• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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• pp.203-204
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• 2016

In this research, it used cement power and reduction slag, which generates high hydration heat in hydration reation without heat cure below -5℃ degree. Purpose of final research is preventing freezing and thawing by making the compressive strength 5MPa in 3days below zero temperature due to own heat of concrete. and it is the result of physical characteristic and thermal property evaluation of reduction slag. Because reduction sag generates high hydration heat, compressive strength development is excellent. By generating highly Hydration heat by C₁₂A₇ and C₃A in reduction slag, compressive strength is developed in low temperature. In case of displacing only reduction slag without SO₃, it is indicated that quick-setting occurs by shortage of SO₃. For preventing quick-setting, gypsum is used essentially. According to this research result, in case of using reduction slag and gypsum as a ternary system, Compressive strength developed 5MPa in 3days below zero temperature. It is identified to prevent early frost damage of concrete below zero temperature.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.397-402
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• 2001

Microstructural characteristics such as hydrates and porosity greatly influence the development of concrete strength. In this study, a strength estimation model for early-age concrete considerig, the microstructural characteristics was proposed, which considers the effects of both an increment of degree of hydration and capillary porosity on a strength increment. Hydration modeling and compressive strength test with curing temperature and curing ages were carried out. By comparing test results with estimated strength, it is found that the strength estimation model can estimate compressive strength of early-age concrete with curing ages and curing temperature within a margin of error.

• 한국세라믹학회지
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• 제40권9호
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• pp.827-831
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• 2003

In proton-conducting perovskites, oxygen ions and protons make a diffusion pair for a chemical diffusion and thus lead to the transport of $H_2O$ under its chemical potential gradient. The present manuscript develops relationships between the chemical diffusion coefficient of $H_2O$ and the diffusion coefficients of protons and oxygen vacancies with an emphasis on the thermodynamic behavior of the oxygen vacancies. Depending on the degree of hydration X, two different expressions of the chemical diffusion coefficient were obtained : equation omitted and equation omitted.

• Bulletin of the Korean Chemical Society
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• 제18권4호
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• pp.450-453
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• 1997

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 봄 학술발표회 논문집
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• pp.422-429
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• 1997

Thermal stress induced by hydration heat may produce cracks in mass concrete structure, which can result in structural problems as well as bad appearance. To minimize crack occurrence in massive structural, thus, the study put an emphasis on the determination of optimized lift height and block size. In the parametric study different sizes and lift heights were used to measure the magnitudes of hydration heat and thermal stresses for 3 different types of concrete fabricated with 1 pure cement and 2 blended Portland cements. As a result of analysis. it was found that magnitude of hydration heat and the occurrence of thermal cracks depend on the restriction conditions and material characteristics, especially adiabatic material parameters. It was also found that optimized lift height and block size can be determined from an appropriate combination of the degree of inner and outer structural restrictions.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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• pp.465-466
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• 2010

In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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• pp.221-222
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• 2009

지연은 일반적으로 알려진 점도 상승에 의한 $Ca^{2+}$이온의 확산 지연에 의한 영향도 있지만 폴리머의 보호 콜로이드인 폴리 비닐 알코올의 가수분해에 의해 생성된 아세테이트 기가 $Ca^{2+}$이온과 반응하여 칼슘 아세테이트를 생성함으로 인한 $Ca^{2+}$이온의 소모에 의해 수화지연이 나타날 수도 있다는 것을 확인하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2012년도 춘계 학술논문 발표대회
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• pp.245-246
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• 2012

The analysis of microstructure is essential to understand the material behavior such as shrinkage, strength, and permeability. In this study, three different easy-to-apply specimen preparation methods for the mercury intrusion analysis were chosen, and their effectiveness in removing pore water and thus impeding further hydration was evaluated. As a result, it was found that the direct freeze-drying was the most effective among the three methods.

• 한국세라믹학회지
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• 제52권1호
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• pp.28-32
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• 2015

In this article, the influence of a hydrolyzed wheat protein retarder on the hydration process, ion concentration in liquid phase, degree of supersaturation, and crystal morphology of plaster was investigated. Furthermore, the retarding mechanism and the strength loss of gypsum were also studied by scanning electron microscopy (SEM). The results indicate that the use of the hydrolyzed wheat protein retarder for plaster achieved a better retarding effect and lower strength loss. The combination of gypsum plaster with the retarder not only decreased the plaster's early hydration rate and prolonged its setting time efficiently, but also militated against the crystal morphology of dihydrate gypsum. For example, the crystal dimensions changed little, but the proportion of needle-shaped crystals decreased. Combination with calcium ions on the surface of dihydrate gypsum crystal nuclei may form a chemisorbed layer, reduce the surface energy of the crystal nuclei, and inhibit the growth of the crystal nuclei of dihydrate gypsum. Consequently, the hydration process of building gypsum becomes greatly extended and is slowed down significantly.

• 한국세라믹학회지
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• 제39권10호
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• pp.943-947
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• 2002

Chlorine을 다량으로 함유하고 있는 산업 폐부산물의 시멘트 키른을 이용한 소각 가능성을 검토하고자 OPC에 KCl을 함량별로 첨가하여 수화발열, 응결시간, 유동성, 길이변화 및 몰탈 압축강도를 측정하였다. 실험결과 KCl를 첨가함에 따라 수화가 촉진되어 유도기가 짧아짐으로써 응결시간이 짧아지고 유동성이 하락하며 초기수축이 커지고 3일 이전의 초기 압축강도는 상승하나 7일 이후의 후기 압축강도는 크게 하락하였다.