• Bulletin of the Korean Chemical Society
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• v.2 no.4
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• pp.129-132
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• 1981

Polystyrene was degraded by using a vibrating ball mill. The viscosities and molecular weights of the degraded products were measured, and the decrease of viscosity $[\eta}$ with ${\dot{s}}$ (rate of shear) observed for the degraded products were analyzed by applying the Ree-Eyring equation for viscous flow. The variation of the parameters $x_2$/{\alhpa}_2,{\beta}_2$ and $x_1{\beta}_1/{\alpha}_1$ in the equation were explained by the fracture of polymer molecules by mechanical force. The electron paramagnetic resonance spectrum of the degraded sample was taken, and it was confirmed that free radicals were produced by the chain-scission of polystyrene.

• Journal of the Korean Society of Food Science and Nutrition
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• v.28 no.2
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• pp.417-422
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• 1999

Algin and chitosan are known as biodegradable natural polymers. PVA is useful for the production of water soluble packaging, paper, textile sizes. PVA/Algin and PVA/chitosan films were prepared by solution blends method in the weight ratio of chitosan, algin for the purpose of useful biodegradable films. Thermal and mechanical properties of blend films such as DSC, impact strength, tensile strength and morphology by SEM were determined. As a result, The ratio of 10.0wt% PVA/chitosan films were similar to PVA at thermal and mechanical properties. PVA/Algin films were found that phase separation was occured as more than 25wt% increasing the blend ratio of algin. PVA/Algin films were observed to be less partially compatibility than 10wt% increasing the blend ratio of algin by DSC, mechanical properties and SEM. Blend films were completely degraded pH 4.0 better than 7.0, 10.0 in the buffer solution. Also, they were rapidly degraded in the enzyme( glucosidase) solution better than pH solution by enzymolysis.

• Journal of Power System Engineering
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• v.21 no.6
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• pp.21-30
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• 2017

This study deals with the characteristics of degraded stainless steel. Stainless steel is heat treated to ensure mechanical properties when designing or manufacturing machinery parts or equipment. In this study, the mechanical properties and wear characteristics of three kinds of stainless steels after artificially heat-treated at 753 K~993 K, where chrome depletion occurs near the grain boundary, were evaluated. The microstructure and fracture surface were also observed. From the results, friction coefficient and wear loss decreased with increasing the heat treatment temperature regardless of the type of stainless steel. Also, as the tensile strength increased, the friction coefficient and wear loss decreased. Wear loss showed proportional to a tendency to increase with increasing friction coefficient.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2002.05a
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• pp.705-710
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• 2002

Welding is used not only during the shipbuilding, but also during the repairing of ships. While repairing of ships, it is inevitable to weld new materials with degraded materials. In this case, it is predicted that the strength of both the sections is not identical each other. In this study, the respective welded joints in terms of mechanical properties such as microstructure, mechanical strength and fatigue crack propagation, with the component obtained from the barge used for a long-term period, were analyzed. It was found that the material degradation had a significant effect on the welded joints. The fatigue crack propagation in welded sections showed a big difference. The rate of fatigue crack growth of degraded material for both heat affected zone and parent metal was faster than that of new material. By contrast, The result within identical materials showed that the heat-affected zone was slower than that of parent metal

• Journal of the Korean Society for Precision Engineering
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• v.19 no.11
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• pp.75-82
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• 2002

Welding is used not only for the shipbuilding, but also for the repairing of ships. While repairing of ships, it is inevitable to weld new materials with degraded materials. In this case, it is predicted that the strength of both the sections is not identical each other. In this study, the respective welded joints in terms of mechanical properties such as microstructure, mechanical strength and fatigue crack propagation, with the component obtained from the barge used for a long-term period, were analyzed. It was found that the material degradation had a significant effect on the welded joints. The fatigue crack propagation in welded sections showed a big difference. The rate of fatigue crack growth of degraded material for both heat affected zone and parent metal was faster than that of new material. By contrast, the result from identical materials showed that the rate of fatigue crack growth of the heat-affected zone was slower than that of parent metal.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.21 no.9
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• pp.1422-1431
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• 1997

When the structures are exposed to their own an application for a long period, a number of variables such as strength properties and corrosion resistance, so on are expected to change. In the present investigation the corrosion behavior and resistance for the original and degraded materials of Ni-Cr-Mo-V steel were evaluated under the conditions of pH 3, 6, 9 and 12 in a distilled water environment. The electrochemical polarization technique was employed in this investigation. Based upon the experimental results obtained, the following conclusions were drawn. A severe and uniform corrosion was observed for both original and degraded materials under the condition of pH 3. At pH 6 and pH 9, these materials showed the degradation by a pitting corrosion. The materials under pH 12 environment were degraded by a uniform corrosion. The corrosion rate per year were the highest in the pH 3 environment, followed by pH 12, pH 6 and pH 9 environment in order. The corrosion resistance was decreased from the original material, slow cooled material (10.deg. C/hr) and step cooled material in order.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.7 s.178
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• pp.1673-1680
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• 2000

The degradation of a boiler header constructed by a material, 1Cr-0.5Mo steel in a fossil power plant is observed when the header is exposed for a long period to the high temperature and pressure. The present investigations are for evaluating the effect of the degradation on the material, such as its strength changes. Reheat-treated metal is used to compare the mechanical properties of the degraded and that of reheat-treated materials. Through the investigation, following results are obtained 1) the area ratio of ferrite in the reheat-treated material is larger than that of the degraded material, 2) the hardness and tensile strength of the degraded material are lower than that of the reheat-treated material, 3) the ductile-brittle transition temperature(DBTT) increased toward high temperature region, 4) the fatigue crack growth rate(FCGR) of the degraded material is higher than that of the reheat-treated material in the region of low ΔK value while FCGR of the both materials are similar in high ΔK region.

• Journal of the Korean Society for Nondestructive Testing
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• v.30 no.5
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• pp.464-470
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• 2010

The integrity of the industrial equipment in use under high temperature and high pressure must be assessed by regularly measuring the degraded mechanical properties during service time. In order to nondestructively monitor the degraded mechanical properties of industrial equipment, a measuring method of the reversible permeability(RP) using surface type probe is presented. The method for measuring the RP is based on that RP is the differential value of hysteresis loop. The RP is exactly the foundation hatmonics induced in a detecting coil measured by lock-in amplifier tuned to a frequency of the alternating perturbing magnetic field. The peak of RP is measured around the coercive force. Steel material used in this work was 12Cr ferritic heat resisting steel. The eleven kinds of samples aged during different times under same temperature ($700^{\circ}C$) were prepared. Peak interval of reversible permeability(PIRP), Vickers hardness, and tensile strength measured for the aged samples decreased abruptly for short aging time (below 500 h), but the change became small at a long aging time. Vickers hardness and tensile strength linearly decreased as RIRP decreased, so the degraded mechanical properties of 12Cr ferritic heat resisting steel could be nondestructively evaluated by measuring RIRP.

• Corrosion Science and Technology
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• v.3 no.3
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• pp.87-97
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• 2004

This paper presents a new approach with meso scale structure models to express mechanical property, such as stress - strain relationships, of concrete. This approach is successful to represent both uniaxial tension and uniaxial compression stress - strain relationship, which is in macro scale. The meso scale approach is also applied to predict degraded mechanical properties of frost-damaged concrete. The degradation of mechanical properties with frost-damaged concrete was carefully observed. Strength and stiffness in both tension and compression decrease with freezing and thawing cycles (FTC), while stress-free crack opening in tension softening increases. First attempt shows that the numerical simulation can express the experimentally observed degradation by introducing changes in the meso scale structure in concrete, which are assumed based on observed damages in the concrete subjected to FTC. At the end applicability of the meso scale approach to prediction of the degradation by combined effects of salt attack and FTC is discussed. It is shown that clarification of effects of frost damage in concrete on corrosion progress and on crack development in the damaged cover concrete due to corrosion is one of the issues for which the meso scale approach is useful.

• Laser Solutions
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• v.6 no.2
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• pp.19-26
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• 2003

6061 aluminum alloy sheets were I-square butt welded using a continuous wave Nd:YAC laser. Heat inputs were varied from 54.6 to 80 J/mm for butt welding using different sets of the laser power and the weld speed. I-square butt welds were also made with and without Ar shielding gas. The effect of Ar shielding gas and heat input on the mechanical properties and formability was investigated using Vickers hardness, transverse-weld tensile and bulge test. Porosity on the weld beads and sections and hot crack on the fracture surfaces of transverse-weld tensile test specimens were investigated using optical and scanning electron microscopy The experimental results showed that mechanical properties and formability of 6061 aluminum alloy laser welds were degraded compared to those of base metal. Mechanical properties and formability of 6061 aluminum alloy laser welds were not substantially changed when Ar shielding gas was supplied or heat inputs were varied.