• 분석과학
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• 제6권2호
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• pp.231-238
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• 1993

적층 액츄에이터에서 바인더의 열적 거동이 액츄에이터의 물성을 좌우하므로 압전-전왜 재료로서 우수한 PNN-PZT/Acrylic binder의 혼합물에서 고분자 열분해 메카니즘과 결합제 번아웃 공정에 영향을 끼치는 요소들을 FTIR, DSC, TGA와 같은 분석기기를 통하여 분석하였다. 결합제는 2단계를 거쳐 번아웃이 되며, 산소 분위기일 경우 열분해가 활발해져서 최종 잔유물이 5% 내외로 최소화되므로 물성이 좋은 액츄에이터를 얻을 수 있다.

• 한국세라믹학회지
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• 제29권10호
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• pp.806-814
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• 1992

The aim of this study was to investigate the change in compressive strength, freacture behavior and degradation of piezoelectric properties with compressive cyclic loading in Pb(Zr, Ti)O3 of tetragonal, morphotropic phase boundary and rhombohedral composition. The highest compressive strength was found in rhombohedral composition. After poling treatment the strength increased by 8.4% and 6.5% in tetragonal and morphotropic phase boundary compositions respectively while changed little in rhombohedral. The increase of compressive strength after poling treatment is believed to be due to the internal stress around grain boundary by domain alginment toward electric field direction in the microstructures having tetragonality and the occurrence of domain switching to the direction perpendicular to electrical field during fracture. Fracture mode relatively change from transgranular to intergranular was observed in the large grain sized tetragonal and morphotropic phase boundary compositions before and after poling but the transgranular fracture mode always remained in the rhombohedral composition. From the X-ray diffractometer analysis the domains parallel to the electric field direction is known to undergo rearrangement during the cyclic loading into random direction that is responsible for the degradation of piezoelectric property.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.43-47
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• 2002

Weight loss experiments have been performed for unidirectional carbon fiber/epoxy laminates under both isothermal and cyclic thermal conditions. It was found that weight losses were the result of both specimen-geometry dependent oxidative degradation and volumetric geometry dependent thermal degradation. Thermal degradation was found to play a major role in the overall weight loss process, and photomicrographs of cross-sectioned, aged specimens confirmed this fact. A method to predict the effect of isothermal environment on the weight loss was introduced and found to be in good agreement with experimental data at temperatures near Tg (glass transition temperature).

• 대한기계학회논문집A
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• 제20권12호
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• pp.3847-3855
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• 1996

In order to study the relationship between static and cynamic behaviors of silion caride, both quasi-static indentaiton and impact experiments of spherical particle have been conducted. The difference inmaterial behavior when using the two mehtods suggests a loading rate difference in the damate pattrern and fracture strength of silicon carbide. This investigation showed some difference in damage pattern according to particla property, especially inthe case of particle impact. There was no differences in deformation behaviors according to the loading rate when the crater profiles were compared with each other at the same contact radius. From the result of residual strength evaluation, it was found that the strength degradation began at the initiation of ring crack and its behavior was colsely related to morphologies of the damage developed which was also dependent upon the extent of deformation atthe loaidng point. In the case of static indentation, there didnot exist the particle property effects onthe strength degradation behavior.

• 설비공학논문집
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• 제13권3호
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• pp.194-199
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• 2001

The turbulent flow resistance of water solution with polymer is reduced as compared with that of pure water. This effects is named th drag reduction and offers the significant reduction of the pumping power and the energy consumption. But the intense shear forces and the high temperature experienced by the polymer solution when passing through the pipes cause the degradation a loss of drag reduction effectiveness. Especially, the degradation behavior is found to be strongly dependent on temperature. This mechanical and thermal degradation can be avoided by adding materials such as surfactant to the polymer solution, which enhance the bonding force between molecules. In the present study, Copolymer and SDS were utilized and they were mixed in 10 different mixture ratios, while total concentration was fixed as 100wppm. Degradation of Copolymer-SDS mixture solutions was investigated experimentally in closed loop at the temperature of $10^{\circ}C\; and\; 80^{\circ}C$ with various flow average velocities of 1.5 m/sec, 3.0m/sec, and 4.5m/sec. Degradation characteristics of polymer solution without surfactant show a radical loss of drag reduction effectiveness at high temperature. Degradation alleviation ability of surfactant is especially effective at high temperature. Consequently, this results show that the addition of surfactant to the polymer solution can control unfavorable degradation phenomena for high temperature systems.

• 한국세라믹학회지
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• 제29권1호
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• pp.65-73
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• 1992

The effect of grain size on the time-dependent piezoelectrice degradation of a poled PZT of MPB composition Pb0.988Sr0.012 (Zr0.52Ti0.48)O3 with 2.4 mol% of Nb2O5 was studied, and the degradation mechanism was discussed. Changes in the internal bias field and the internal stress both responsible for the time-dependent degradation of poled PZT were examined by the polarization reveral technique, XRD and Vickers indentation, respectively. The piezoelectric degradation increased with increasing time and grain size, and the internal bias field due to space charge diffusion decreased with increasing grain size of poled PZT. The internal bias field, however, was almost insensitive to the degradation time regardless of the grain size. On the other hand, both the x-ray diffraction peak intensity ratio of (002) to (200) and the fracture behavior including the crack propagation support that the ferroelectric domain rearrangement of larger grain size showed rapid relaxation of the internal stress compared with smaller one, which is thought the origin of the larger piezoelectric degradation in the former. In conclusion, the contribution of space charge diffusion on the piezoelectric degradation of PZT is strongly dependent on both the grain size and the composition. Thus, the relaxation of internal stress due to the ferroelectric domain rearrangement as well as the amount and time-dependence of the internal bias field due to space charge diffusion should be considered simultaneously in the degradation mechanism of PZT.

• 한국수소및신에너지학회논문집
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• 제9권3호
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• pp.111-118
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• 1998

The intrinsic degradation behavior of $(V_{0.53}Ti_{0.47})_{0.925}Fe_{0.075}$ alloy with BCC structure and the two plateau regions (the low and high plateau region) has been investigate during the temperature-induced hydrogen absorption-desorption cycling (thermal cycling). After 400 thermal cycles between room temperature and $600^{\circ}C$ under 10atm $H_2$, the total reversible hydrogen absorption capacity decreased by about 40%. From thermal desorption analysis it was found that the degradation behavior at each plateau region was different. In addition, XRD analysis showed that the crystal structure of the sample in de-hydrided state was changed from BCC to BCT after degradation, and that of the sample in hydrided state it was maintained as FCC although peaks were broadened after degradation. From the result of static isothermal hydrogenation treatment it were found that crystal structure change from BCC to BCT was caused by the thermal energy. TEM analysis showed that the peak broadening was due to the formation of an amorphous phase in FCC matrix.

• 한국환경과학회지
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• 제11권3호
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• pp.227-234
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• 2002

Laboratory experiments were conducted to examine the behavior of metalaxyl in environment which was used as pesticide in green soil of golf course and as functions of the characteristics of adsorption, desorption and degradation in soil texture and organic matter contents. Acid water containing metalaxyl was conducted to evaluate the effects on adsorption, desorption and degradation. The adsorption of metalaxyl played more significant role in organic contents than clay contents, and pH Increases more pH 2.5 than pH 5.6. The desorption of metalaxyl from contaminants soil decreased higher organic contents LS-soil than S-soil, but the desorption amount of metalaxyl increased more pH 5.6 than pH 2.5. The rate of degradation of metalaxyl in green soil environmental increased higher organic contents LS-soil than S-soil and decreased more pH 2.5 than pH 5.6. These results indicated that the behavior of metalaxyl of the green soil was affected the soil texture of the golf course. Increasing of organic contents, the adsorption amount of metalaxyl on soil increased. Moreover the decrease of the pH of solution increased adsorption amounts and decreased desorption amounts. As the results, the transportation of metalaxyl in soil decreased the acidic rates. The acidification of soil by the acid rain increased the adsorption amount of metalaxyl, but the degradation of metalaxyl decreased. Therefore, it is possible to sustain contamination in run-off the stream and ground water by residuals in soil.

• 한국전기전자재료학회논문지
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• 제20권6호
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• pp.541-545
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• 2007

The critical current degradation behaviors of multifilamentary Bi-2223 superconducting tapes under pressurized liquid nitrogen were investigated using a r-shaped sample holder which gives a series of bending strains to tape. Three kinds of externally-reinforced Bi-2223 tapes with different hermeticity were used as samples. The tape with the thicker reinforcement layer had a better bending strain tolerance of $I_c$, but when the bending strain was calculated at the outermost filament, the $I_c$ degradation behavior became identical. For all samples, $I_{c0}$ decreased with the increase of applied pressure, but the $I_c$ degradation behavior with bending strain at each pressure level was similar. Furthermore, after depressurization from 1 MPa to atmospheric pressure, $I_c$ was completely recovered to its initial values. When the samples were warmed up to room temperature after pressurization tests, the ballooning damage occurred at lower bending strain regions. The region where ballooning was observed was identical to the one where the significant $I_c$ degradation occurred.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 2002년도 학술대회 논문집
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• pp.144-148
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• 2002

Influences of bending strain on the critical current (I$_{c}$) were investigated in Bi-2223 superconducting tapes at 77K. The effect of bending mode on the I$_{c}$ degradation behavior was discussed in viewpoints of test method, n-value and damage morphology. Especially, in this paper, we reported the I$_{c}$ behavior in Ag alloy/Bi-2223 multifilamentary super- conducting tapes under bending occurred within width x length plane of the tape which was called as a hard bending.nding.