• 제목/요약/키워드: Degradation data

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Steam Gasification of Coal and Petroleum Coke in a Thermobalance and a Fluidized Bed Reactor (열천칭과 유동층반응기에서 석탄과 Petroleum Coke의 수증기 가스화반응)

  • Ji, Keunho;Song, Byungho
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1015-1020
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    • 2012
  • Lignite of low rank coal and petroleum coke of high sulfur content can be high potential energy sources for coal gasification process because of their plentiful supply. The steam gasification of lignite, anthracite, and pet coke has been carried out in both an atmospheric thermobalance reactor and a lab-scale fludized bed reactor (0.02 m i.d. ${\times}$ 0.6 m height). The effects of gasification temperature ($600{\sim}900^{\circ}C$) and partial pressure of steam (0.15~0.95 atm) on the gasification rate and on the heating value of product gas have been investigated. The modified volumetric reaction model was applied to the experimental data to describe the behavior of carbon conversion, and to evaluate kinetic parameters of char gasification. The results shows that higher temperature bring more hydrogen in the product syngas, and thus increased gas heating value. The feed rate of steam is needed to be optimized because an excess steam input would lower the gasification temperature which results in a degradation of fuel quality. The rank of calorific value of the product gas was anthracite > lignite > pet coke. Their obtained calorific value at $900^{\circ}C$ with 95% steam feed were 10.0 > 6.9 > 5.7 $MJ/m^3$. This study indicates that lignite and pet coke has a potential in fuel gas production.

Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.190-197
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    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

QoS and Multi-Class Service Provisioning with Distributed Call Admission Control in Wireless ATM Networks (무선 ATM망에서 QoS와 다중 서비스를 지원하는 분산된 호 수락 제어 알고리즘과 성능 분석)

  • Jeong, Da-Ip;Jo, Yeong-Jong
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.37 no.2
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    • pp.45-53
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    • 2000
  • In wireless environment, due to the limited capacity of radio channels it is not easy to guarantee QoS provisioning to mobile users. Therefore, one of the key problems to support broadband multimedia multi-services in wireless ATM networks is to study an effective call admission control(CAC). The purpose of this paper is to propose a distributed CAC scheme that guarantees multi QoS and multi-class service. Control parameters of the proposed scheme are QoS threshold and channel overload probability. With these parameter control, we show that the scheme can guarantee the requested QoS to both new and handover calls. In the scheme, channels are allocated dynamically, and QoS measurements are made in a distributed manner. We show that by providing variable data rate to calls it can effectively prohibit the QoS degradation even if there are severe fluctuations of network traffic. We compare the proposed CAC scheme to the well-known schemes such as guard band call admission control scheme. Through numerical examples and simulations, the proposed scheme is shown to improve the performance by lowering the probability of handover call dropping

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Seismic Performance of Circular RC Bridge Columns with Longitudinal Steel Connection Details (축방향철근 연결상세에 따른 철근콘크리트 원형교각의 내진성능)

  • Lee Jae-Hoon;Son Hyeok-Soo;Ko Seong-Hyun
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.249-260
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    • 2004
  • The longitudinal steel connection of reinforced concrete bridge column is sometimes practically unavoidable, however the current Korean bridge design specifications have no special provisions about lap-splices of longitudinal steel. This paper reports experimental results of a research program investigating the seismic performance of circular RC bridge columns with respect to longitudinal steel connection detailing. Twenty-one circular column specimens were tested under quasi-static test. The columns with the entire longitudinal steel lap-spliced within plastic hinge region show relatively sudden strength degradation and low ductility than the columns with continuous longitudinal steel and the columns with half of longitudinal steel lap-spliced. However, the seismic performance of the column with mechanically connected longitudinal steel is similar to that of the column with continuous longitudinal steel. The final objectives of this study are to suggest appropriate longitudinal reinforcement connection details for the limited ductility design concept and to provide quantitative reference data and tendency for performance or damage assessment based on the performance levels such as cracking, yielding, collapse, etc. Ultimate displacement/drift ratio, displacement ductility, response modification factor, equivalent viscous damping ratio, residual deformation index, and effective stiffness are investigated and discussed in this paper.

XOR-based High Quality Information Hiding Technique Utilizing Self-Referencing Virtual Parity Bit (자기참조 가상 패리티 비트를 이용한 XOR기반의 고화질 정보은닉 기술)

  • Choi, YongSoo;Kim, HyoungJoong;Lee, DalHo
    • Journal of the Institute of Electronics and Information Engineers
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    • v.49 no.12
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    • pp.156-163
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    • 2012
  • Recently, Information Hiding Technology are becoming increasingly demanding in the field of international security, military and medical image This paper proposes data hiding technique utilizing parity checker for gray level image. many researches have been adopted LSB substitution and XOR operation in the field of steganography for the low complexity, high embedding capacity and high image quality. But, LSB substitution methods are not secure through it's naive mechanism even though it achieves high embedding capacity. Proposed method replaces LSB of each pixel with XOR(between the parity check bit of other 7 MSBs and 1 Secret bit) within one pixel. As a result, stego-image(that is, steganogram) doesn't result in high image degradation. Eavesdropper couldn't easily detect the message embedding. This approach is applying the concept of symmetric-key encryption protocol onto steganography. Furthermore, 1bit of symmetric-key is generated by the self-reference of each pixel. Proposed method provide more 25% embedding rate against existing XOR operation-based methods and show the effect of the reversal rate of LSB about 2% improvement.

Development of Long-Term Electricity Demand Forecasting Model using Sliding Period Learning and Characteristics of Major Districts (주요 지역별 특성과 이동 기간 학습 기법을 활용한 장기 전력수요 예측 모형 개발)

  • Gong, InTaek;Jeong, Dabeen;Bak, Sang-A;Song, Sanghwa;Shin, KwangSup
    • The Journal of Bigdata
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    • v.4 no.1
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    • pp.63-72
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    • 2019
  • For power energy, optimal generation and distribution plans based on accurate demand forecasts are necessary because it is not recoverable after they have been delivered to users through power generation and transmission processes. Failure to predict power demand can cause various social and economic problems, such as a massive power outage in September 2011. In previous studies on forecasting power demand, ARIMA, neural network models, and other methods were developed. However, limitations such as the use of the national average ambient air temperature and the application of uniform criteria to distinguish seasonality are causing distortion of data or performance degradation of the predictive model. In order to improve the performance of the power demand prediction model, we divided Korea into five major regions, and the power demand prediction model of the linear regression model and the neural network model were developed, reflecting seasonal characteristics through regional characteristics and migration period learning techniques. With the proposed approach, it seems possible to forecast the future demand in short term as well as in long term. Also, it is possible to consider various events and exceptional cases during a certain period.

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Influence of Dry Roasting of Whole Faba Beans (Vicia faba) and Whole Lupin Seeds (Lupinus albus) on Rumen Disappearance and Estimated Intestinal Digestion of CP Using the Optimal Three-Step In Vitro Technique in Dairy Cows

  • Yn, P.;Egan, A.R.;Lenry, B.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.7
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    • pp.1054-1062
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    • 1999
  • The effects of dry roasting whole faba beans (WFB) and whole lupin seeds (WLS) at 110, 130 or $150{^{\circ}C}$ for 15, 30 or 45 min on rumen (RDCP%), estimated intestinal (IDCP%) and total tract disappearance of CP (TDCP%) and intestinal availability (IARUCP%) of rumen undegraded CP (RUCP%) were determined. The RDCP values were estimated by in sacco technique by incubating nylon bags for 8, 12 and 24 h in the rumen of dairy cows. The IDCP and IARUCP values were estimated using a sequence of ruminal incubation, in vitro incubation in acid-pepsin for 1 h and then in pancreatin for 24 h of three-step in vitro procedure technique. Dry roasting at 130 and $150^{\circ}C$ decreased RDCP with correspondingly increasing IDCP. The IDCP value generally increased from 12.3(raw) to 8.6, 14.8 and 39.6% (WFB) and from 28.3 (raw) to 33.7, 36.2 and 56.2% (WLS) at 8 h rumen incubation; from 2.9 (raw) to 2.9, 4.6 and 23.3% (WFB) and from 19.6 (raw) to 19.0, 24.0 and 46.6% (WLS) at 12 h rumen incubation; from 1.3 (raw) to 1.9, 1.7 and 11.0% (WFB) and from 4.4 (raw) to 4.2, 10.7 and 36.7% (WLS) at 12 h rumen incubation as the temperatures rose to 110, 130 and $150{^{\circ}C}$ respectively. The TDCP values were always high and increased by time in the rumen, the average values of which were 97.9, 96.6; 99.2, 96.9 and 99.6, 98.7% for WFB and WLS, respectively, at 8, 12 and 24 h rumen incubation. But within the same retention time, TDCP was generally unchanged. The average IARUCP increased from 87.3 (raw) to 87.4, 88.7 and 92.0% (WFB); from 87.6 (raw) to 88.9, 91.5 and 93.0% (WLS) at roasting temperatures of 110, 130 and $150{^{\circ}C}$, respectively. It was concluded that dry roasting can shift the digestion of CP from rumen to the lower gastrointestinal tract without depressing the digestion of RUCP. The best processing condition in this study was dry roasting at $150{^{\circ}C}$ for 45 min in terms of effects on the disappearances and availability of CP. Research data on intestinal availability of individual amino acids need to be further investigated.

Synthesis and Micellar Characterization of CBABC Type PLGA-PEO-PPO-PEO-PLGA Pentablock Copolymers

  • Seong, Haseob;Cho, Eun-Bum;Oh, Joongseok;Chang, Taihyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2342-2348
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    • 2014
  • Poly(lactic-co-glycolic acid) (PLGA) were grafted to both ends of Pluronic$^{(R)}$ F68 ($(EO)_{75}(PO)_{30}(EO)_{75}$) triblock copolymer to produce poly{(lactic acid)$_m$-co-(glycolic acid)$_n$}-b-poly(ethylene oxide)$_{75}$-b-poly(propylene oxide)$_{30}$-b-poly(ethylene oxide)$_{75}$-b-poly{(lactic acid)$_m$-co-(glycolic acid)$_n$} (PLGA-F68-PLGA) pentablock copolymers. Molecular weights of PLGA blocks were controlled and five kinds of pentablock copolymers with different PLGA block lengths were synthesized using in-situ ring-opening polymerization of D,L-lactide and glycolide with tin(II) 2-ethylhexanoate ($Sn(Oct)_2$) catalyst. PLGA-F68-PLGA pentablock copolymers were characterized by $^1H$- and $^{13}C$-NMR, GPC, and TGA. The numbers (2m, 2n) of repeating units for lactic acid and glycolic acid inside PLGA segments were obtained as (48, 17), (90, 23), (125, 40), (180, 59), and (246, 64), with $^1H$-NMR measurement. From NMR data, the resultant molecular weights were determined in the range of 12,700-29,700, which were similar to those obtained from GPC. Polydispersity index was increased in the range of 1.32-1.91 as the content of PLGA blocks increased. TG and DTG thermograms showed discrete degradation traces for PLGA and F68 blocks, which indicate the weight fractions of PLGA blocks in pentablock copolymers can be calculated by TG profile and it is possible to remove PLGA block selectively. Hydrodynamic radius and radius of gyration of pentablock copolymer micelle were obtained in the range of 46-68 nm and 31-49 nm, respectively, in very dilute (i.e. 0.005 wt %) aqueous solution of THF:$H_2O$ = 10:90 by volume at $25^{\circ}C$.

3D Shape Embodiment of Dam using the 3D Laser Scanning System (3차원 레이저 스케닝 시스템을 이용한 댐체의 3차원 형상구현)

  • Shon, Ho-Woong;Yun, Bu-yeol;Park, Dong-il;Pyo, Ki-Won
    • Journal of the Korean Geophysical Society
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    • v.9 no.4
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    • pp.377-386
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    • 2006
  • There is an inseparable relation between human race and engineering work. As world developed into highly industrialized society, a diversity of large structures is being built up correspondently to limited topographical circumstance. Though large structures are national establishments which provide us with convenience of life, there are some disastrous possibilities which were never predicted such as ground subsidence and degradation. It is very difficult to analyze the volume of total metamorphosis with the relative displacement measurement system which is now used and it is impossible to know whether there is structural metamorphosis within a permissible range of design or not. In this research with an object of 13-year-old earthen dam, through generating point-cloud which has 3D spatial coordinates(x, y, z) of this dam by means of 3D Laser Scanning, we can get real configuration data of slanting surface of this dam with this method of getting a number of 3D spatial coordinates(x, y, z). It gives 3D spatial model to us and we can get various information of this dam such as the distance of slanting surface of dam, dimensions and cubic volume. It can be made full use of as important source material of reinforcement and maintenance works to detect previously the bulging of the dam through this research.

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Nonlinear Modeling of RC Shear Walls Using Fiber and Shear Spring Elements (전단스프링과 섬유요소를 이용한 철근콘크리트 전단벽의 비선형 해석모델에 관한 연구)

  • Lee, Kwang-Ho;You, Tae-Sang;Kim, Tae-Wan;Jeong, Seong-Hoon
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.559-566
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    • 2012
  • In this study, fiber elements and a spring are used to build a reinforced concrete shear wall model. The fiber elements and the spring reflect flexural and shear behaviors of the shear wall, respectively. The fiber elements are built by inputting section data and material properties. The spring parameters representing strength and stiffness degradation, pinching, and slip were determined by comparing behaviors of fiber element and VecTor2 results. 'Pinching4' model in OpenSees is used for shear spring. The parameter selecting process for shear spring is a complicated and time consuming process. To study the applicability of the fiber element, reinforced concrete buildings containing a shear wall are evaluated using nonlinear dynamic analysis with various wall aspect ratio (H/L), various beam heights, and stiffness and flexural strength of beam and wall ratios. The aspect ratio of the wall showed distinct difference in IDR (interstory drift ratio) of the models with and without spring. On the other hand, the height of beam and ratio of stiffness and flexural strength of beam and wall did not show clear relation.