• Title/Summary/Keyword: Derivatives Transactions

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Improvement of Sensitivity Based Concurrent Subspace Optimization Using Automatic Differentiation (자동미분을 이용한 민감도기반 분리시스템동시최적화기법의 개선)

  • Park, Chang-Gyu;Lee, Jong-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.2
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    • pp.182-191
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    • 2001
  • The paper describes the improvement on concurrent subspace optimization(CSSO) via automatic differentiation. CSSO is an efficient strategy to coupled multidisciplinary design optimization(MDO), wherein the original design problem is non-hierarchically decomposed into a set of smaller, more tractable subspaces. Key elements in CSSO are consisted of global sensitivity equation, subspace optimization, optimum sensitivity analysis, and coordination optimization problem that require frequent use of 1st order derivatives to obtain design sensitivity information. The current version of CSSO adopts automatic differentiation scheme to provide a robust sensitivity solution. Automatic differentiation has numerical effectiveness over finite difference schemes tat require the perturbed finite step size in design variable. ADIFOR(Automatic Differentiation In FORtran) is employed to evaluate sensitivities in the present work. The use of exact function derivatives facilitates to enhance the numerical accuracy during the iterative design process. The paper discusses how much the automatic differentiation based approach contributes design performance, compared with traditional all-in-one(non-decomposed) and finite difference based approaches.

Synthesis and Luminescent Properties of Tetrafluorophenyl Containing Poly(p-phenylenevinylene) Derivatives

  • Ahn, Taek
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.3
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    • pp.162-167
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    • 2015
  • To investigate the effect of fluoro groups substitution on poly(p-phenylenevinylene) derivatives, poly(2,3,5,6- tetrafluoro-p-phenylenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene), PCTF-PPV, and poly[2,3,5,6-tetrafluoro-p-phenylenevinylene-alt-2-methoxy-5-(2-ethylhexyloxy)-p-phenylenevinylene], PMTF-PPV, were synthesized by the well-known Wittig condensation polymerization process. To compare the influences of fluoro groups, no fluoro groups containing model polymers, poly(p-phenylenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene), PCPPPV and poly[p-phenylenevinylene-alt-2-methoxy-5-(2-ethylhexyloxy)-p-phenylenevinylene], p-PMEH-PPV, were also synthesized. The resulting polymers were completely soluble in common organic solvents and exhibited good thermal stability up to 300℃. The polymers showed UV-visible absorbance and photoluminescence (PL) in the ranges of 259~452 nm and 500~580 nm, respectively. The tetrafluorophenyl containing PCTF-PPV and PMTF-PPV showed relatively red-shifted PL peaks at 521 nm and 580 nm, respectively, compared to that of non-fluoro groups containing polymers (PCP-PPV: 500 nm and p-PMEH-PPV: 539 nm). The single-layer light-emitting diode was fabricated in a configuration of ITO/polymer/Al. Electroluminescene (EL) emissions of PCP-PPV, PCTF-PPV, p-PMEH-PPV and PMTF-PPV were shown at 507, 524, 556, and 616 nm, respectively.

Development of an Optimization Technique for Robust Design of Mechanical Structures (기계 구조의 강건 설계를 위한 최적화 기법의 개발)

  • Jeong, Do-Hyeon;Lee, Byeong-Chae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.1 s.173
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    • pp.215-224
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    • 2000
  • In order to reduce the variation effects of uncertainties in the engineering environments, new robust optimization method, which considers the uncertainties in design process, is proposed. Both design variables and system parameters are considered as random variables about their nominal values. To ensure the robustness of performance function, a new objective is set to minimize the variance of that function. Constraint variations are handled by introducing probability constraints. Probability constraints are solved by the advanced first order second moment (AFOSM) method based on the reliability theory. The proposed robust optimization method has an advantage that the second derivatives of the constraints are not required. The suggested method is examined by solving three examples and the results are compared with those for deterministic case and those available in literature.

An Integral Equation for Kinked Cracks in Finite Plane Bodies (유한영역에서의 꺾인균열 해석을 위한 적분방정식 적용 연구)

  • 서욱환
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.9
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    • pp.2138-2144
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    • 1993
  • An integral equation representation of cracks was presented which differs from well-known "dislocation layer" representation. In this new representation, the equations are written in terms of the displacement discontinuity across the crack surfaces rather than derivatives of the displacement-discontinuity. It was shown in that the new technique is well-suited to the treatment of kinked cracks. In the present paper, this integral equation representation is coupled to the direct boundary-element method for the treatment of finite bodies containing kinked cracks. The method is demonstrated for two-dimensional finite domains but extension to three-dimensional problems would appear to be possible. The resulting approach is shown to be simple, yet very accurate. accurate.

Electrical and Optical Properties of Substituted Heterocyclic Conducting Polymers (치환 복소환 도전성 고분자의 전기.광학적 성질)

  • ;;;Katsumi Yoshino
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.40 no.1
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    • pp.91-98
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    • 1991
  • Electrical conductivity of poly (3-alkylthiophene) derivatives with substituted long alkyl chain such as poly (3-butylthiophene), poly (3-hexylthiophene), poly (3-octylthiophene), poly (3-decylthiophene), poly (3-dodecylthiophene), and poly (3-docosylthiophene) increases with increasing temperature. However, after attaining a maxiumum value, it decreases with further temperature increase. Hysteresis is also observed in the temperature dependence of conductivity and absorption spectra. The absorption spectra also changes rapidly at the phase transition. These phenomena are discussed in terms of the increase of the energy band gap in the liquid states due to the decrease of co-planarity of thiophene rings accompanied by remarkable conformation changes.

Effect of Antioxidants on the Oxidative Stability of Biodiesel Fuels (항산화제가 바이오디젤유의 산화안정성에 미치는 영향)

  • Ryu, Kyung-Hyun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.6
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    • pp.81-86
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    • 2007
  • Biodiesel fuel that consists of saturated and unsaturated long-chain fatty acid alkyl esters is an alternative diesel fuel produced from vegetable oils or animal fats. However, air causes autoxidation of biodiesel fuel during storage, which can reduce fuel quality by adversely affecting its properties, such as the kinematic viscosity and acid value. One approach for improving the resistance of fatty derivatives to autoxidation is to mix them with antioxidants. This study investigated the effectiveness of five such antioxidants in mixtures with biodiesel fuels produced by three biodiesel manufacturers : tert-butylhydroquinone (TBHQ), butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), propyl gallate (PrG) and $\alpha$-tocopherol. Oxidation stability was determined using Rancimat equipment. The results show that TBHQ, BHA, and BHT were the most effective and $\alpha$-tocopherol was the least effective at increasing the oxidation stability of biodiesel. This study recommends that TBHQ and PrG be used for safeguarding biodiesel fuel from the effects of autoxidation during storage.

Systematic Approaches for Blue Light-emitting Polymers by Introducing Various Naphthalene Linkages into Carbazole Containing PPV Derivatives

  • Ahn, Taek
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.5
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    • pp.258-262
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    • 2013
  • Poly(2,3-naphthalenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene), 2,3-PNCPV, poly(2,6-naphthalene vinylenealt- N-ethylhexyl-3,6-carbazolevinylene), 2,6-PNCPV, and poly(1,4-naphthalenevinylene-alt-N-ethylhexyl-3,6- carbazolevinylene), 1,4-PNCPV were synthesized through the Wittig polycondensation reaction. The conjugation lengths of the polymers were controlled by differently linked naphthalenes in the polymer main chain. The resulting polymers were completely soluble in common organic solvents, and exhibited good thermal stability at up to $400^{\circ}C$. The synthesized polymers showed UV-visible absorbance and photoluminescence (PL) in the ranges of 357-374 nm and 487-538 nm, respectively. The carbazole and 2,3-linked naphthalene containing 2,3-PNCPV showed a blue PL peak at 487 nm. A single-layer light-emitting diode was fabricated with an ITO/polymer/Al configuration. The electroluminescence (EL) emission of 2,3-PNCPV was shown at 483 nm.

Optimal Shape Design of Excavator Boom Using the Semi-Analytical Method (민감도 근사해석법을 이용한 굴삭기 붐의 최적형상설계)

  • Lim, O-Kaung;Cho, Heon
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.1
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    • pp.301-309
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    • 1995
  • Shape optimal design of an excavator boom to minimize weight can be formulated as a nonlinear programming problem with an automesh refinement carried out by using the finite element method. The design variables are the radii and the coordinates of the circle to describe the excavator boundary shape. In addition to the displacement and stress constraints, geometric constraints are imposed such that the nodes cannot cross the certain range. The optimum design is obtained by using the PLBA nonlinear programming code. The sensitivity derivatives are calculated using the semi-analytical scheme. Numerical results of an excavator boom show potential for weight reduction of 4.4%(65.6 kgf) when considering the displacement, stress and geometric constraints.

An Experimental Study of the Effects of Water Vapor in Intake Air on Comvustion and knock Characteristics in a Spark Ignition Engine (흡기중 수증기 함량이 스파크 점화기관의 연소 및 노킹에 미치는 영향에 관한 실험적 연구)

  • 이택헌;전광민
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.1
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    • pp.205-212
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    • 1998
  • In this study, the effects of water vapor in inlet air on combustion efficiency, general performance, knock characteristics and emission gas concentration were investig- ated through the experiments of combustion and vibration analyses, emission gas analysis by changing water vapor quantity in inlet air with temperature and humidity auto control unit. With partial vapor pressure increase, the brake torque at wide open throttle status decreased and the average ignition delay angle increased, IMEP (indicated mean effective pressured using the integral and 3rd derivatives of filtered cylinder pressure as knock intensity, which matched well with the method of frequency power spectrum of block vibration signal. Water vapor in intake air had influence on the spark knock sensitivity. With the increase of water vapor content in intake air NOx emission was decreased and HC emission was increased.

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Sparse Representation based Two-dimensional Bar Code Image Super-resolution

  • Shen, Yiling;Liu, Ningzhong;Sun, Han
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.4
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    • pp.2109-2123
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    • 2017
  • This paper presents a super-resolution reconstruction method based on sparse representation for two-dimensional bar code images. Considering the features of two-dimensional bar code images, Kirsch and LBP (local binary pattern) operators are used to extract the edge gradient and texture features. Feature extraction is constituted based on these two features and additional two second-order derivatives. By joint dictionary learning of the low-resolution and high-resolution image patch pairs, the sparse representation of corresponding patches is the same. In addition, the global constraint is exerted on the initial estimation of high-resolution image which makes the reconstructed result closer to the real one. The experimental results demonstrate the effectiveness of the proposed algorithm for two-dimensional bar code images by comparing with other reconstruction algorithms.