• 제목/요약/키워드: Defect concentration

검색결과 236건 처리시간 0.023초

($Eu^{2+}$, $Nd^{3+}$를 도핑시킨 $BaAl_{2}O_{4}$ 형광체의 광학 및 장잔광특성 (Optical and Long After-Glow Characteristics of $Eu^{2+}$, $Nd^{3+}$ doped $BaAl_{2}O_{4}$ Phosphorescent Crystals)

  • 김정환;김병규;이동규
    • 한국응용과학기술학회지
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    • 제19권3호
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    • pp.174-180
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    • 2002
  • In recent days, the study of a new phosphorescent phosphor has been performed in order to overcome the defect of sulfide phosphor and increase the brightness and long after-glow characteristic of phosphorescent phosphor. Particularly, sulfide phosphor usually used is so chemically unstable that the study of oxide phosphors are processing. $Eu^{2+}$, $Nd^{3+}$ doped Ba-Al-O phosphors sintered at $600{\sim}1500^{\circ}C$ for 2hours had the PL emission spectrum and after-glow over $1200^{\circ}C$. In this system, as the mole concentration of alumina increases, emission bands of phosphors moved from 500nm to 380nm. The optimum concentration of flux was 5wt% and after-glow characteristics of phosphors were found at the host material molar ratio ($BaCO_{3}:Al_{2}O_{3}$), 1:1 and 1:3.

CFD를 활용한 밀폐공간 가스질식사고의 피해 영향 평가 (An Estimation of the Consequence Analysis for Asphyxiation Accident in Confined Space using C.F.D.)

  • 조완수;김의수
    • 한국안전학회지
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    • 제33권5호
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    • pp.28-34
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    • 2018
  • Recently, various engineering approaches have been widely used in the accident investigation field to identify the cause of the accident and to predict damage by accident. Computational analysis is the most commonly used method of accident investigation technique. This technique is mainly used to identify the mechanism of the accident generation and to determine the cause when it is difficult to reproduce the situation at the time of the accident or when it is impossible to perform a reproduction experiment. In this study, The computational fluid dynamics analysis for nitrogen asphyxiation accident generated by defect of building structural between diffusion outlet and cooling tower was performed to determine the inflow path of the suffocation gas, death possibility by concentration of suffocation gas and predicted the time of death due to the accident using 3D modeling and FLACS program. We can quantify diffusion concentration of asphyxiation gas and predict mechanism of death occurrence by accident and evaluate the consequence Analysis through this study. In the future, This method can be widely used in the field of gas safety by improving the reliability and validity of the analysis.

Computer Models on Oxygenation Process in the Pulmonary Circulation by Gas Diffusion

  • Chang, Keun-Shik;Bae, Hwang
    • International Journal of Vascular Biomedical Engineering
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    • 제4권1호
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    • pp.9-16
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    • 2006
  • In this article we introduce computer models that have been developed in the past to determine the concentration of metabolic gases, the oxygen and carbon dioxide, along the pulmonary circulation. The terminal concentration of these gases in the arterial blood is related with the total change of the partial pressure of the same gases in the alveoli for the time beginning with inspiration and ending with expiration. It is affected not only by the ventilation-perfusion ratio and the gas diffusion capacity of the lung membrane but also by the pulmonary defect such as shunt, dead space, diffusion impairment and ventilation-perfusion mismatch. Some pathological pulmonary symptoms such as ARDS and CDPD can be understood through the mathematical models of these pulmonary dysfunctions. Quantitative study on the blood oxygenation process using various computer models is therefore of foremost importance in order to monitor not only the pulmonary health but also the cardiac output and cell metabolism. Reviewed in this paper include the basic and advanced methods that enable numerical study on the gas exchange and on the arterial oxygenation process, which might depend on the various heart and lung physiological conditions listed above.

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수소 첨가에 의한 비정질 ITO 박막의 기계적 특성 연구 (Effect of Hydrogen on Mechanical S tability of Amorphous In-Sn-O thin films for flexible electronics)

  • 김서한;송풍근
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.56-56
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    • 2018
  • Transparent conductive oxides (TCOs) have attracted attention due to their high electrical conductivity and optical transparency in the visible region. Consequently, TCOs have been widely used as electrode materials in various electronic devices such as flat panel displays and solar cells. Previous studies on TCOs focused on their electrical and optical performances; there have been numerous attempts to improve these properties, such as chemical doping and crystallinity enhancement. Recently, due to rapidly increasing demand for flexible electronics, the academic interest in the mechanical stability of materials has come to the fore as a major issue. In particular, long-term stability under bending is a crucial requirement for flexible electrodes; however, research on this feature is still in the nascent stage. Hydrogen-incorporated amorphous In-Sn-O (a-ITO) thin films were fabricated by introducing hydrogen gas during deposition. The hydrogen concentration in the film was determined by secondary ion mass spectrometry and was found to vary from $4.7{\times}10^{20}$ to $8.1{\times}10^{20}cm^{-3}$ with increasing $H_2$ flow rate. The mechanical stability of the a-ITO thin films dramatically improved because of hydrogen incorporation, without any observable degradation in their electrical or optical properties. With increasing hydrogen concentration, the compressive residual stress gradually decreased and the subgap absorption at around 3.1 eV was suppressed. Considering that the residual stress and subgap absorption mainly originated from defects, hydrogen may be a promising candidate for defect passivation in flexible electronics.

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PEO-PPO-PEO 블록공중합체를 사용한 마이셀 증진 한외여과법 (유해유기물의 가용화 및 분리특성) (Micellar Enhanced Ultrafiltration Using PEO-PPO-PEO Block Copolymer)

  • 최영국;이동진;김정훈;김동권;이수복
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 춘계 총회 및 학술발표회
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    • pp.83-86
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    • 1998
  • 1. Introduction : Low molecular harmful organics such as 1-naphthol and phenol are widely used in industries, and pose serious environmental problems. Wastewater containing low molecular harmful organics may be ejected from various sources including metal-plating industries, circuit-board manufacturing process, photographic and photo-processing industries, refineries and metal-tailing leachate. The pollution of nation harbors, waterways and ground water resources with these organics has reached critical portions, and might also give hazardous influence on human health. Micellar enhanced ultrafiltration(MEUF) is a recently developed process to remove dissolved organics and/or heavy metals present in small or trace quantities from aqueous solution. In this system, the fatal defect is leakage of surfactants especially at low concentration below CMC(critical micelle concentration), which becomes a secondary pollution. Our group proposed to use biosurfactant and polymeric micelle to solve problems mentioned above. In this study we investigated a modified MEUF using PEO-PPO-PEO (polyethyleneoxide-polypropyleneoxide-polyethyleneoxide) block copolymers for the removal of organic solutes such as 1-naphthol and phenol from aqueous wastewater. We proposed PEO-PPO-PEO block copolymers as new surfactants for forming micelles in MEUF, and investigated the solubilization characteristics and efficiency for the removal of 1-naphthol and phenol. PEO-PPO-PEO block copolymers are, environmentally mild and safe as biosurfactants.

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Corrosion Protection Properties of Cobalt Salt for Water-Based Epoxy Coatings on 2024-T3 Aluminum Alloy

  • Thai, Thu Thuy;Trinh, Anh Truc;Pham, Gia Vu;Pham, Thi Thanh Tam;Xuan, Hoan Nguyen
    • Corrosion Science and Technology
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    • 제19권1호
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    • pp.8-15
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    • 2020
  • In this paper, the efficiency and the inhibition mechanisms of cobalt salts (cobalt nitrate and cobalt-exchange silica Co/Si) for the corrosion protection of AA2024 were investigated in a neutral aqueous solution by using the electrochemical impedance spectroscopy (EIS) and polarization curves. The experimental measurements suggest that cobalt cation plays a role as a cathodic inhibitor. The efficiency of cobalt cation was important at the concentration range from 0.001 to 0.01 M. The formation of precipitates of oxides/hydroxides of cobalt on the surface at low inhibitor concentration was confirmed by the Scanning Electron Microscopy/Energy Dispersive X-Ray Spectroscopy (SEM/EDS) analysis. EIS measurements were also conducted for the AA2024 surface covered by water-based epoxy coating comprising Co/Si salt. The results obtained from exposure in the electrolyte demonstrated the improvement of the barrier and inhibition properties of the coating exposed in the electrolyte solution for a lengthy time. The SEM/EDS analysis in artificial scribes of the coating after salt spray testing revealed the release of cobalt cations in the coating defect to induce the barrier layer on the exposed AA2024 substrate.

ZnO 투명 전도막의 전기적 특성에 미치는 Al2O3 의 도핑 농도 및 방전전력의 효과 (Effect of Doping Amounts of Al2O3 and Discharge Power on the Electrical Properties of ZnO Transparent Conducting Films)

  • 박민우;박강일;김병섭;이세종;곽동주
    • 한국재료학회지
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    • 제14권5호
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    • pp.328-333
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    • 2004
  • Transparent ZnO:Al conductor films for the optoelectronic devices were deposited by using the capacitively coupled DC magnetron sputtering method. The effect of Al doping concentration and discharge power on the electrical and optical properties of the films was studied. The film resistivity of $8.5${\times}$10^{-4}$ $\Omega$-cm was obtained at the discharge power of 40 W with the ZnO target doped with 2 wt% $Al_2$$_O3$. The transmittance of the 840 nm thick film was 91.7% in the visible waves. Increasing doping concentration of 3 wt% $Al_2$$O_3$ in ZnO target results in significant decrease of film resistivity, which may be due to the formation of $Al_2$$O_3$ particles in the as-deposited ZnO:Al film and the reduced ZnO grain sizes. Increasing DC power from 40 to 60 W increases deposition rate by more than 50%, but can induce high defect density in the film, resulting in higher film resistivity.

회전코일 와전류신호를 이용한 증기발생기 곡관형 튜브의 축방향노치 신호의 특성 (Characteristics of Eddy Current Signals of Axial Notches in Steam Generator U-bend Tubes using Rotating Pancake Coils)

  • 김창수;문용식
    • 한국압력기기공학회 논문집
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    • 제8권3호
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    • pp.7-12
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    • 2012
  • Steam generator tubes are critical boundary of the primary and secondary side in nuclear power plants. Eddy current testing is commonly used as the method of non-destructive testing for the safety and integrity of steam generator tubes in the nuclear power plants. Changes in the geometric shape act as a stress concentration factor likely to cause a defect during the steam generator operation. The mixed-signals with the geometric shape are distorted and attributes that are difficult to detect signals. An example is bending stress due to compression process at a U-bend occurring in the intrados region which has a small radius of curvature. The resulting change in the geometric shape may lead to a dent like occurrences. The dent can cause stress concentration and generates stress corrosion cracks. In this study, the steam generator tubes of nuclear power plant were selected to study for analysis of mixed-signal containing dent and stress corrosion cracks.

Electrical characteristics and deep-level transient spectroscopy of a fast-neutron-irradiated 4H-SiC Schottky barrier diode

  • Junesic Park;Byung-Gun Park;Hani Baek;Gwang-Min Sun
    • Nuclear Engineering and Technology
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    • 제55권1호
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    • pp.201-208
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    • 2023
  • The dependence of the electrical characteristics on the fast neutron fluence of an epitaxial 4H-SiC Schottky barrier diode (SBD) was investigated. The 30 MeV cyclotron was used for fast neutron irradiation. The neutron fluences evaluated through Monte Carlo simulation were in the 2.7 × 1011 to 1.45 × 1013 neutrons/cm2 range. Current-voltage and capacitance-voltage measurements were performed to characterize the samples by extracting the parameters of the irradiated SBDs. Neutron-induced defects in the epitaxial layer were identified and quantified using a deep-level transient spectroscopy measurement system developed at the Korea Atomic Energy Research Institute. As the neutron fluence increased from 2.7 × 1011 to 1.45 × 1013 neutrons/cm2, the concentration of the Z1/2 defects increased by approximately 20 times. The maximum defect concentration was estimated as 1.5 × 1014 cm-3 at a neutron fluence of 1.45 × 1013 neutrons/cm2.

Proton Conduction in Nonstoichiometric Σ3 BaZrO3 (210)[001] Tilt Grain Boundary Using Density Functional Theory

  • Kim, Ji-Su;Kim, Yeong-Cheol
    • 한국세라믹학회지
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    • 제53권3호
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    • pp.301-305
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    • 2016
  • We investigate proton conduction in a nonstoichiometric ${\Sigma}3$ $BaZrO_3$ (210)[001] tilt grain boundary using density functional theory (DFT). We employ the space charge layer (SCL) and structural disorder (SD) models with the introduction of protons and oxygen vacancies into the system. The segregation energies of proton and oxygen vacancy are determined as -0.70 and -0.54 eV, respectively. Based on this data, we obtain a Schottky barrier height of 0.52 V and defect concentrations at 600K, in agreement with the reported experimental values. We calculate the energy barrier for proton migration across the grain boundary core as 0.61 eV, from which we derive proton mobility. We also obtain the proton conductivity from the knowledge of proton concentration and mobility. We find that the calculated conductivity of the nonstoichiometric grain boundary is similar to those of the stoichiometric ones in the literature.