• 제목/요약/키워드: Decomposition Products

검색결과 377건 처리시간 0.048초

An Overview of Theoretical and Practical Issues in Spatial Downscaling of Coarse Resolution Satellite-derived Products

  • Park, No-Wook;Kim, Yeseul;Kwak, Geun-Ho
    • 대한원격탐사학회지
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    • 제35권4호
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    • pp.589-607
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    • 2019
  • This paper presents a comprehensive overview of recent model developments and practical issues in spatial downscaling of coarse resolution satellite-derived products. First, theoretical aspects of spatial downscaling models that have been applied when auxiliary variables are available at a finer spatial resolution are outlined and discussed. Based on a thorough literature survey, the spatial downscaling models are classified into two categories, including regression-based and component decomposition-based approaches, and their characteristics and limitations are then discussed. Second, open issues that have not been fully taken into account and future research directions, including quantification of uncertainty, trend component estimation across spatial scales, and an extension to a spatiotemporal downscaling framework, are discussed. If methodological developments pertaining to these issues are done in the near future, spatial downscaling is expected to play an important role in providing rich thematic information at the target spatial resolution.

다당류 탄수화물의 분해과정을 통한 보관 벼의 감모현상에 관한 연구 (A study on the deterioration phenomenon of stored rice during the decomposition process of polysaccharide carbohydrates)

  • 윤용식;안재민;황왕택;노형민;박해민;오경석
    • Journal of Applied Biological Chemistry
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    • 제66권
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    • pp.289-298
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    • 2023
  • 보관된 벼는 시간이 지남에 따라 물리화학적인 변성이 일어난다. 쌀알의 변성에 영향을 주는 중요한 요인으로 온도와 함수율을 들 수 있다. 가급적 저온보관과 밀폐보관이 중요하다. 미시적인 관점에서, 쌀에 함유된 단백질과 지질의 변성은 이미 많은 연구들이 보고되었다. 한편, 실제 보관 현장에서 확인되는 벼의 중량 감소, 즉 감모현상은 현재 진행형이며 다양한 원인으로 발생될 수 있다. 본 논문에서는, 쌀의 주성분인 탄수화물의 분해과정이 감모현상에 중요한 역할을 한다고 가정하였으며, 효소에 의한 탄수화물 분해과정들을 살펴보았다. 관심의 대상이 되는 주요 탄수화물로는 전분과 세포벽에 포함된 탄수화물이 있다. 쌀의 보관 과정 중 중량 감소는 주로 전분의 주성분인 아밀로스와 아밀로펙틴의 분해가 원인일 것으로 보이지만, 단백질과 지질을 포함한 다른 성분들의 변성 또한 종합적으로 영향을 주고 있다고 유추된다.

평판형 유전체 장벽 방전 반응기에서 Acetonitrile의 분해 특성 (Decomposition of Acetonitrile by Planar Type Dielectric Barrier Discharge Reactor)

  • 송영훈;김관태;류삼곤;이해완
    • 한국군사과학기술학회지
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    • 제5권3호
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    • pp.105-112
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    • 2002
  • A combined process of non-thermal plasma and catalytic techniques has been investigated to treat toxic gas compounds in air. The treated gas in the present study is $CH_3$CN that has been known to be a simulant of toxic chemical agent. A planar type dielectric barrier discharge(DBD) reactor has been used to generate non-thermal plasma that produces various chemically active species, O, N, OH, $O_3$, ion, electrons, etc. Several different types of adsorbents and catalysts, which are MS 5A, MS 13X, Pt/alumina, are packed into the plasma reactor, and have been tested to save power consumption and to treat by-products. Various aspects of the present techniques, which are decomposition efficiencies along with the power consumption, by-product analysis, reaction pathways modified by the adsorbents and catalysts, have been discussed in the present study.

DESIGN OF MI DECOMPOSITION MODULE FOR THE COMS IMPS

  • Seo, Seok-Bae;Kang, Chi-Ho;Koo, In-Hoi;Ahn, Sang-Il;Kim, Eun-Kyou
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume I
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    • pp.267-270
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    • 2006
  • COMS has two imaging payloads, MI (Meteorological Imager) and GOCI (Geostationary Ocean Colour Imager). In GOCI case, data are packaged per each slot - one part of 16 two-dimensional arrays for imaging sensors - so its generation algorithm is simple. But MI case, data are made up with sequences of 480 bit blocks and are transmitted to its ground station sequentially. Moreover there is no time information in each 480 bit MI block, so a system in its ground system should be attaching time information at received MI blocks. DM (Decomposition Module) is one module of IMPS that receives Raw Data from DATS and generates Level 0 Products that include time tagging. This paper explains DM design for MI of COMS payloads.

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Preparation and Sintering Characteristics of Y-doped $SrZrO_3$ by Citrate Gel Method

  • Jeon, Yang-Seuk;Sim, Soo-Man
    • The Korean Journal of Ceramics
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    • 제5권3호
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    • pp.217-223
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    • 1999
  • Proten-conductive $SrZr_{0.95} Y_{0.05} O_{2.975}$ powder was prepared by citrate gel method its characteristics and sinterability were investigated. Amorphous gel could be obtained from a citric acid solution that $SrCO_3$ and metal nitrates were dissolved. The initial decomposition of the gel proceeded up to $250^{\circ}C$, followed by combustion of its decomposition products in the temperature range from $250^{\circ}C$ to $500^{\circ}C$. A well-crystallized perovskite phase with a stoichiometric composition after calcination at $1000^{\circ}C$. Sintering green compacts of this powder for 6 h showed a considerable densification to start at $1200^{\circ}C$ and resulted in 86.8% and 96.5% relative densities at $1400^{\circ}C$ and $1600^{\circ}C$, respectively. Whereas, the powder compacts prepared by solid state reaction had much lower relative densities, 73% at $1400^{\circ}C$ and 92% at $1600^{\circ}C$.

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Tris(8-hydroxyquinolino) molybdenum (III)의 합성과 열적 성질에 관하여 (Preparative and Thermal Studies of Tris (8-hydroxyquinolino)molybdenum (III))

  • 최규원;오준석;이광우;이원
    • 대한화학회지
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    • 제12권4호
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    • pp.146-149
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    • 1968
  • A new chelate compound, tris(8-bydroxyquinolino)molybdenum(III), [$Mo(C_9H_6ON)_3$], has been prepared by the method of electrolytic reduction of the acidic molybdate solution. Thermal decomposition products of the chelate has been studied by DTA and TGA method. It is concluded that the decomposition product is a yellowish green colored bis(8-hydroxyquinolino)dioxo molybdenum(VI), [$MoO_2(C_9H_6ON)_2$].

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침강 유황 제조에 있어서의 Hexatomic Sulfur의 Octatomic Sulfur로의 변환에 관한 연구(II) (Studies on the Conversion of Hexatomic Sulfur to Octatomic Sulfur in the Manufacture of the Precipitated Sulfur (II))

  • 라운룡;강화수
    • 약학회지
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    • 제27권3호
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    • pp.229-234
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    • 1983
  • In the manufacture of precipitated sulfur calcium pentasulfide ($CaS_{5}$, train product) and calcium thiosulfate ($CaS_{2}O_{3}$, by-product) are decomposed simultaneously by hydrochloricacid into coarse (not being uniform) particle-size products. To improve this drawback, calcium thiosulfate was prepared directly without making calcium pentasulfide and obtained $S_{6}$ by the acid-decomposition. In the conversion of hexatomic sulfur to octatomic sulfur, the polymerization and the depolymerization were observed by using purification method. The conversion of $S_{6}$ to $S_{8}$ is proceeded by two steps. The first step reaction is affected by impurities (especially $SO_{2}$ and $H_{2}S$), Hexatomic sulfur is inert to triethylamine for the time being by purification, and thereafter a slow conversion to polymeric and then to octatomic sulfur occurs. Instead of calcium pentasulfide, the acid decomposition of calcium thiosulfate has several advantages; uniformity of particle-size of product, increase of yield, and simplicity of procedure.

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An ab initio Study on the Molecular Elimination Reactions of Methacrylonitrile

  • Oh, Chang-Young;Park, Tae-Jun;Kim, Hong-Lae
    • Bulletin of the Korean Chemical Society
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    • 제26권8호
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    • pp.1177-1184
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    • 2005
  • Ab initio quantum chemical molecular orbital calculations have been performed for the unimolecular decomposition of methacrylonitrile ($CH_3C(CN)=CH_2$), especially for HCN and $H_2$ molecular elimination channels. Structures and energies of the reactants, products, and relevant species along the individual reaction pathways were determined by MP2 gradient optimization and MP4 single point energy calculations. Direct four-center elimination of HCN and three-center elimination of H2 channels were identified. In addition, H or CN migration followed by HCN or H2 elimination channels via the methylcyanoethylidene intermediate was also identified. Unlike the case of crotonitrile previously studied, in which the dominant decomposition process was the direct three-center elimination of HCN, the most important reaction pathway should be the direct threecenter elimination of $H_2$ in the case of methacrylonitrile.

Basic Zirconium Sulfate의 제조와 그 열분해 거동 (The Preparation and Thermal Decomposition of the Basic Zirconium Sulfate)

  • 석상일;정하균;주명희;박도순
    • 한국세라믹학회지
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    • 제27권6호
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    • pp.707-712
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    • 1990
  • The basic zirconium sulfate was prepared from ZrOCl2.8H2O and H2SO4 in the 9$0^{\circ}C$ aqueous solution. The pH and amount of unreacted zirconium in the solution that reacton had completed was 0.2 and 10%. As the pH was increased to 1.4 by NH4OH theresulting precipitates were the mixtures of the basic zirconium sulfate and the zirconium hydroxide although the precipitates were recovered completely. The thermal decomposition behavior of this sample has been examined by thermal analysis(TG-DTA), X-ray diffraction study, infrared spectroscopy and sulfur analysis. As a result, it was found that the precipitates have perfectly been decomposed at 85$0^{\circ}C$ accompanying to the release of a molecule of water below 25$0^{\circ}C$ and 85% sulfate at about $600^{\circ}C$. The thermally decomlposed products were initially amorphous phase, which were become metastable tetragonal phase with increment of temperature and finally transformed to the stable monoclinic phase at 100$0^{\circ}C$.

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2,4,6-Trinitrotoluene (TNT)의 광분해 특성 (Photo-decomposition Characteristics of 2,4,6-Trinitrotoluene in a UV/$H_2O_2$ Process)

  • 권범근;최원용;윤제용
    • 상하수도학회지
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    • 제24권6호
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    • pp.775-788
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    • 2010
  • The decomposition of 2,4,6-trinitrotoluene (TNT) and the mass balance of nitrogen (N) species as products were investigated in a UV/H2O2system by varying pH, concentrations of $H_2O_2$, and $O_2$. All experiments were conducted in a semi-batch system employing a 50 mL reaction vessel and a coil-type quartz-tube reactor. In contrast with previous studies employing batch mode, TNT decomposition in the semi-batch mode was proportionally enhanced by increasing $H_2O_2$ concentration to 10 mM (0.034%), indicatingthat an inhibitory effect of excess $H_2O_2$on hydroxyl radical (${\cdot}OH$) can be negligible. N compounds are released as $NO_2^-$ in the early stages of the reaction, but $NO_2^-$ is rapidly oxidized to $NO_3^-$ by means of ${\cdot}OH$. $NH_4^+$ was also detected in this study and showed gradually the increase with increasing reaction time. In this study, $NH_4^+$ production can involve the reduction of nitro group of TNT concurrent with the production of $NO_3^-$. Of the N species originating from TNT decomposition, 12 ~ 72% were inorganic forms (i.e. [$NO_3^-$] + [$NO_2^-$] + [$NH_4^+$]). This result suggests that the large remaining N portions indicate that unidentified N compounds can exist.