• 한국정보디스플레이학회:학술대회논문집
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• 2000.01a
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• pp.191-192
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• 2000

New copolyimides containing nitrile side group were synthesized from copolymerization of pyromellitic dianhydride, m-phenylene diamine and 3,5-diaminobenzonitrile and subsequent thermal imidization of the resulting poly(amic acid). Crystallinity, glass transition temperature and initial decomposition temperature of copolyimides were almost identical to those of homo polyimide prepared from PMDA and m-PDA. Change of pretilt angle induced by the orientation layer of resulting copolyimide was investigated by using a nitrile-containg nematic liquid crystal cell after rubbing. As the content of polar nitrile group was increased in the copolymer, pretilt angle was increased from $3.65^{\circ}$ to $6.49^{\circ}$. The mechanism of this was speculated as the dipolar interaction between the liquid crystal and nitrile groups in copolyimide.

• Journal of the Korean Chemical Society
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• v.16 no.2
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• pp.84-92
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• 1972

A mechanism for the ring formation of nickel phthalocyanine (Ni-Pc) has been proposed based on chemical kinetics. The effect of the catalyst on the rate was examined, and ammonium molybdate has been found to be the most effective. The reaction order of the ring formation was determined to be of the 1st order over all, with only the concentration of urea affecting the rate of the ring formation. All the results including thermodynamic parameters support a conclusion that the rate-determining step seems to be the enolization of the urea-catalyst transition complex, followed by fast decomposition of the tautomeric enolized urea into ammonia and isocyanic acid. These intermediates then reacted with the phthalic anhydride to form imino and diimino-phthalimide, which condense to form nickel phthalocyanine in the presence of the nickel cation.

• Journal of the Korean Chemical Society
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• v.7 no.2
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• pp.106-114
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• 1963

The products from polymer pyrolysis at $450^{\circ}$ are cooled with ice, then liquid and gaseous portions are analysed by gas chromatography. Di-2-ethyl hexyl sebacate column, silicone oil column, silica gel column and tetraethyleneglycol dimethylether column, which was most effective for the separation of hydrocarbon gases, are used. Identification of isomers could be secured more effectively by gas chromatography than mass spectrometry. Elucidation of the mechanism for thermal decomposition of polymers could be done through the identification of pyrolysis products. Although more extensive work is needed, some patterns of polymer pyrolysis are discussed.

• Bulletin of the Korean Chemical Society
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• v.23 no.7
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• pp.990-994
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• 2002

Hydroxybenzothiophenes, dihydroxy-benzothiophenes, and benzothiophenedione were identified as inter-mediates of benzothiophene (BT) exposed to ultrasonic irradiation. It is proposed that benzothiophene is oxidized by OH radical to sequentially for m hydroxybenzothiophenes, dihydroxybenzothiophenes, and benzothiophenedione. Benzothiophene is decomposed rapidly following pseudo-first-order kinetics in a first-order manner by ultrasonic irradiation in aqueous solution. The toxicity of sonochemically treated solutions was checked by E. coli and a less inhibition in bacterial respiration was observed from the 120-min treated benzothiophene sample than from the untreated benzothiophene sample. Also evolution of carbon dioxide and sulfite was observed during ultrasonic reaction. A pathway for ultrasonic decomposition of benzothiophene in aqueous solution is proposed.

• Bulletin of the Korean Chemical Society
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• v.25 no.1
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• pp.45-50
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• 2004

$Cu^{II}$-complexes of N-salicylideneaniline and its derivatives were not light sensitive in most solvents such as acetonitrile. A photo-decomposition occurred upon irradiation in halocarbon solvents such as $CHCl_3$. It has been suggested that such photoreactivity is attributed to the reactivity of charge-transfer to solvent (CTTS) excited state attained upon irradiation. A mechanism has been proposed to account for the results obtained. The complexes have been thermally analysed in nitrogen and static air using thermogravimetry (TG) and derivative thermogravimetry (DTG). The thermal degradation of the complexes proceeds in two or three stages. The kinetic parameters obtained from the Coats-Redfern and Horowitz-Metzger equations show the kinetic compensation effect.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05a
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• pp.74-77
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• 2004

Porous membranes were prepared via thermally induced phase separation (TIPS) of (ethylene-co-vinyl alcohol) (EVOH)/glycerol mixtures. The liquid-liquid (L-L) phase boundaries are shifted to higher temperature when the ethylene contents in EVOH increase. Moreover, the kinetic study proved that the growth of droplets formed by the general liquid-liquid (L-L) phase separation obeyed a power-law scaling relationship in the later stage of spinodal decomposition (SD). A new phase separation mechanism was presented, in which the L-L phase separation could be resulted from the crystallization. The hollow fiber membranes were prepared. The membranes showed asymmetric structures with skin layer near the outer surface, the larger pores just below the skin layer and the smaller pores near the inner surface. The effect of ethylene content (EC) in EVOH, cooling water bath temperature and take-up speed on membrane performance was investigated.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.219-220
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• 2006

To understand the effect of powder characteristics on the thermal debinding behavior, PIM parts produced with powders with different particle sizes and particle shapes were examined to determine their weight losses during thermal debinding. The results show that the average diameter of the pore channel in the compact increased when the temperature increased and when coarse powders were used. However, the weight loss rates did not increase proportionally with the pore size. This suggests that the different powders that are frequently used in PIM parts do not affect the thermal debinding rate significantly. This is because the pore size is much larger than the mean free path of the decomposed gas molecules. Thus, the diffusion rates of the gases are not rate-controlling in thermal debinding. The controlling mechanism of the thermal debinding rate is the decomposition of the backbone binder in the PIM parts.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.436-437
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• 2006

The $Ag/TiO_{2-x}N_x$ nanoparticles were synthesized by photochemical deposition in a $TiO_{2-X}N_X$ suspension system. The prepared products were characterized by means of XRD, Uv-vis and photoluminescence spectra (PL). Its photocatalytic activity was investigated by the decomposition of methylene blue (MB) solution under illumination of visible and ultraviolet light, respectively. Compared to $TiO_{2-x}N_x$, the photocatalytic activity of the as-prepared $Ag/TiO_{2-x}N_x$ is obviously enhanced due to the decreasing recombination of a photoexcitated electron-hole pairs. The Mechanism in which photocatalytic activity is enhanced has been discussed in detail.

• Journal of Communications and Networks
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• v.4 no.3
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• pp.189-198
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• 2002

Precoder has been shown to be able to provide source diversity and design flexibility. In this paper we employ precoding techniques for block transmission based on a multirate filterbank structure. To accommodate multiuser communication with variable data rates, different precoders with corresponding coefficients and up/down sampling rates are used. However, due to unknown multipath distortion, different interferences may exist in the received data, such as multiuser interference, intersymbol interference and interblock interference. To estimate channel parameters for a desired user, we employ all structured signature waveforms associated with different symbols of that user and apply subspace techniques. Therefore better performance of channel estimator can be achieved than the conventional subspace method based only on the signature of the current symbol. The delay for that user can also be jointly estimated. Channel identifiability conditions and asymptotic channel estimation error are investigated in detail. Numerical examples are provided to justify the proposed method. gest either multicode (MC) or multiple processing gain (MPG) mechanism [2], while requiring data rates to be integral multiples of some basic low-rate. In order to support variable rate transmission however, a comprehensive scheme needs to be investigated.

• Proceedings of the Korean Information Science Society Conference
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• 1999.10a
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• pp.99-101
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• 1999

최근 들어 XML에 대한 연구가 늘어나면서, XML(eXtensible Markup Language)문서에 대한 저장/검색에 대한 다양한 방법들이 제시되고 있다. 특히 XML 문서의 구조적인 특성을 살리면서 문서의 저장 및 변경을 원활하게 지원할 수 있는 방안에 대한 요구가 늘고 있다. 기존의 저장관리 시스템을 위한 저장 모델로는 크게, XML 문서의 빠른 검색을 지원할 수 있는 가상분할모델(Virtual Fragmentation Model)과 문서에 대한 변경을 빠르게 지원해 줄 수 있는 분할모델(Decomposition Model)로 나누어 볼 수 있는데, 본 연구에서는 이 두가지 모델의 장점을 취합하여 문서의 검색 속도는 가상분할모델정도로, 문서의 변경속도는 분할모델정도로 빠르게 지원해 줄 수 있는 페이징(Paging)기법에 대해 설계하였다. 본 페이징 기법은 XML문서뿐만 아니라, HTML(HiperText Markup Language) 문서의 저장관리 시스템에서도 똑같이 적용될 수 있다. 본 연구의 후반부에서는 페이징 기법과 다른 기법에 대한 비교를 통하여 페이징 기법의 성능을 분석하였다.