• Title/Summary/Keyword: Decomposition rates

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The Determination of Anaerobic Biodegradability Rates Livestock Byproducts Using Double First-Order Kinetic Model

  • Shin, Kook-Sik;Yoon, Young-man;Jung, Ha-Il;Hyun, Byung-Geun;Cho, Hyun-Joon;Sonn, Yeon-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.5
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    • pp.542-548
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    • 2015
  • This study investigated methane productions and a degradation rate of organic matters by German standard method, VDI4630 test. In this study, 4 livestock byproducts from livestock farm were selected for the investigation. The objective of this study was to estimate a distribution of organic matters by using the double first-order kinetics model in order to calculate the rate of biodegradable organic matters which degrade rapidly in the initial stage and the persistently biodegradable organic matters which degrade slowly later. As a result, all the byproducts applied in this study showed rapid decomposition in the initial stage. Then the decomposition rate began to slow down for a certain period and the rate became 5 times slower than the initial decomposition rate. This trend of decomposition rate changes is typical conditions of organic matter decompositions. The easily degradable factors ($k_1$) ranged between $0.145{\sim}0.257day^{-1}$ and persistent degradable factors ($k_2$) were $0.027{\sim}0.080day^{-1}$. Among these results, greater organic matter decomposition rates from VDI4630 had greater $k_1$ values (0.257, $0.211day^{-1}$) and smaller $k_2$ values (0.027, $0.030day^{-1}$) for dairy wastewater and forage byproduct, respectively.

Study on Decomposition of Several Pesticides by Gamma-Irradiation (감마선 조사에 의한 농약 성분의 분해 연구)

  • Lee, Joo-Sang;Jung, Su-Yeon;Oh, Seung-Yeol;Jang, Beom-Su;Park, Sang Hyun
    • Journal of Radiation Industry
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    • v.6 no.3
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    • pp.205-209
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    • 2012
  • The decomposition of 50 pesticides present in an aqueous solution using ${\gamma}-irradiation$ from a $^{60}Co$ gamma-ray source was investigated using laboratory-scale experiment. The rates of decomposition were determined using a gas chromatography-electron capture detector (GC-ECD), high-performance liquid chromatography-photo diode array detector (HPLC-PDA), and HPLC-fluorescence detector (FLD). When the initial concentration of pesticides was 10 ppm, and the radiation dose was 2, 5, 10, 20, and 30 kGy, respectively, 14 pesticide samples showed high removal rates (>50%) at absorbed doses of more than 10 kGy. With the exception of procymidone, they were all completely removed at a 30 kGy irradiation dose. These results provide fundamental data on the reactivity between gamma-irradiation and pesticides in an aqueous solution. Further, an evaluation of the toxicity of radiolytic intermediate products is required.

Hydrogen production by catalytic decomposition of methane over carbon black catalyst in a fluidized bed (카본블랙 촉매를 이용한 유동층 반응기에서 메탄의 직접 열 분해에 의한 수소생산 연구)

  • Jung, Jae-Uk;Nam, Woo-Seok;Yun, Ki-Jun;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.284-287
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    • 2005
  • A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_2 - free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane decomposition reaction was carried out at the temperature range of $850-925^{\circ}C$, methane gas velocity of $1.0U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by SEM image.

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Hydrogen production by catalytic decomposition of methane and propane mixture over carbon black catalyst in a fluidized bed (카본블랙 촉매를 이용한 유동층 반응기에서 메탄과 프로판 혼합물의 촉매 분해에 의한 수소생산 연구)

  • Lee, Seung-Chul;Yoon, Yong-Hee;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.57-60
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    • 2007
  • A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_{2}$ - free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane and propane mixture decomposition reaction was carried out at the temperature range of 850 - 900 $^{\circ}C$, methane and propane mixture gas velocity of 1.0 $U_{mf}$ ${\sim}$ 3.0 $U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by SEM image.

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Effects of controlled environmental changes on the mineralization of soil organic matter

  • Choi, In-Young;Nguyen, Hang Vo-Minh;Choi, Jung Hyun
    • Environmental Engineering Research
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    • v.22 no.4
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    • pp.347-355
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    • 2017
  • This study investigated how the combined changes in environmental conditions and nitrogen (N) deposition influence the mineralization processes and carbon (C) dynamics of wetland soil. For this objective, we conducted a growth chamber experiment to examine the effects of combined changes in environmental conditions and N deposition on the anaerobic decomposition of organic carbon and the emission of greenhouse gases from wetland soil. A chamber with elevated $CO_2$ and temperature showed almost twice the reduction of total decomposition rate compared to the chamber with ambient atmospheric conditions. In addition, $CO_2$ fluxes decreased during the incubation under the conditions of ambient $CO_2$ and temperature. The decrease in anaerobic microbial metabolism resulted from the presence of vegetation, which influences the litter quality of soils. This can be supported by the increase in C/N ratio over the experimental duration. Principle component analysis results demonstrated the opposite locations of loadings for the cases at the initial time and after three months of incubation, which indicates a reduction in the decomposition rate and an increasing C/N ratio during the incubation. From the distribution between the decomposition rate and gas fluxes, we concluded that anaerobic decomposition rates do not have a significantly positive relationship with the fluxes of greenhouse gas emissions from the soil.

Hydrogen Activation and Carbon Dioxide Decomposition Using An Inorganic Recycling Resource (무기성 순환자원의 수소 활성화 및 이산화탄소 분해)

  • Park, Young-Koo;Ko, Jae-Churl;Jeon, Jae-Youl;Park, Joon-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.483-490
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    • 2009
  • This research was conducted to estimate the characteristics of carbon dioxide decomposition using an inorganic sludge. The inorganic sludge was composed of high amount (66.8%) of $Fe_2O_3$. Hydrogen could be reduced with 0.247, 0.433, 0.644, and 0.749 at 350, 400, 450, and $500^{\circ}C$, respectively. The carbon dioxide decomposition rates at 250, 300, 350, 400, 450, and $500^{\circ}C$ were 32, 52, 35, 62, 75, and 84%, respectively. High temperature led to high reduction of hydrogen and better decomposition of carbon dioxide. The specific surface area of the sludge after hydrogen reduction was higher than that after carbon dioxide decomposition. The specific surface area of the sludge was more decreased with increasing of temperature.

Hydrogen production by catalytic decomposition of methane and propane mixture over carbon black catalyst in a fluidized bed (카본블랙 촉매를 이용한 유동층 반응기에서 메탄과 프로판 혼합물의 촉매 분해에 의한 수소생산 연구)

  • Lee, Seung-Chul;Yoon, Yong-Hee;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.97-100
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    • 2007
  • A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_2$ - free hydrogen . The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane and propane mixture decomposition reaction was carried out at the temperature range of 850 - 900 $^{\circ}C$, methane and propane mixture gas velocity of 1.0 $U_{mf}$ ${\sim}$ 3.0 $U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by TEM image.

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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Jung, Jae-Uk;Nam, Woo-Seok;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.85-88
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2$-free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The propane decomposition rate used carbon black N33O as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600{\sim}800^{\circ}C$, paropane gas velocity of $1.0 U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The carbon which was by-product of methane decomposition reaction was deposited on the catalyst surface that was observed by SEM. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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Wood and Leaf Litter Decomposition and Nutrient Release from Tectona grandis Linn. f. in a Tropical Dry Deciduous Forest of Rajasthan, Western India

  • Kumar, J.I. Nirmal;Sajish, P.R.;Kumar, Rita.N.;Bhoi, Rohit Kumar
    • Journal of Forest and Environmental Science
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    • v.26 no.1
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    • pp.17-23
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    • 2010
  • The present study was conducted to quantify wood and leaf litter decomposition and nutrient release of a dominant tree species, Tectona grandis Linn. F. in a tropical dry deciduous forest of Rajasthan, Western India. The mean relative decomposition rate was maximum in the wet summer and minimum during dry summer. Rainfall and its associated variables exhibited greater control over litter decomposition than temperature. The concentrations of N and P increased in decomposing litter with increasing retrieval days. Mass loss was negatively correlated with N and P concentrations. The monthly weight loss was significantly correlated (P < 0.05) with soil moisture and rainfall in both wood and leaf litter. Tectona grandis was found to be most suitable tree species for plantation programmes in dry tropical regions as it has high litter deposition and decomposition rates and thus it has advantages in degraded soil restoration and sustainable land management.

Audio Coder Using an Adaptive Wavelet packet Decomposition and Psychoacoustic (적응 웨이블릿 패킷을 이용한 오디오 부호화기와 심리음향 모델링)

  • 김준성
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1998.06c
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    • pp.245-248
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    • 1998
  • In this paper, a new variable wavelet packet decomposition audio coder, based on the time varying characteristic of the audio signals, is proposed and presents a technique to incorporate psychoacoustic models into an adaptive wave let packet scheme. The proposed filterbank improves the defect of the polyphase filterbank that could not properly represent the critical band and the defect of QMF-tree filter that need high complexity to implement. The filterbank consists of varying number of subband from 4 to 26 bands and use Daubechies 6-order wave let. The codec yields excellent quality at total bit rates of about 128kbps for monophonic CD-quality signals with an sampling frequency of 44.1kHz and reduces complexity by 19% for various bit-rates and sources with encoding and decoding process.

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