• Title/Summary/Keyword: Decolorization

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Decolorization of Rhodamine B by Fenton, Fonton-like and Photo-Fenton-like Oxidation (펜톤, 펜톤-유사 및 광-펜톤-유사 반응을 이용한 Rhodamine B의 탈색)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.33 no.2 s.95
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    • pp.150-157
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    • 2007
  • The chemical and photochemical decolorization of Rhodamine B (RhB) in water has been carried out by Fenton, Fenton-like and photo-Fenton-like process. The effect of applied $H_2O_2,\;Fe^{2+}$ dosage (Fenton process), $H_2O_2,\;Fe^{\circ}$ dosage (Fenton-like and photo-Fenton-like process), UV light power (photo-Fenton-like process) pH (all processes) have been studied. The results obtained showed that more than 98% of color removal was obtained for the RhB solutions in every process. However, Fenton-like process was not suitable for the color removal of RhB because Fenton-like process was required much more reagents than Fenton and photo-Fenton-like process. The Fenton and photo-Fenton-like process showed similar reagents need. Optimum pH for three processes in this study is about pH 3. The relative order of sensitivity for pH of each process was: Fenton-like > photo-Fenton-like > Fenton.

Elimination of COD and Color of Dye by UV/H2O2, UV/TiO2 System (UV/H2O2, UV/TiO2 시스템에서 염료의 색도 및 COD 제거)

  • Kim, Kei-Woul;Park, Joung Mi;Sim, Su-Jin;Yee, Hi-Joung;Rhee, Dong Seok
    • Journal of Industrial Technology
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    • v.20 no.A
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    • pp.51-56
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    • 2000
  • The Photocatalytic decolorization and degradation of commercial dyes were studied using a batch reactor. Degussa P25 titanium dioxide and $H_2O_2$ were used as the photocatalyst and proved to be effective for dyes degradation when they were irradiated with UV light. The light source was a 20W low pressure mercury lamp. Three different kinds of dyes, such as direct dye(congo red), acid dye (acid black) and disperse dye(disperse blue) were tested. Extending the UV only treatment up to 120min, direct dye was decolorized to 60% and degraded to 30% as COD. On the other side, acid and disperse dyes were eliminated less than 10% as color and COD. But, color and COD were eliminated about 90% for all of the three dyes by $UV/H_2O_2$ system. And then the most effective decolorization was done for direct dye with 96% removal efficiency by $UV/TiO_2$ system at 120min with 500mg/L of $TiO_2$.

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Potential of Activated Carbon Derived from Local Common Reed in the Refining of Raw Cane Sugar

  • D-Abdullah, Ibrahim;Girgis, Badie S.;Tmerek, Yassin M.;Badawy, Elsaid H.
    • Carbon letters
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    • v.11 no.3
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    • pp.192-200
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    • 2010
  • Common reed (Fragmites australis), a local invasive grass, was investigated as a possible feedstock for the production of activated carbon. Dried crushed stems were subjected to impregnation with phosphoric acid (30, 40 and 50%) followed by pyrolysis at $400{\sim}500^{\circ}C$ with final washing and drying. Obtained carbons were characterized by determining: carbon yield, ash content, slurry pH, textural properties and capacity to remove color bodies from factory-grade sugar liquor. Produced carbons possessed surface area up to 700 $m^2/g$, total pore volumes up to 0.37 $cm^3/g$, and proved to be microporous in nature. Decolorization of hot sugar liquor at $80^{\circ}C$ showed degrees of color removal of 60 up to 77% from initial color of 1100~1300 ICU, at a carbon dose of 1.0 g/100 ml liquor. No correlation seems to hold between synthesis conditions and % R but depends on the degree of microporosity. A commercial activated carbon N showed a comparative better color removal capacity of 91%. Common reed proved to be a viable carbon precursor for production of good adsorbing carbon suitable for decolorization in the sugar industry, as well as in other environmental remediation processes.

Removal of Rhodamine B in Water by Ultraviolet Radiation Combined with Electrolysis(II) (전기분해와 UV 조사에 의한 수중 Rhodamine B의 제거(II))

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.18 no.6
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    • pp.667-674
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    • 2009
  • This study has carried out to evaluate the effect of NaCI as electrolyte of single (electrolysis and UV process) and complex (electrolysis/UV) processes for the purpose of removal and mineralization of Rhodamine B (RhB) dye in water. It also evaluated the synergetic effect on the combination of electrolysis and UV process. The experimental results showed that RhB removal of UV process was decreased with increase of NaCl, while RhB removal of electrolysis and electrolysis/UV process was increased with increase of NaCI. The decolorization rate of the RhB solution in every process was more rapid than the mineralization rate identified by COD removal. The latter took longer time for further oxidation. Absorption spectra of an aqueous solution containing RhB showed a continued diminution of the RhB concentration in the bulk solution: concomitantly, no new absorption peaks appeared. This confirmed the decolorization of RhB, i.e., the breakup of the chromophores. It was observed that RhB removal in electrolysis/UV process is similar to the sum of the UV and electrolysis. However, it was found that the COD of RhB could be degraded more efficiently by the electrolysis/UV process than the sum of the two individual process. A synergetic effect was demonstrated in electrolysis/UV process.

Study of chemical coagulation conditions for a disperse red dye removal from aqueous solutions

  • Tiaiba, Mohammed;Merzouk, Belkacem;Mazour, Mohammed;Leclerc, Jean P.;Lapicque, Francois
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.9-15
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    • 2018
  • Coagulation process using aluminum sulfate ($Al_2(SO_4)_3$) and ferric chloride ($FeCl_3$) was employed as a treatment method for decolorization of a synthetic textile wastewater containing red dye in this paper. Factors such as initial pH, coagulant dosage, initial concentration, conductivity and mixing conditions that influence color removal efficiency were experimentally tested. It was found that $Al_2(SO_4)_3$ is more efficient than $FeCl_3$ as coagulant. When $40mgL^{-1}$ aluminum sulfate was used, results showed that color induced by the red dye was efficiently removed (> 90 %) and was obtained in a large range of initial pH from 4 to 8 with, and for a dye concentration lower than $235mg\;L^{-1}$. After addition of the coagulant, the medium had to be mixed for 30 min at 60 rpm, then allowed to settle for 40 min. The effects of water conductivity in the range $0.035-2.42mS\;cm^{-1}$ and dye concentration up to $380mg\;L^{-1}$ were also followed and discussed.

Effect of Operating Parameters on Electrochemical Degradation of Rhodamine B by Three-dimensional Electrode (3차원 전극을 사용한 Rhodamine B의 전기분해에 미치는 운전인자의 영향)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.35 no.4
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    • pp.295-303
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    • 2009
  • A simulated wastewater containing the dye Rhodamine B (RhB) was electrolytically treated using a three-dimensional electrode reactor equipped with granular activated carbon (GAC) as particle electrode. The effect of type of packing material (GAC, ACF, Nonwoven fabric fiber coated with activated carbon), amounts of GAC packing (25-100 g), current (0.5-3 A) and electrolyte concentration (0.5-3 g/l) was evaluated. Experimental results showed that performance for RhB decolorization of the 3 three-dimensional electrodes lie in: GAC > Nonwoven fabric fiber > ACF. When considered RhB decolorization, oxidants concentration and electric power, optimum GAC dosage was 50 g. Generated concentration of 3 oxidants ($ClO_2$, free Cl, $H_2O_2$) was increased with increase of applied current, however optimum current for RhB degradation was 2.5 A. The oxidants concentration was increased with increase of NaCl concentration and optimum NaCl dosage for RhB degradation was 1.5 g/l.