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http://dx.doi.org/10.5668/JEHS.2007.33.2.150

Decolorization of Rhodamine B by Fenton, Fonton-like and Photo-Fenton-like Oxidation  

Kim, Dong-Seog (Department of Environmental Science, Catholic University of Daegu)
Park, Young-Seek (Division of Health Science, Daegu University)
Publication Information
Journal of Environmental Health Sciences / v.33, no.2, 2007 , pp. 150-157 More about this Journal
Abstract
The chemical and photochemical decolorization of Rhodamine B (RhB) in water has been carried out by Fenton, Fenton-like and photo-Fenton-like process. The effect of applied $H_2O_2,\;Fe^{2+}$ dosage (Fenton process), $H_2O_2,\;Fe^{\circ}$ dosage (Fenton-like and photo-Fenton-like process), UV light power (photo-Fenton-like process) pH (all processes) have been studied. The results obtained showed that more than 98% of color removal was obtained for the RhB solutions in every process. However, Fenton-like process was not suitable for the color removal of RhB because Fenton-like process was required much more reagents than Fenton and photo-Fenton-like process. The Fenton and photo-Fenton-like process showed similar reagents need. Optimum pH for three processes in this study is about pH 3. The relative order of sensitivity for pH of each process was: Fenton-like > photo-Fenton-like > Fenton.
Keywords
Fenton; Fenton-like; photo-Fenton-like; optimum condition; pH;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 박영식, 안갑환 : 응집, 오존 및 UV 후처리가 염색폐수의 COD와 색도제거에 미치는 영향. 한국환경위생학회지, 27(4), 93-98, 2001
2 황병호, 강명근, 김현경, 원호식, 공성호, 배우근 : 생물학적 및 Fenton 공정에 의한 염색종합폐수의 유기물질 및 색도 제거특성. 대한환경공학회지, 25(9), 1085-1091, 2003
3 이상호, 문혜진, 김유미 : 펜톤 산화 방법에 따른 염색 폐수 처리 효율 향상에 관한 연구. 대한환경공학회지, 25(2), 87-93, 2003
4 장윤영, 최상일 이철효 : 매립지 침출수처리를 위한 펜톤유사반응에 관한 연구. 한국물환경학회지, 16(3), 413-420, 2000
5 장윤영, 최승희, 황경엽 : 나노크기 미세 철입자를 이용한 질산오염수의 고속탈질처리. 한국물환경학회지, 14(4), 463-468, 1998
6 Faust, B. C. and Hoigne, W. H. : Photolysis of Fe complexes as sources of OH radicals in clouds, fog, and rain III. Atmospheric Environment. A, 24, 79-89, 1990   DOI   ScienceOn
7 박성호, 한인섭 : $Fe_0,\;Fe_{2+},\;Fe_{3+}/H_2O_2$ 시스템을 이용한 침출수의 Fenton 산화반응. 대한환경공학회지, 27(4), 402-408, 2005
8 정동철, 장윤영, 최상일 : 0가 철에 의한 난분해성 유기물질의 펜톤유사반응에 관한 연구. 대한환경공학회 추계학술발표회 논문집(1), 29-30, 1999
9 Luching, F., Koser, H., Jank, M. and Ritter, A. : Iron powder, graphite and activated carbon as catalysts for the oxidation of 4-chlorophenol with hydrogen peroxide in aqueous solution. Water Research, 32(9), 2607-2614, 1998   DOI   ScienceOn
10 Malik, P. K. and Sanyal, S. K. : Kinetics of decolorization of azo dyes in wastewater by $UV/TiO_2$ process. Separation and Purification Technology, 36, 167-175, 2004   DOI   ScienceOn
11 Arslan-Alaton, I. and Gurses, F. : Photo-fenton-like and phto-fenton-like oxidation of Procaine Penicillin G formulation effluent. Journal Photochemistry and Photobiology, A: Chemistry, 165, 165-175, 2004   DOI   ScienceOn
12 조일형, 고영림, 이소진, 이홍근, 조경덕 : Fenton 및 Photo-Fenton 산화공정을 이용한 염색폐수의 처리에 관한 연구. 한국환경위생학회지, 26(4), 29-37, 2000
13 Adams, C. E., Ford, D. L. and Eckenfelder, W. W. : Development of design and operation criteria for wastewater treatment. Environtal Press, Inc., Nashville, 1981
14 Chu, W., Kwan, C. Y., Chan, K. H. and Kam, S. K. : A study of kinetic modeling and reaction pathway of 2,4-dichlorophenol transformation by photo-Fentonlike oxidation. Journal of Hazardous Materials, B, 121, 119-126, 2005   DOI   ScienceOn
15 Bossmann, S. H., Oliveros, E., Gb, S., Siegwart, S., Dahlen, E. P., Payawan, L., Straub, M., Wrner, M., Braun, A. M. : New evidence against hydroxyl radi cals as reactive intermeadiates in the thermal and photochemically enhanced Fenton reactions. Journal of Physical Chemistry A., 102, 5542-5550, 1998   DOI   ScienceOn
16 Hsueh, C. L., Huang, Y. H., Wang, C. C. and Chen, C. Y. : Degradation of azo dyes using low iron concentration of fenton and fenton-like system. Chemosphere, 58, 1409-1414, 2005   DOI   ScienceOn
17 Sims, A. F. E. : Phenol oxidation with hydrogen. Effluent and Water Treatment Journal, 21(3), 109-121, 1981
18 배범한, 정재훈, 이성재, 장윤영, 박규홍, 장윤석 : 제강분진을 촉매로 활용한 펜톤유사산화에 의한 고농도 para-nitrophenol의 처리. 대한환경공학회지, 23(10), 1749-1760, 2001
19 Neamtu, M., Yediler, A., Siminiceanu, I. and Kettrup, A. : Oxidation of commercial reactive azo dye aqueous solutions by the photo-Fenton and Fenton-like processes. Journal of Photochemistry and Photobiollogy A: Chemistry, 161, 87-93, 2003   DOI   ScienceOn
20 오동규, 윤태일 : Fenton's Reasent를 이용한 염색폐수의 처리. 대한환경공학회지, 13(2), 123-129, 1991
21 Kang, G. G., Kim, S. Y., Chang, Y. Y., Bae, B. H. and Chang, Y. S. : Steelers' dust-catalyzed oxidative treatment of landfill leachate. Korean Society of Soil and Groundwater Environment, 7(1), 25-31, 2002
22 성일화 : 펜톤산화 반응에 의한 복합폐수의 처리효율 연구. 한국환경보건학회지, 32(5), 446-450, 2006   과학기술학회마을
23 김선희, 이상호 : 펜톤산화와 오존산화 조합에 따른 염색폐수의 유기물질 및 색도 처리효율 비교 평가에 관한 연구. 상하수도학회지, 18(6), 778-784, 2004
24 Sevimli, M. F. and Kinacl, C. : Decolorization of textile wastewater by ozonation and Fenton's process. Water Science Technology, 45(12), 279-286, 2002
25 이상호, 최봉종, 이승목, 김영운 : Fenton 공정과 Photo-Fenton 공정의 매립지 침출수 처리효율 비교. 대한환경공학회지, 24(3), 467-475, 2002
26 Wang, Y. T. : Effect of chemical oxidation on anaerobic biodegradation of model phenolic compounds. Environmental Science Technology, 64(3), 268-273, 1992
27 이웅, 이성재, 박규홍, 배범한, 장윤영, 장윤석 : 제강분진을 이용한 4-chlorophenol의 펜톤유사 산화반응. 한국물환경학회지, 19(4), 401-414, 2003
28 임학규, 남궁규철, 윤제용 : 펜톤 화학 반응의 이론적이해. 공업화학, 16(1), 9-14, 2005
29 Kang, S. F., Lioa, C. H. and Po, S. T. : Decolorization of textile wastewater by photo-Fenton oxidation technology. Chemosphere, 41, 1287-1294, 2000   DOI   ScienceOn
30 Perez, M., Torrades, F., Domenech, X. and Peral, J. : Fenton and photo-Fenton oxidation of textile effluents. Water Research, 36, 2703-2710, 2002   DOI   ScienceOn