• Title/Summary/Keyword: Densimeter

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Excess Molar Enthalpies and Excess Molar Volumes for the Binary Mixtures {1,2-dichloropropane+2-(2-methoxyethoxy)ethanol, and +2-(2-ethoxyethoxy)ethanol} at 298.15 K (2성분계 {1,2-dichloropropane+2-(2-methoxyethoxy)ethanol 및 + 2-(2-ethoxyethoxy)ethanol}에 대한 298.15 K에서의 과잉몰엔탈피 및 과잉몰부피)

  • Kim, Jaewon;Kim, Moongab
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.444-452
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    • 2006
  • This paper reports experimental excess molar volumes $V^E_m$ using a digital vibrating-tube densimeter and excess molar enthalpies $H^E_m$ by means of an isothermal microcalorimeter with a flow mixing cell for the binary mixtures{1,2-dichloropropane + 2-(2-methoxyethoxy)ethanol} and {1,2-dichloropropane + 2-(2-ethoxyethoxy)ethanol} at 298.15 K under atmospheric pressure. All the $V^E_m$ and $H^E_m$ of the two binary mixtures showed S-shaped forms, being negative for poor and positive for rich 1,2-dichloropropane mole fractions. These show that the excess properties were shown to be negative deviation from ideality due to the strong self-association effect among 2-(2-alkoxyethoxy)ethanol molecules at an early stage of mixing, a relatively high energy then is needed to break hydrogen bonds of 2-(2-alkoxyethoxy)ethanol with an increase ofhalogenated hydrocarbon molecular at high mole fraction of 1,2-dichloropropane. The values of excess molar properties($V^E_m$ and $H^E_m$) were fitted by the Redlich-Kister equation using Nelder-Mead's simplex pattern search method. The Wilson, NRTL, and UNIQUAC models were used to correlate the $H^E_m$ values.

A Memory-based Reasoning Algorithm using Adaptive Recursive Partition Averaging Method (적응형 재귀 분할 평균법을 이용한 메모리기반 추론 알고리즘)

  • 이형일;최학윤
    • Journal of KIISE:Software and Applications
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    • v.31 no.4
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    • pp.478-487
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    • 2004
  • We had proposed the RPA(Recursive Partition Averaging) method in order to improve the storage requirement and classification rate of the Memory Based Reasoning. That algorithm worked not bad in many area, however, the major drawbacks of RPA are it's partitioning condition and the way of extracting major patterns. We propose an adaptive RPA algorithm which uses the FPD(feature-based population densimeter) to stop the ARPA partitioning process and produce, instead of RPA's averaged major pattern, optimizing resulting hyperrectangles. The proposed algorithm required only approximately 40% of memory space that is needed in k-NN classifier, and showed a superior classification performance to the RPA. Also, by reducing the number of stored patterns, it showed an excellent results in terms of classification when we compare it to the k-NN.

Excess Molar Volumes and Enthalpies for 1,2-dichloropropane + 2-methoxyethanol at the Temperature 298.15K. (1,2-dichloropropane(l) - 2-methoxyethanoI(2)계의 과잉 몰 부피 및 과잉 몰 엔탈피의 측정)

  • Kim, Moon-Gab;Lee, Young-Sei
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.2
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    • pp.193-198
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    • 2001
  • 2성분계 혼합물(1,2-dichloropropane + 2-methoxyethanol)에 대해 과잉몰 부피(excess molar volumes) $V^E$ 및 과잉 몰엔탈피(excess molar enthalpies) $H^E$를 298.15K에서 측정하였다. 혼합물의 밀도측정은 digital vibrating tube densimeter를 이용하였고, 과잉 몰엔탈피는 isothermal flow microcalorimeter를 이용하였다. 측정한 과잉 몰부피는 전 조성 영역에서 양의 편차를 나타내었으며, 과잉 몰엔탈피는 S 자형용 보였다. 또한 얻어진 data는 Nelder- Mead의 simplex method를 이용하여 Redlich-Kister 다항식에 접합 (fitting)하였다.

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A Study on Comparison of Density Test Methods for Quality Control of Cement and Mineral Admixture (시멘트 및 혼화재의 품질관리를 위한 밀도 시험방법 비교 연구)

  • Jae-Seung, Lee;Sang-Kyun, Noh;Cheol, Park;Hong-Chul, Shin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.435-442
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    • 2022
  • In this study, the density of KS L 5110 was compared with that of gas pycnometer and electronic densimeter for efficient density management of cement, blast furnace slag powder and fly ash. Correlation and usability according to the test method were reviewed, and based on the results of the experiment, the availability of alternative test methods was analyzed. As a result of the density test according to test methods, the density of cement, blast furnace slag powder and fly ash tended to decrease in the order of gas pycnometer, KS L 5110 and electronic densimeter. Because the volume range of the sample to be evaluated is different depending on test methods. The coefficient of determination R2 was in the range of 0.71 to 0.93, and the correlation according to test methods showed a relatively good correlation. If correction is applied through correlation, it is analyzed that alternative test methods can be used. As a result of the usability review considering the test procedure, measurement time and coefficient of variation, the gas pycnometer had the simplest test procedure and good reliability. In addition, it is expected that the reproducibility between the testers is relatively high because the skill is not greatly required.

An Experimental Study on Correlation between Oil Discharge and Various Operating Conditions of a CO2 Compressor (CO2 압축기의 운전조건과 오일토출의 상관분석에 관한 실험적 연구)

  • Lee, Ik-Soo;Kang, Byung-Ha
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.1
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    • pp.73-79
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    • 2011
  • A portion of oil for lubrication of compressor flows together with refrigerant in the refrigeration system. If the oil discharge from a compressor is increased in the refrigeration system, not only pressure drop is increased in other components, such as evaporator and gas cooler, but also heat transfer coefficient in the heat exchangers is decreased. Oil discharge rate from a compressor may strongly depend on operating conditions of a compressor. In this study, one stage single rotary compressor is employed for measuring oil circulation ratio(OCR). Carbon dioxide and PAG oil are used as refrigerant and lubricant. Using a U-tube densimeter, mixture density is measured. Oil circulation ratio(OCR) can be estimated by measured mixture density. The results obtained indicate that the oil circulation ratio(OCR) is increased as the suction temperature or compressor operating frequency is increased. Oil circulation ratio(OCR) correlation of the compressor is also suggested.

Effect of Suction Temperature and Compressor Frequency on Oil Circulation Ratio in a $CO_2$ Refrigeration System ($CO_2$ 냉동시스템에서 압축기의 흡입온도와 운전주파수가 오일 순환량에 미치는 영향)

  • Kim, Kyung-Jae;Lee, Ik-Soo;Kang, Byung-Ha;Kim, Suk-Hyun
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.893-898
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    • 2009
  • The quantity of discharged oil from a compressor is one of the most important issues for proper operation of refrigeration system. If the oil is increased in the system not only pressure drop is increased in other components, such as evaporator and gas cooler but also heat transfer coefficient in the heat exchangers is decreased. In addition, the lack of oil in the compressor may cause a critical of the system failure. In this study, one stage single rotary compressor is used for measuring oil circulation ratio(OCR). Carbon dioxide and PAG oil are used as refrigerant and lubricant. Using a U-tube densimeter, mixture density is measured. Characteristics of oil circulation ratio have been investigated for $CO_2$ rotary compressor in the range of operation frequency 45 Hz to 63 Hz and the suction temperature range of $0^{\circ}C$ to $15^{\circ}C$. The results obtained indicate that the oil circulation ratio is increased as the suction temperature or compressor operating frequency is increased.

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Type of Solution and the Effects of Temperature Change in a Rapid Appraisal of Cement Fineness with a Liquid Densimeter (액체밀도계에 의한 시멘트의 분말도 신속평가에서 용액 종류 및 온도변화의 영향)

  • Lee, Jae-Jin;Kim, Min-Sang;Moon, Byeong-Yong;Kim, Yeong-Tae;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.167-168
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    • 2017
  • With the recent increase in demand for construction there has been an increase in the use of the raw material cement when mixing concrete; managing quality of cement powder, therefore, is most important. Therefore this study sought at first to develop a rapid appraisal using the Hydrometer method researched previously, for it was thought that when suspending cement in a solution and applying the Hydrometer method to it the temperature changes in the solution would have a great effect on the density value of the Hydrometer method; yet there has been no report of such influence factors. Therefore after analyzing the influence factors that the type of suspending solution and changes in temperature could have on rapid appraisal of fineness, using the Hydrometer method, this study was able to determine that using water at 20℃ was the most appropriate, and with every temperature increase of 10℃ the value of fineness should also be increased above or below 7% as well.

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An Optimizing Hyperrectangle method for Nearest Hyperrectangle Learning (초월평면 최적화를 이용한 최근접 초월평면 학습법의 성능 향상 방법)

  • Lee, Hyeong-Il
    • Journal of the Korean Institute of Intelligent Systems
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    • v.13 no.3
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    • pp.328-333
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    • 2003
  • NGE (Nested Generalized Exemplars) proposed by Salzberg improved the storage requirement and classification rate of the Memory Based Reasoning. It constructs hyperrectangles during training and performs classification tasks. It worked not bad in many area, however, the major drawback of NGE is constructing hyperrectangles because its hyperrectangle is extended so as to cover the error data and the way of maintaining the feature weight vector. We proposed the OH (Optimizing Hyperrectangle) algorithm which use the feature weight vectors and the ED(Exemplar Densimeter) to optimize resulting Hyperrectangles. The proposed algorithm, as well as the EACH, required only approximately 40% of memory space that is needed in k-NN classifier, and showed a superior classification performance to the EACH. Also, by reducing the number of stored patterns, it showed excellent results in terms of classification when we compare it to the k-NN and the EACH.

A novel barium oxide-based Iraqi sand glass to attenuate the low gamma-ray energies: Fabrication, mechanical, and radiation protection capacity evaluation

  • Al-Saeedi, F.H.F.;Sayyed, M.I.;Kapustin, F.L.;Al-Ghamdi, Hanan;Kolobkova, E.V.;Tashlykov, O.L.;Almuqrin, Aljawhara H.;Mahmoud, K.A.
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.3051-3058
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    • 2022
  • In the present work, untreated Iraqi sand with grain sizes varied between 100 and 200 ㎛ was used to produce a colored glass sample that has shielding features against the low gamma-ray energy. Therefore, a weight of 70-60 wt % sand was mixed with 9-14 wt% B2O3, 8-10 wt% Na2O, 4-6 wt% of CaO, 3-6 wt% Al2O3, in addition to 0.3% of Co2O3. After melting and annealing the glass sample, the X-ray diffraction spectrometry was applied to affirm the amorphous phase of the fabricated glass samples. Moreover, the X-ray dispersive energy spectrometry was used to measure the chemical composition, and the MH-300A densimeter was applied to measure the fabricated sample's density. The Makishima-Makinzie model was applied to predict the mechanical properties of the fabricated glass. Besides, the Monte Carlo simulation was used to estimate the fabricated glass sample's radiation shielding capacity in the low-energy region between 22.1 and 160.6 keV. Therefore, the simulated linear attenuation coefficient changed between 10.725 and 0.484 cm-1, raising the gamma-ray energy between 22.1 and 160.6 keV. Also, other shielding parameters such as a half-value layer, pure lead equivalent thickness, and buildup factors were calculated.

Measurement and Correlation of Densities and Excess Volumes for Water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP and Water + MDEA +AMP systems (Water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP, Water+ MDEA + AMP 계의 밀도와 과잉부피 측정 및 상관)

  • Na, Jaeseok;Min, Byoung-Moo;Park, Young Cheol;Moon, Jong-Ho;Chun, Dong Hyuk;Lee, Jong-Seop;Shin, Hun Yong
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.204-211
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    • 2018
  • In this study, densities of water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP binary systems and Water+MDEA+AMP ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube densimeter (DMA4500). The experimental excess volumes have been obtained from the experimental density results and have been fitted using the Redlich-Kister-Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.