• Title/Summary/Keyword: Deposition time

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Terahertz time domain spectroscopy of GdBCO superconducting thin films

  • Ji, Gangseon;Park, Woongkyu;Lee, Hyoung-Taek;Song, Chang-Yun;Seo, Choongwon;Park, Minjo;Kang, Byeongwon;Kim, Kyungwan;Kim, Dai-Sik;Park, Hyeong-Ryeol
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.1
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    • pp.15-17
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    • 2019
  • We present terahertz optical properties of $GdBa_2Cu_3O_{7-x}$ (GdBCO) superconducting thin films. GdBCO films with a thickness of about 105 nm were grown on a $LaAlO_3$ (LAO) single crystal substrate using a conventional pulsed laser deposition (PLD) technique. Using an Ar ion milling system, the thickness of the GdBCO film was reduced to 58 nm, and its surface was also smoothened. Terahertz (THz) transmission spectra through two different GdBCO films are measured over the range between 0.2 and 1.5 THz using THz time domain spectroscopy. Interestingly, the THz transmission of the thinner GdBCO film has been increased to six times larger than that of the thicker one, while the thinner film is still maintaining its superconducting property at below 90 K.

Comparison of Numerical Analysis Methods of APro for the Total System Performance Assessment of a Geological Disposal System

  • Hyun Ho Cho;Hong Jang;Dong Hyuk Lee;Jung-Woo Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.1
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    • pp.165-173
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    • 2023
  • Various linear system solvers with multi-physics analysis schemes are compared focusing on the near-field region considering thermal-hydraulic-chemical (THC) coupled multi-physics phenomena. APro, developed at KAERI for total system performance assessment (TSPA), performs a finite element analysis with COMSOL, for which the various combinations of linear system solvers and multi-physics analysis schemes should to be compared. The KBS-3 type disposal system proposed by Sweden is set as the target system and the near-field region, which accounts for most of the computational burden is considered. For comparison of numerical analysis methods, the computing time and memory requirement are the main concerns and thus the simulation time is set up to one year. With a single deposition hole problem, PARDISO and GMRES-SSOR are selected as representative direct and iterative solvers respectively. The performance of representative linear system solvers is then examined through a problem with an increasing number of deposition holes and the GMRES-SSOR solver with a segregated scheme shows the best performance with respect to the computing time and memory requirement. The results of the comparative analysis are expected to provide a good guideline to choose better numerical analysis methods for TSPA.

The Effect of Acidic Deposition on Nitrate Reductase Activity and Photosynthesis of Hypnum plumaeforme (산성강하물이 털깃털이끼(Hypnum plumaeforme)의 질산 환원효소와 광합성에 미치는 영향)

  • 이점숙;임병선;임현빈
    • The Korean Journal of Ecology
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    • v.17 no.1
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    • pp.69-78
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    • 1994
  • The acidic deposition (wet) was collected at three different locations; representative industrial (Kun-Jang industrial areas), semiindustrial (Kunsan City) and nonindustrial (Daeya areas) region between March, 1991 and June, 1993. Samples were analyzed for major chemical components along with pH. Also the responses of Hypnum filunzaeforme to the acidic deposition adjusted to pH 4.6, 3.6 and 2.6 with 1:4 molar ratio of nitric to sulfuric acid were investigated. Seasonal variation of pH showed the lowest in early spring and the highest in summer. The annual mean concentrations of $S0_4^{2-},\;NO_3^{-}\;and\;NH_4^{+}$ were 2.94 (81.0%), 0.48 (13.2%) and 0.21 (5.78%) mg/l in industrial region and 0.61 (64.21%), 0.25 (26.3%) and 0.9 (9.5%) mg /I in nonindustrial region, respectively. $S0_4^{2-}$ contents of industrial region was 4 times higher than those of nonindustrial region. The ratio of $S0_4^{2-}\;to\;NO_3^{-}$ was 4.75~7.35 in industrial region and 0.69-6.36 in nonindustrial region. The acidic deposition near industrial region was associated with excess ions, expecially $S0_4^{2-}$. Nitrate reductase activity(NRA) of mosses was inhibited by acidic deposition in both regions. The time required for the maximum NRA induction by 2mM $KNO_3$ was shortened in mosses collected from industrial region. Photosynthesis of H. plumaejorme began to decrease with acidic deposition by pH below 4.6, and was completely inhibited at pH 2.6 in both regions. Water potential of mosses treated with acidic deposition was almost constant during 18 days, however after withholding the supply of acidic deposition, it was rapidly decreased.

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A Study on the Sediment Deposition Height Computation at Gunsan Port Using EFDC (EFDC를 이용한 군산항의 유사 퇴적고 계산에 관한 연구)

  • Lee, Dong Joo;Park, Young Ki
    • Journal of Korea Water Resources Association
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    • v.46 no.5
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    • pp.531-545
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    • 2013
  • This paper was considered on the applicability of EFDC KUNSAN_SEDTRAN MODEL (2012) to calculate Gunsan Port sediment deposition height efficiently and to use for grasping its aspects quantitatively and providing its prevention measures reasonably based on well-known 3-dimensional EFDC sediment transport module. This model was calibrated and verified with various measured field data of A Report of Hydrological Variation on Kum River Estuary (2004). Due to the model calibration and relevant literature investigation for cohesive sediment parameters, settling velocity (WS), critical deposition stress (TD), reference surface erosion rate (RSE), critical erosion stress (TE) were identified as 2.2E-04m/s, 0.20 $N/m^2$, 0.003 $g/s{\cdot}m^2$, 0.40 $N/m^2$ respectivly on this model. In order to examine the applicability and precision of the model computation, the calculated model data of sediment deposition height at 13 stations for 71 days and suspended-sediment concentration at 2 stations, inner port and outer port for 15 days were compared and analyzed with the measured field data. As a result, the model applicability for sediment deposition height simulation was evaluated as NSE coefficient 0.86 and the precision for suspended-sediment concentration computation was evaluated as time averaged relative error (RE) 23%.

Development of an Improved Numerical Methodology for Design and Modification of Large Area Plasma Processing Chamber

  • Kim, Ho-Jun;Lee, Seung-Mu;Won, Je-Hyeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.221-221
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    • 2014
  • The present work proposes an improved numerical simulator for design and modification of large area capacitively coupled plasma (CCP) processing chamber. CCP, as notoriously well-known, demands the tremendously huge computational cost for carrying out transient analyses in realistic multi-dimensional models, because electron dissociations take place in a much smaller time scale (${\Delta}t{\approx}10-8{\sim}10-10$) than time scale of those happened between neutrals (${\Delta}t{\approx}10-1{\sim}10-3$), due to the rf drive frequencies of external electric field. And also, for spatial discretization of electron flux (Je), exponential scheme such as Scharfetter-Gummel method needs to be used in order to alleviate the numerical stiffness and resolve exponential change of spatial distribution of electron temperature (Te) and electron number density (Ne) in the vicinity of electrodes. Due to such computational intractability, it is prohibited to simulate CCP deposition in a three-dimension within acceptable calculation runtimes (<24 h). Under the situation where process conditions require thickness non-uniformity below 5%, however, detailed flow features of reactive gases induced from three-dimensional geometric effects such as gas distribution through the perforated plates (showerhead) should be considered. Without considering plasma chemistry, we therefore simulated flow, temperature and species fields in three-dimensional geometry first, and then, based on that data, boundary conditions of two-dimensional plasma discharge model are set. In the particular case of SiH4-NH3-N2-He CCP discharge to produce deposition of SiNxHy thin film, a cylindrical showerhead electrode reactor was studied by numerical modeling of mass, momentum and energy transports for charged particles in an axi-symmetric geometry. By solving transport equations of electron and radicals simultaneously, we observed that the way how source gases are consumed in the non-isothermal flow field and such consequences on active species production were outlined as playing the leading parts in the processes. As an example of application of the model for the prediction of the deposited thickness uniformity in a 300 mm wafer plasma processing chamber, the results were compared with the experimentally measured deposition profiles along the radius of the wafer varying inter-electrode gap. The simulation results were in good agreement with experimental data.

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Preparation and Characterization of Organic-inorganic Hybrid Composite Film with Plate-shaped Alumina by Electrophoretic Deposition as a Function of Aging Time of Sol-Gel Binder

  • Kim, Doo Hwan;Park, Hee Jeong;Choi, Jinsub;Lim, Hyung Mi
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.366-373
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    • 2015
  • Sol-gel binder was prepared by hydrolysis and condensation reaction using boehmite sol and methyltrimethoxysilane as a function of aging-time. The coating slurry was composed of a plate-shape alumina in the sol-gel binder for the EPD process, in which particles dispersed in the slurry were deposited on the electrode under an electric field due to the surface charge. We studied the effects of three parameters: the content of boehmite, the aging time, and the applied voltage, on the physical, thermal, and electrical properties of the hybrid composite films by EPD. The amount of boehmite was 10 ~ 20 wt% and the aging time was 0.5 ~ 72, with a fixed amount of plate-shape alumina of 10 wt%. The condition of applied voltage was 5 ~ 30 V with a distance of 2 cm between the electrode during the EPD process. We confirmed that a structure of hybrid composite films of well-ordered plate alumina was deposited on the substrate when the film was prepared using a sol-gel binder composed of 15 wt% boehmite with 1 hr aging time and EPD at 10 V. The process shows a weight loss of 7% at $500^{\circ}C$ in TGA and a breakdown voltage of 8 kV at $87{\mu}m$.

Deposition Velocity of Iodine Vapor ($(I_2)$) for Radish Plants and Its Root-Translocation Factor : Results of Experimental Exposures (요오드 증기($I_2$)의 무 작물체에 대한 침적속도 및 뿌리 전류계수 : 피폭실험 결과)

  • Choi, Yong-Ho;Lim, Kwang-Muk;Jun, In;Park, Doo-Won;Keum, Dong-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.2
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    • pp.151-158
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    • 2010
  • In order to measure the deposition velocity of $I_2$ vapor for radish plants and its translocation factor for their roots, radish plants were exposed to $I_2$ vapor for 80 min. at different growth stages between 29 and 53 d after sowing. The exposure was performed in a transparent chamber during the morning time. Deposition velocities ($ms^{-1}$) were on the whole in the range of $1.0{\times}10^{-4}{\sim}2.0{\times}10^{-4}$ showing an increasing tendency with an increase in the biomass density. The results showed some agreement with existing reports that a higher relative humidity would lead to a higher deposition velocity. The acquired deposition velocities were lower than by factors of several tens than some field measurements probably due to a very low wind speed (about $0.2\;ms^{-1}$) in the chamber. Translocation factors (ratio of the total iodine in the roots at harvest to the total plant deposition), estimated in a more or less conservative way, were $1.3{\times}10^{-3}$ for an exposure at 29 d after sowing and $5.0{\times}10^{-3}$ for an exposure at 53 d after sowing. In using the present experimental data, meteorological conditions and chemical and physical forms of iodine need to be carefully considered.

Optimum Design of Vaporizer Fin with Liquefied Natural Gas by Numerical Analysis

  • Jeong Hyo-Min;Chung Han-Shik;Lee Sang-Chul;Kong Tae-Woo;Yi Chung-Seub
    • Journal of Mechanical Science and Technology
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    • v.20 no.4
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    • pp.545-553
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    • 2006
  • Generally, the temperature drop under $0^{\circ}C$ on vaporizer surface creates frozen dews. This problem seems to increase as the time progress and humidity rises. In addition, the frozen dews create frost deposition. Consequently, heat transfer on vaporizer decreases because frost deposition causes adiabatic condition. Therefore, it is very important to solve this problem. This paper aims to study of the optimum design of used vaporizer at local LNG station. In this paper, experimental results were compared with numerical results. Geometries of numerical and experimental vaporizers were identical. Studied parameters of vaporizer are angle between two fins $(\Phi)$ and fin thickness $(TH_F)$. Numerical analysis results were presented through the correlations between the ice layer thickness $(TH_{ICE})$ on the vaporizer surface to the temperature distribution of inside vaporizer $(T_{IN})$, fin thickness $(TH_F)$, and angle between two fins $(\Phi)$. Numerical result shows good agreement with experimental outcome. Finally, the correlations for optimum design of vaporizer are proposed on this paper.

Synthesis of Yttria Doped Ceria Powders by a Citrate Method and Their Thin Film Preparation by Electrospray Method (구연산법에 의한 Yttria Doped Ceria (YDC) 분말 합성 및 정전분무법에 의한 YDC 박막 제조)

  • Kwon, Hyuk Taek;Baik, Seung Min;Kim, Jinsoo
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.76-80
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    • 2010
  • In this study, YDC powders with uniform composition and particle size were synthesized by a citrate method and their thin film deposition was conducted by electrospray deposition method. Polymeric precursor was prepared first by reaction of metal salts with citrate acid and ethylene glycol. Fluorite crystalline YDC powders were obtained by calcining the precursor at $750^{\circ}C$ for 3 h. The electrospray deposited films prepared at the optimum conditions became dense and defect-free after heat treatment at $1400^{\circ}C$ for 3 h. The film thickness was linearly varied with the deposition time.

Preparation of Crack-free ZIF-7 Thin Films by Electrospray Deposition (정전분무법에 의한 결함없는 ZIF-7 박막의 제조)

  • Melgar, Victor Manuel Aceituno;Kim, Jinsoo
    • Membrane Journal
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    • v.23 no.4
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    • pp.278-282
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    • 2013
  • Zeolitic imidazolate frameworks (ZIFs) have been the focus of interest for their physical and chemical properties, especially, for their extraordinary gas separation properties. In this study, a novel and efficient method for the fabrication of continuous ZIF-7 film on ${\alpha}$-alumina substrate has been investigated. The electrospray deposition method was tried for the first time to prepare ZIF films directly without the necessity of prior substrate seeding. It has the advantage of depositing thin ZIF-7 films directly on the ${\alpha}$-alumina substrate by electrospraying the precursor solution. The ZIF-7 films have been characterized through XRD, FE-SEM, and single gas permeation tests.