two basic principles: First, discrimination which is an increasing requirement of low voltage electrical distribution systems. Second, which is less well known: cascading, which consists of installing a device, whose breaking capacity is less than the three-phase short-circuit current at its terminals and helped by main circuit-breaker. The important advantage of cascading is to be able to install at a branch circuit-breaker of a lesser performance without endangering the safety of the installation for more economical usage. To determine and guarantee co-ordination between two circuit breakers, it is necessary to carry out a theoretical approach, first, and then confirm the results by means of standard tests. This is illustrated in appendix A of IEC 947-2.

• Journal of the Semiconductor & Display Technology
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• v.13 no.2
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• pp.45-52
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• 2014

This paper proposes an efficient photo retrieval system that automatically indexes for searching of relevant images, using a combination of geo-coded information, direction/location of image capture device and content-based visual features. A photo image is labeled with its GPS (Global Positioning System) coordinates and direction of the camera view at the moment of capture, and the label leads to generate a geo-spatial index with three core elements of latitude, longitude and viewing direction. Then, content-based visual features are extracted and combined with the geo-spatial information, for indexing and retrieving the photo images. For user's querying process, the proposed method adopts two steps as a progressive approach, filtering the relevant subset prior to use a content-based ranking function. To evaluate the performance of the proposed scheme, we assess the simulation performance in terms of average precision and F-score, using a natural photo collection. Comparing the proposed approach to retrieve using only visual features, an improvement of 20.8% was observed. The experimental results show that the proposed method exhibited a significant enhancement of around 7.2% in retrieval effectiveness, compared to previous work. These results reveal that a combination of context and content analysis is markedly more efficient and meaningful that using only visual feature for image search.