• 제목/요약/키워드: Decomposition effect

검색결과 1,113건 처리시간 0.029초

금속 이온에 의한 과산화수소의 촉매분해 (Catalytic Decomposition of Hydrogen Peroxide by Transition Metal Ions)

  • 김세종;윤병호
    • 펄프종이기술
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    • 제38권3호
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    • pp.79-84
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    • 2006
  • Hydrogen peroxide has been a bleaching chemical for varied pulp, especially mechanical and deinking pulp. It is catalytically decomposed by some transition metals in pulp slurry. In this paper, some metals which can be contained in pulp such as manganese, copper, iron, magnesium and calcium were used to investigate their effect on the decomposition of hydrogen peroxide. From the result, hydrogen peroxide was more decomposed in the order of Mn, Cu, $Fe^{3+}\;and\;Fe^{2+}$, while Mg and Ca had little effect on the decomposition of hydrogen peroxide. The effect of Mg/Mn ratio on the decomposition of hydrogen peroxide was also investigated. At the specific ratio of them(Mg/Mn=10), hindering effect of peroxide decomposition by Mg was decreased.

자기 공명 영상 시스템에서 자화율 분해 영상법에 관한 연구 (A Study of Susceptibility Decomposition in MRI)

  • 노용만;홍인기
    • 대한의용생체공학회:의공학회지
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    • 제16권4호
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    • pp.395-402
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    • 1995
  • 자기공명 영상 시스템에서 영상을 얻고자 하는 물체내의 자화율 차이는 복셀내의 스핀들의 위상을 변화시킨다. 또한 스핀들 상호간의 위상변화로 인하여 영상 신호는 감쇄된다. 이러한 신호 세기의 감쇄는 자기공명 영상분야에서 자화율 효과라 알려져 왔고 이런 효과를 억제시키거나 또는 이용하는 연구가 심도있게 논의되어왔다. 본 논문에서 자화율 효과로 인한 신호의 변화를 분석할 수 있는 새로운 스펙트럼 분해법과 영상법을 제안하였다. 그리고 자화율 스펙트럼 분해법을 위한 펄스시퀀스를 개발하였고, 이것을 상자성(paramagnetic) 성질 때문에 자화율 효과가 생기는 정맥영상에 적용하였다. 컴퓨터 모의 실험과 팬텀(phantom)을 대상으로 한 실험 결과로 스펙트럼 분해법의 타당성을 보였다.

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A damage localization method based on the singular value decomposition (SVD) for plates

  • Yang, Zhi-Bo;Yu, Jin-Tao;Tian, Shao-Hua;Chen, Xue-Feng;Xu, Guan-Ji
    • Smart Structures and Systems
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    • 제22권5호
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    • pp.621-630
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    • 2018
  • Boundary effect and the noise robustness are the two crucial aspects which affect the effectiveness of the damage localization based on the mode shape measurements. To overcome the boundary effect problem and enhance the noise robustness in damage detection, a simple damage localization method is proposed based on the Singular Value Decomposition (SVD) for the mode shape of composite plates. In the proposed method, the boundary effect problem is addressed by the decomposition and reconstruction of mode shape, and the noise robustness in enhanced by the noise filtering during the decomposition and reconstruction process. Numerical validations are performed on plate-like structures for various damage and boundary scenarios. Validations show that the proposed method is accurate and effective in the damage detection for the two-dimensional structures.

The Effect of chemical and physical properties of Korean tales on the decomposition of Malathion in dust formulations

  • Kang, Duk-Chae;Lee, Sung-Hwan;Cho, Chai-Moo
    • Applied Biological Chemistry
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    • 제2권
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    • pp.45-52
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    • 1961
  • The decomposition of malathion in dust for mulations prepared from four Korean tales as carriers during storage period has been studied. Amberlite CG-120, a cation exchange resin . which has higher cation exchange capacity than tales, was also used as a carrier in hope of finding out the effect of nagative charge upon the decomposition of malathion. Besides the original talc powders obtained directly from the mines, the hydrogen ion saturated forms were also used as carriers for comparisonal study. The saturated ions for the resin were hydrogen, sodium and magnesium. As the physical properties of the tales, colloid content, water adsorption capacity, PH, specific surface, phosphate fixing capacity and exchangeable canons were determined, and these properties were correlated with the amount of the decomposition. Following results were obtained from the experiment. 1. The malathion in the talc in dust was found to decompose around 10-15% ofthe total withina month. About 50% of the decom position that took place after a month was found to occur within a week. 2. The resin which has higher cation exchange capacity than the tales was highly effective in the decomposition of malathion compared with the tales. 3. In every case the saturation of the exchange complexes with hydrogen ion greatly accelerated the decomposition of malathion. 4. The most highly correlated physical properties with the decomposition were colloid content and specific surface of the tales. 5. The water adsorption and phosphate fixing capacities of the tales were found not to correlate with the amount of malathion decomposed. From the experimental results it was concluded that the active negative spots on the colloidal tales or the resin attract the electropositive phosphorus atom in a malathion molecule thereby inducing the decomposition easier. The presence of hydrogen ion nearby might cause a catalytic effect in the decomposition of malathion.

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Effect of Sparse Decomposition on Various ICA Algorithms With Application to Image Data

  • Khan, Asif;Kim, In-Taek
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2008년도 하계종합학술대회
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    • pp.967-968
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    • 2008
  • In this paper we demonstrate the effect of sparse decomposition on various Independent Component Analysis (ICA) algorithms for separating simultaneous linear mixture of independent 2-D signals (images). We will show using simulated results that sparse decomposition before Kernel ICA (Sparse Kernel ICA) algorithm produces the best results as compared to other ICA algorithms.

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The Decomposition of Leaf Litters of Some Tree Species in Temperate Deciduous Forest in Korea I. Losses in Dry Weight of Leaf Litter

  • Yang, Keum-Chul;Shim, Jae-Kuk
    • The Korean Journal of Ecology
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    • 제26권4호
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    • pp.203-208
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    • 2003
  • Losses in the dry weight of leaf litter from six tree species were studied during 16 months on the forest floor in temperate deciduous forest of Mt. Cheonma in the vicinity of Seoul in Korea by using litter bag method. The decomposition rate of each leaf litter varies with each species. After 16 months elapsed, the leaf litter of Acer pseudo-sieboidianum showed the highest decomposition constant (0.82) as Olson´s decomposition constant, while that of Pinus densiflora showed the lowest decomposition constant (0.33). The decomposition constant of Quercus mongolica, Q. serrata, Betula ermani and Carpinus laxiflora showed 0.43, 0.37, 0.66 and 0.75, respectively. The decomposition constant of leaf litter was considered with temperature and precipitation which accumulated daily during each term of litter bag collection. The decomposition constant of leaf litter showed closely positive correlation with daily accumulative temperature and precipitation. The relationships between decomposition constant and the daily accumulative temperature and precipitation at each period of litter bag collection were analyzed through multi-regression analysis. The correlation coefficients as a result of multi-regression analysis in Q. mongolica, Q. serrata, P densiflora, B. ermani, C. laxiflorais and A. pseudo-sieboldianum were 0.83, 0.81, 0.69, 0.77, 0.77 and 0.62, respectively. The precipitation showed higher effect, about 10 times, on the leaf litter decomposition than the daily accumulative temperature.

초음파분해반응에 있어서 희가스의 영향 (Effects of Noble Gas on the Sonolytic Decomposition)

  • 임봉빈;김선태
    • 한국환경과학회지
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    • 제11권7호
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    • pp.749-755
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    • 2002
  • The effects of noble gas (such as helium, neon, argon, krypton, and xenon) on the sonolytic decomposition of water and 2-methyl-2-propanol(t-butanol) with 200 KHz high power ultrasound were investigated. The physical properties of the noble gas have an effect on the formation rate of products $(H_2O_2,\;H_2,\;O_2)$ and the decomposition rate on the sonolytic decomposition of water. The pyrolysis products, such as methane, ethane, ethylene, and acetylene are formed during the sonolytic decomposition of t-butanol. From the estimation of the ratio $[C_2H_4+C_2H_2] / [C_2H_6]$, the cavitation temperature would be varied by the used noble gas. In all cases for the sonolytic decomposition of water, t-butanol, and diethyl phthalate, the decomposition rates were xenon > krypton > argon > neon > helium with a significant difference and were closely correlated with the formation rate of OH radical and high temperature inside the cavitation bubble under each noble gas.

n-Pentane 증기의 광촉매 분해 시 Methyl Ethyl Ketone 증기와 Ethyl Acetate 증기의 영향 (Effect of Methyl Ethyl Ketone and Ethyl Acetate Vapor on Photocatalytic Decomposition of n-Pentane Vapor)

  • 감상규;전진우;이민규
    • 한국환경과학회지
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    • 제23권6호
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    • pp.1151-1156
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    • 2014
  • The photocatalytic decomposition characteristics of single n-pentane, n-pentane mixed with methyl ethyl ketone (MEK), and n-pentane mixed with ethyl acetate (EA) by cylindrical UV reactor installed with $TiO_2$-coated perforated plane were studied. The effects of the residence time, the inlet gas concentration, and the oxygen concentration were investigated. The removal efficiency of n-pentane was increased with increasing the residence time and the oxygen concentration, but decreased with increasing the inlet concentration of n-pentane. The photocatalytic decomposition rates of single n-pentane, n-pentane mixed with MEK, and n-pentane mixed with EA fitted well on Langmuir-Hinshelwood kinetics equation. The maximum elimination capacities of single n-pentane, n-pentane mixed with MEK, and n-pentane mixed with EA were obtained to be $465g/m^3{\cdot}day$, $217g/m^3{\cdot}day$, and $320g/m^3{\cdot}day$, respectively. The presence of coexisting MEK and EA vapor had a negative effect on the photocatalytic decomposition of n-pentane and the negative effect of MEK was higher than that of EA.

뜸의 지방 분해 효과에 관한 문헌적 고찰 연구 (Literature Review Study of Lipolysis Effect of Moxibustion Treatment)

  • 조석인;송인;홍권의
    • Journal of Acupuncture Research
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    • 제29권5호
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    • pp.119-126
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    • 2012
  • Objectives : This literature review was researched to observe the evidence of effect of moxibustion in adipose tissue decomposition. Methods : We reviewed studies which contained lipolysis effect of moxibustion treatment in Pubmed. Results : Moxibuston improves blood flow in adipose tissue and stimulates metabolism in the course of lipolysis. Many studies reported that moxibustion stimulated reptin, insulin, testosterone, 5-HT and thromboxane. Especially, moxibustion triggers the HPA axis system, which has an effect on lipometabolism. Based on such effects, moxibustion is considered to have an effect on adipose tissue decomposition. Conclusions : Although moxibution is considered to be effective in adipose tissue decomposition, futher study is needed.

전자빔 공정에 의한 Pentachlorophenol 분해 (Pentachlorophenol(PCP) Decomposition by the Electron-beam Process)

  • 권중근;김종오;권범근
    • 한국지반환경공학회 논문집
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    • 제13권7호
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    • pp.49-54
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    • 2012
  • 본 연구에서는 전자빔(E-beam) 공정을 이용한 펜타클로로페놀(Pentachlorophenol, PCP)의 분해 특성을 조사하였다. 이를 위해 주어진 반응시간(0.6 s) 동안 생성될 수 있는 각종 반응성 화학종의 농도를 예측하였으며, PCP 분해에 미치는 pH와 과산화수소의 영향 및 이에 따른 G-value 등을 조사하였다. 실험결과, 전자빔공정에서 PCP의 분해는 pH의 영향을 받지 않았다. 1mM 이하의 과산화수소의 주입은 PCP 분해를 촉진시킬 수 있으나 그 이상의 과산화수소의 주입은 오히려 PCP의 분해를 감소시키거나 부산물의 형성을 유도할 것으로 관찰되었다. 특히, 옥살산과 미확인된 유기염소 성분의 농도를 증가시키는 것으로 나타났다. 그래서 전자빔공정에서 수산화라디칼의 발생원으로써 적절한 농도의 과산화수소 주입이 고려되어야 할 것으로 생각된다.