• Title/Summary/Keyword: Degassing

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Mercerization in Degassed Sodium Hydroxide Solution

  • Kim Seung-Il;Lee Eui-So;Yoon Heung-Soo
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.186-190
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    • 2006
  • The application of a degassing system to mercerization process was investigated. It was found that the physical properties of cotton fabrics mercerized in the degassed NaOH solution were superior to those mercerized in NaOH solution. The degree of penetration of the degassed water was examined by measuring wicking height. The wicking height in the degassed water without the wetting agent is higher than that of the saturated water with 0.1 % of wetting agent.

Influence of Surface area, Surface Chemical Structure and Solution pH on the Adsorption of Pb(II) Ions on Activated Carbons

  • Goyal, Meenakshi;Amutha, R.
    • Carbon letters
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    • v.7 no.2
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    • pp.97-104
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    • 2006
  • The influence of carbon surface area, carbon-oxygen groups associated with the carbon surface and the solution pH on the adsorption of Pb(II) ions from aqueous solutions has been studied using three activated carbons. The adsorption isotherms are Type I of BET classification and the data obeys Langmuir adsorption equation. The BET surface area has little effect on the adsorption while it is strongly influenced by the presence of acidic carbon oxygen surface groups. The amount of these surface groups was enhanced by oxidation of the carbons with different oxidizing agents and reduced by eliminating these groups on degassing at different temperatures. The adsorption of Pb(II) ions increases on each oxidation and decreases on degassing the oxidized carbons. The increase in adsorption on oxidation has been attributed to the formation of acidic carbon-oxygen surface groups and the decrease to the elimination of these acidic surface groups on degassing. The adsorption is also influenced by the pH of the aqueous solution. The adsorption is only small at pH values lower than 3 but is considerably larger at higher pH values. Suitable mechanisms consistent with the adsorption data have been suggested.

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Equilibrium and Dynamic Adsorption of Methylene Blue from Aqueous Solutions by Surface Modified Activated Carbons

  • Goyal, Meenakshi;Singh, Sukhmehar;Bansal, Roop C.
    • Carbon letters
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    • v.5 no.4
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    • pp.170-179
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    • 2004
  • The equilibrium and dynamic adsorption of methylene blue from aqueous solutions by activated carbons have been studied. The equilibrium studies have been carried out on two samples of activated carbon fibres and two samples of granulated activated carbons. These activated carbons have different BET surface areas and are associated with varying amounts of carbon oxygen surface groups. The amounts of these surface groups was enhanced by oxidation with $HNO_3$ and $O_2$ gas at $350^{\circ}C$ and decreased by degassing at increasing temperatures of $400^{\circ}$, $650^{\circ}$ and $950^{\circ}C$. The adsorption increases on oxidation of the carbon surface and decreases on degassing. The increase in adsorption has been attributed to the formation of acidic carbon-oxygen surface groups and the decrease in adsorption on degassing to their elimination. The dynamic adsorption studies have been carried out on the two granulated activated carbons using two 50 mm diameter glass columns at a feed concentration of 300 mg/L and at different hydraulic loading rates (HLR) and bed heights. The minimum achievable concentrations are comparatively lower while the adsorption capacities are higher for GAC-S under the same operating conditions. The adsorption capacity of a carbon increases with increase in HLR but the rate of increase decreases at higher HLR values.

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Degassing of Molten A328 Aluminum Alloy by Ultrasonic Vibration (초음파 진동에 의한 A328 알루미늄 합금 용탕의 탈가스)

  • Choe, Kyeong-Hwan;Jang, Hoon;Lim, Jung-Kyu;Kim, Sang-Sub;Cho, Gue-Serb
    • Journal of Korea Foundry Society
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    • v.31 no.6
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    • pp.342-346
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    • 2011
  • A328 alloy is an attractive candidate for recycle-friendly aluminum alloy in the recycling of automotive components. In this study, A328 alloy melt was degassed by ultrasonic vibration and the effect of treatment time on the density, fluidity and mechanical properties was investigated. Experimental results reveal that a constant value of density can be reached after less than 180 seconds of ultrasonic treatment time, but the density decreased when the treatment time was 300 seconds. Ti which was dissolved from the horn during ultrasonic treatment reduced the fluidity of melt. After degassing by ultrasonic vibration for 180 seconds, tensile strength increased from 201MPa to 250MPa, and elongation increased from 2.38% to 3.50%, however, further treatment deteriorated the mechanical properties.

A Technique to Minimize Impurity Signal from Blank Rhenium Filaments for Highly Accurate TIMS Measurements of Uranium in Ultra-Trace Levels

  • Park, Jong-Ho;Choi, In-Hee;Song, Kyu-Seok
    • Mass Spectrometry Letters
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    • v.1 no.1
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    • pp.17-20
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    • 2010
  • As background significantly affects measurement accuracy and a detection limit in determination of the trace amounts of uranium, it is necessary to minimize the impurities in the filaments used for thermal ionization mass spectrometry (TIMS). We have varied the degassing condition such as the heating currents and duration times to reduce the backgrounds from the filaments prepared with zone-refined rhenium tape. The most efficient degassing condition of the heating current and the duration time was determined as 3.5 A and 60 min, respectively. The TIMS measurement combined with the isotope dilution mass spectrometry (IDMS) technique showed that the uranium backgrounds were determined to be in a few fg level from blank rhenium filaments. The background minimized filaments were utilized to measure the uranium isotope ratios of a U030 (NIST) standard sample. The excellent agreement of the measurement with the certified isotope ratios showed that the degassing procedure optimized in this study efficiently reduced the impurity signals of uranium from blank rhenium filaments to a negligible level.

AN EXPERIMENTAL STUDY ON THE BONDING STRENGTH BETWEEN PORCELAIN AND Ni-Cr BASED PORCELAIN ALLOY (도재(陶材)와 도재(陶材) 소부용(燒付用) Ni-Cr계(系) 합금간(合金間)의 결합력(結合力)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Kim, Kyoung-Sun
    • The Journal of Korean Academy of Prosthodontics
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    • v.19 no.1
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    • pp.61-73
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    • 1981
  • The effects of the opaque porcelain firing temperature, the bonding agent and the degassing prior to the opaque firing On the bond strength were investigated by means of the tensile shear stIe$. The diffusional behaviours at the interface of the porcelain and the alloy, and .the microstructures of the ceramic and metal composite were studied for understanding the bonding mechanism. The results obtained in this experiment were summarizd as follow; 1. With no application of bonding agent, the tensile shear strength of the specimen firing at $1840^{\circ}F$ was higher than that of the specimen firing at $1760^{\circ}F$. 2. The highest bond strength was obtained by application of bonding agent without degassing prior to the opaque firing. 3. Application of bonding agent after the degassing showed the lowest bond strength. 4. The greater number of pores were observed at the firing temperature of $1840^{\circ}F$ than that of $1760^{\circ}F$ in the porcelain and the interface respectively.

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Mixing and Gas Removal Behavior in Scrap Remelt of Light Metal by Impeller Agitation (임펠러 교반에 의한 경량금속 스크랩 용해로에서의 혼합 및 탈 가스 거동)

  • 한정환;이주한;김석범;변지영;심재동
    • Resources Recycling
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    • v.7 no.3
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    • pp.42-51
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    • 1998
  • Hydrogen in atmosphere can easily dissolve in melt of light metal alloys. Increasing demand for recycling of light metal a alloys has, therefore, focused attention on the removal of hydrogen gas, and alloy addition in melt has become an imporLant r refining process. For this purpose behaviors of mixing and hydrogen degassing in impeller agitated refming vessel with/without barnes were investigated. Flow patterns, mixing time behavior and kinetics of degassing in various agitating conditions were analysed in watet model experiments. And, numerical analysis on turbulent flow pattern in impeller agitated vessels was performed.

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Effects of special heat treatment on changes in the hardness of a metal-ceramic alloy during the firing process (금속-도재 보철용 합금의 열처리가 소성과정 중 경도 변화에 미치는 영향)

  • Sung-Min Kim
    • Journal of Technologic Dentistry
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    • v.45 no.3
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    • pp.55-60
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    • 2023
  • Purpose: This study aimed to evaluate the effects of a special heat treatment on Pd-Au-Ag metal-ceramic alloy after degassing treatment and on changes in the hardness of the alloy during the firing process. Methods: Specimen alloys were cast and subjected to degassing at 900℃ for 10 minutes. These specimens were then subjected to a special heat treatment at 600℃ for 15 minutes in a dental porcelain furnace. Further, the specimens were subjected to simulated firing in the porcelain furnace. The resulting specimens were then tested for hardness, and changes in the microstructure were observed. Results: There was a decrease in the hardness of the alloy during the simulated firing of the cast alloy due to the coarsening of the particles. Meanwhile, additional heat treatment after degassing was found to play a crucial role in preventing a decrease in hardness. This treatment effectively suppressed the coarsening of the precipitates during repeated firing at high temperatures. Conclusion: Specific heat treatment of the Pd-Au-Ag metal-ceramic alloy prevented a decrease in its hardness and extended the lifespan of the metal-ceramic prosthesis.