• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 1999.04b
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• pp.343-348
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• 1999

Presence of small amount of old newspapers printed with waterbased flexographic inks leads to a significant loss of brightness of the deinked pulp by flotation process. Recently there has been an increased interests in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. Effects of the deinking processes on pulp quality and white water characteristics were examined. It was shown that neutral deinking would provide significant improvement in brightness, yield, and freeness as compared with conventional alkaline deinking. Three was no increase change in brightness when OMG was added in the furnish up to 20%, and it was attributed to the redeposition of flexo inks on chemical pulp fibers.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.40 no.2
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• pp.16-22
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• 2008

The pilot scale ultrasonic deinking was carried out in order to confirm the commercialization possibility of ultrasonic deinking. White ledger was used as a raw material and the results were compared to the results obtained from the conventional deinking. The fraction of smaller ink particle was increased and the improved ink removal efficiency was also obtained by the ultrasonic treatment. The brightness and breaking length of ultrasonic deinked pulp were superior to those of the conventional deinked pulp. Most interesting findings in this study were that the significant improvement in effluent quality and the reduction of chemicals and energy cost were obtained by the ultrasonic deinking.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.11a
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• pp.9-14
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• 2006

Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently. This paper presents an overview of ONP deinking efficiency with cellulolytic enzymes and synthetic collector in low alkalinity process. The deinking efficiency of old news print even in low alkalinity condition was enhanced with enzyme contained complex agent. The brightness of deinked pulp was increased with less residual ink particles and yield of deinked pulp was improved compared to the deinked pulp of conventional alkaline method.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.4
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• pp.34-41
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• 2003

The effect of wettability of deinking agents which formed with various nonionic surfactants against the pulp fibers and ink particles were studied, And the effect of flotation processes on the deinking were also investigated. The wettabilities of the deinking agents against the water and ink particles were measured by Washburn tube and sessile drop techniques, respectively. As the water absorption increased (i.e., hydrophilicity increased), the ink removal increased, which indicates that the ink removal is strongly affected by the detachment process due to the swelling of the pulp. Also, when the contact angle of air/ink/deinking agent increased, the hydrophobicity of the ink particles increased, the efficiency of the ink removal and the brightness increased.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.3
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• pp.24-28
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• 2001

The utilization of wastepaper as a papermaking raw material is everlastingly required for the environmental protection of earth. However the recycling of wastepaper for this purpose cause another problem such as the increasing of the load of wastewater treatment, lower strength properties of paper, and poor printability, etc. The interest in the development of the environmentally friendly deinking technology is increased continuously. Thus, our research team have tried to apply the ozone to the deinking of white ledger and ONP, and obtained the positive results which can be considered as an alternative method for the conventional deinking method. The purpose of this study is to investigate the mechanism of ozone deinking. Styrene acrylate and polystyrene were treated with ozone and measured the change of molecular weight with the GPC. The molecular weight distribution obtained with GPC showed only slight increase by the ozone treatment, and gel formation by the polymerization was observed. Therefore the removal of ink particles with ozone treatment seems to be facilitated by the increase of the brittleness and decrease of adhesive property.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.3
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• pp.18-23
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• 2001

The effect of pulp consistency on the deinking properties in the ozone deinking of ONP was investigated in order to develop the environmentally friendly deinking method. The pulp consistency and ozone treatment time were varied for this purpose. Higher pulp consistency during ozone treatment gave better ink removal efficiency than the conventional deinking method. In was also found that the increase of pulp consistency can decrease the ozone treatment time which can meet the deinking quality. WRV of ozone deinked pulp obtained at 10% and 30% of pulp consistencies was lower than those of the conventional deinking method. However, the higher pulp consistency during ozone treatment improved WRV. Highest brightness was obtained at the ozone treatment condition of 30% pulp consistency and 10 minutes. The lower brightness at the other ozone treatment condition should be originated from the excessive decrease of ink particle size and then decrease of true ink removal efficiency. Scott bond was increased with the increase of pulp consistency and treatment time. However, the improvement of breaking length with ozone treatment was no significant.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.10a
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• pp.39-41
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• 2011

The recycling rate of recovered paper in Korea is the highest in the world, 92%, but remanufacturing yield is low due to the extremely poor quality of the paper. The poor quality, in turn, influences to the reject amount in deinking process. To increase the yield of old newspaper recycling process, hydrophobic degree of inorganic pigments of deinking stock must be reduced. To determine the hydrophobicity, Pitch Potential Deposit Tester (PDT) was newly designed and applied with respect to the SB latex property of various quality used in Korea; its hydrophobic degree according to Tg, gel content, charge and particle size of latex and optimum designing condition of SB latex. And below are the conclusions: 1. The reason of excessive reject from old newspaper deinking process for total amount of printed ink is loss of inorganic pigments. When lipase, a biochemical catalyst, was applied with the purpose of preventing inorganic pigments loss about more than 70% of total reject weight and promoting hydration of pulp for deinking, deinking process yield of pre flotation secondary stage increased remarkably without any changes of deinking efficiency. 2. Lipase improved deinking stock by cutting ester linkage on surface of hydrophobic materials to promote its hydration. From this, it reached the conclusion that hydration degree of stock exercises significant effect on flotation deinking process yield. 3. Inorganic alkali promotes hydration of deinking stock. But there have been needs for more fundamental measures other than inorganic alkali of promoting hydration for yield improvement. For this, this study intended to find out reasons of chemical properties change on surface of hydrophobic material by change of pH. 4. Pitch Deposit Test (PDT) was performed for understanding principle of why surface of coating flake from OMG is hydrophobic and why it becomes hydrophilic when pH of stock is alkaline. As a result of this test, it is determined that swelling property by change of pH of latex film, which were used as coating adhesive is the reason for hydrophobic change. 5. Hydrophilicity of coating flake increased with hydrophilic pigments. And as more of SB Latex adhesive was used and higher of calcium hardness of stock became, its hydrophilicity decreased. SB Latex adhesive film is reformed by mechanical friction. For having hydrophilicity under neutral pH, strong bruising action such as kneading is required. 6. Because swelling of adhesive film decreases as Tg of SB latex gets lower and mean diameter gets smaller, it shows hydrophobicity under neutral pH. This lowers hydrophilicity of coating flake, which leads to easy elimination with flotation reject on DIP process. Therefore, for improving future flotation yield, it is necessary to develop to use eco-friendly clean SB latex by raising Tg and increasing mean diameter for recycling, and as a result, to reduce excessive loss of coating flake as a reject from deinking process.

• Current Research on Agriculture and Life Sciences
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• v.22
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• pp.49-56
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• 2004

Cellulolytic enzymes were prepared from alkaline resistant microorganisms which were newly screened from calcic soil. Characteristics of enzymes and enzymatic deinking efficiency of wastepaper were investigated. The results were summarized as fellows: 1. The recovery rate of crude enzyme was 93.7% in Bio-B and 57.4% in Bio-F. 2. The protein content in crude enzymes was lowest and the thermal stability of crude enzymes was highest in Bio-F. 3. The brightness gain of Bio-F deinked pulp was best in ONP and Bio-B deinked pulp was best in MOW. 4. The reject yield was increased with enzymatic deinking flotation process. 5. The residual ink area of paper was increased with enzymatic deinking and large size of ink particles were remained in paper.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.32 no.1
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• pp.41-47
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• 2000

The objective of this study is to assess the possibility of ozone as an environmentally friendly new deinking alternative for conventional deinking method. It is well known that the white ledger is very difficult to deink because the toner ink has the peculiar shape and size. Ozonization could remove the ink particles above 300 microns and thus improved the ink removal efficiency. Ozonization also improved the WRV of recycled fiber and apparent density, scott bond strength , breaking length, double fold and tear index. Thus, we believe that ozonization could be used as a deinking means of white ledger instead of the convention미 deinking method.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06a
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• pp.123-128
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• 2006

Enzymatic deinking method can avoids the alkaline environment as usual required in chemical deinking, which consequently cuts chemical costs and reduced the white water pollution. The electrostatic wastepaper was dinked with commercial cellulolytic enzymes and surfactant in neutral pH and the effectiveness of deinking and the physical properties of deinked pulp were evaluated. The disintegrating efficiency of the electrostatic wastepaper in neutral pH was enhanced with enzyme treatments. Although the freeness of deinked pulp with enzymes was higher than that of deinked pulp with chemical deinking agents, the brightness of the enzymatic deinked pulp was slightly lower than that of the chemical deinked pulp. But, by additions of nonionic surfactants, the brightness of deinked pulp was increased with less residual ink particles and mechanical properties of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method.